44 results on '"isotope analyses"'
Search Results
2. Monks on the move? An assessment of mobility at the medieval Nubian monastery of Ghazali, Sudan (ca. 680–1,275 CE).
- Author
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Stark, Robert J., Ciesielska, Joanna A., and Obłuski, Artur
- Subjects
- *
MONASTERIES , *DENTAL enamel , *MONKS , *ISOTOPIC analysis - Abstract
The location of Ghazali monastery away from the Nile valley within the relatively isolated environs of the Bayuda desert presents a landscape suggestive of mobility toward the monastery by those who chose to reside there as monks. To assess this potentiality, a sample of 37 individuals from the monastic cemetery (Cemetery 2) were analysed for 87Sr/86Sr and δ18O to assess residency during dental enamel formation. The data generated bring into question the nature of mobility to Ghazali monastery, particularly in regard to the potential movement of people from the Nile valley, adjacent desertic landscapes, and further afield. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
3. Interdisciplinary analyses of the remains from three gallery graves at Kinnekulle: tracing Late Neolithic and Early Bronze Age societies in inland Southwestern Sweden.
- Author
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Blank, Malou, Tornberg, Anna, Sjögren, Karl-Göran, Knipper, Corina, Frei, Karin M, Malmström, Helena, Fraser, Magdalena, and Storå, Jan
- Abstract
In this paper, we investigate the Scandinavian Late Neolithic and Early Bronze Age of Kinnekulle in southwestern Sweden. The above-mentioned periods in the study area are poorly understood and the archaeological record consists of a few stray finds and a concentration of 20 gallery graves. This study focuses on three of the gallery graves where commingled skeletons from successive burials were recovered. The human remains and the artefacts from the graves were used for discussing individual life stories as well as living societies with the aim of gaining new knowledge of the last part of the Neolithic and the beginning of the Early Bronze Age in southwestern Sweden. We focused on questions concerning health and trauma, mobility and exchange networks, and diet and subsistence of the people using the graves. Chronological, bioarchaeological, and biomolecular aspects of the burials were approached through the application of archaeological and osteological studies, as well as stable isotope, strontium isotope, radiocarbon, and mtDNA analyses. The study provides evidence for high mobility and diverse diets, as well as inhumations primarily dated to the transition between the Late Neolithic and Early Bronze Age. We suggest that the mountain plateau of Kinnekulle was mainly reserved for the dead, while the people lived in agriculture-based groups in the surrounding lower lying regions. [ABSTRACT FROM AUTHOR]
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- 2023
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4. Resonance photo-ionisation mass spectrometry techniques for the analysis of heavy noble gas isotopes in extra-terrestrial samples
- Author
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Nottingham, Mark and Gilmour, James
- Subjects
551.9 ,Early Solar System ,Cosmic ray exposure ,Four-wave mixing ,Calcium Aluminium rich Inclusions ,Isotope analyses ,Krypton ,RIMSKI ,Resonance Ionisation ,Mass Spectrometry - Abstract
The field of noble gas mass spectrometry is a rapidly developing one. There is a sustained requirement for continuous development of instrumentation in order to allow researchers to answer critical questions facing their respective fields. Within planetary science, the question of whether our solar system is 'typical', has been a driving force behind many lines of research. This project sought to build upon the strong instrumental base of the Isotope Geochemistry and Cosmochemistry group of the University of Manchester, in order to develop the Resonance Ionisation Mass Spectrometer for Krypton Isotopes. From that basis, it then sought to develop techniques and protocols for the analysis of extra-terrestrial samples, particularly those of very low mass. The thesis is broken down into three studies. The first involved the development of the mechanisms used to fill the Xe-Ar four-wave mixing cell. This section covers the development, implementation, and characterisation of the newly installed mass flow controllers. The additional control over the mixing ratio granted allowed an eightfold increase to the sensitivity of the instrument. The reproducibility of the gas ratio is consistently shown throughout, and has ultimately reduced the tuning time of the instrument from a number of weeks to a day. The second section details the required procedures involved in data reduction, and the development of protocols and software for the RIMSKI instrument. A range of approaches are assessed, including a novel approach to cosmic ray exposure age calculations. The methods are discussed and implemented on extra-terrestrial samples, the Stannern eucrite and the Bereba eucrite. Finally, the analytical limits of the RIMSKI instrument are expanded via the measurement of the krypton systems of individual calcium-aluminium-rich inclusions. It is observed that Allende CAIs show a trapped component, Br-derived Kr, as well as an anomalous 'heavy Kr' component (one that is enriched in 86Kr). It is additionally noted that there is a lack of cosmogenic krypton to be found in all but one of the measured inclusions. The implications of these findings are discussed.
- Published
- 2017
5. Creating communities of care: Sex estimation and mobility histories of adolescents buried in the cemetery of St. Mary Magdalen leprosarium (Winchester, England).
- Author
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Filipek, Kori Lea, Roberts, Charlotte A., Montgomery, Janet, Gowland, Rebecca L., Moore, Joanna, Tucker, Katie, and Evans, Jane A.
- Subjects
- *
AMELOGENIN , *PEPTIDES , *COMMUNICABLE diseases , *ISOTOPES , *HANSEN'S disease - Abstract
Objectives: This study examines the biological sex and geographical origins of adolescents buried at the St Mary Magdalen leprosarium (Winchester, UK). The data are combined with archaeological and palaeopathological evidence to broaden the understanding of mobility and its relationship to leprosy and leprosaria in Medieval England. Materials and Methods: Nineteen individuals (~10–25 at death) with skeletal lesions diagnostic of leprosy were analyzed using standard osteological methods. Amelogenin peptides were extracted from five individuals whose biological sex could not be assessed from macroscopic methods. Enamel samples were analyzed to produce 87Sr/86Sr and δ18O values to explore mobility histories. Results: Amelogenin peptides revealed three males and two females. Tooth enamel samples provided an 87Sr/86Sr ratio range from 0.7084 to 0.7103 (mean 0.7090, ±0.0012, 2σ). δ18OP values show a wide range of 15.6‰–19.3‰ (mean 17.8 ± 1.6‰ 2σ), with corresponding δ18ODW values ranging from −9.7‰ to −4.1‰ (mean −6.3 ± 2.4‰ 2σ). Discussion: Amelogenin peptide data reveal the presence of adolescent females with bone changes of leprosy, making them the youngest confirmed females with leprosy in the archaeological record. Results also show at least 12 adolescents were local, and seven were from further afield, including outside Britain. Since St. Mary Magdalen was a leprosarium, it is possible that these people traveled there specifically for care. Archaeological and palaeopathological data support the notion that care was provided at this facility and that leprosy stigma, as we understand it today, may not have existed in this time and place. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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6. Dataset of oxygen, carbon, and strontium isotope values from the Imperial Roman site of Velia (ca. 1st-2nd c. CE), Italy
- Author
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Robert J. Stark, Matthew V. Emery, Henry Schwarcz, Alessandra Sperduti, Luca Bondioli, Oliver E. Craig, and Tracy L. Prowse
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Southwestern Italy (Campania) ,Cilento of Lucania ,Isotope analyses ,Dental enamel ,Imperial Roman ,Human mobility ,Computer applications to medicine. Medical informatics ,R858-859.7 ,Science (General) ,Q1-390 - Abstract
The oxygen (δ18Ocarbonate), strontium (87Sr/86Sr), and previously unpublished carbon (δ13Ccarbonate) isotope data presented herein from the Imperial Roman site of Velia (ca. 1st to 2nd c. CE) were obtained from the dental enamel of human permanent second molars (M2). In total, the permanent M2s of 20 individuals (10 male and 10 female) were sampled at the Museo delle Civiltà in Rome (formerly the Museo Nazionale Preistorico Etnografico “L. Pigorini”) and were subsequently processed and analysed at McMaster University. A subsample of teeth (n=5) was initially subjected to Fourier transform infrared spectroscopy (FTIR) analysis to assess for diagenetic alteration through calculation of crystallinity index (CI) values. Subsequently, tooth enamel was analysed for δ13Ccarbonate and δ18Ocarbonate (VPDB) using a VG OPTIMA Isocarb isotope ratio mass spectrometer (IRMS) at McMaster Research for Stable Isotopologues (MRSI), and 87Sr/86Sr was measured by dynamic multi-collection using a thermal ionization mass spectrometer (TIMS) in the School of Geography and Earth Sciences. The dental enamel isotope data presented represent the first δ18O, δ13Ccarbonate, and 87Sr/86Sr values analysed from Imperial Roman Campania to date, providing data of use for comparative analyses of δ18O, δ13C, and 87Sr/86Sr values within the region and for assisting in documenting human mobility in archaeological contexts. Full interpretation of the δ18O and 87Sr/86Sr data presented here is provided in “Imperial Roman mobility and migration at Velia (1st to 2nd c. CE) in southern Italy” [1].
- Published
- 2021
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7. Moving Forward: A Bioarchaeology of Mobility and Migration.
- Author
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Gregoricka, Lesley A.
- Subjects
- *
ARCHAEOLOGICAL human remains , *RESIDENTIAL mobility , *HUMAN migrations , *IDENTITY (Psychology) , *HUNTER-gatherer societies , *ANTHROPOMETRY , *BODY marking , *SOCIAL groups - Abstract
Growing interest in bioarchaeology and its ability to address complex questions tied to social and biological identities in the past has led to the development of nuanced methods for evaluating mobility and migration using human skeletal remains. Improving our ability to identify both short- and long-term migration through observations of body modification, analyses of biological distance, and applications of biogeochemical and aDNA techniques has enabled us to move beyond the simple dichotomous classification of past individuals as either local or nonlocal. These approaches have elucidated the complexity of migration processes while also revealing the heterogeneous ways in which individual agents and social groups incorporate, instigate, experience, and adapt to movement. These data have likewise demonstrated the potential of bioarchaeology to reveal broader patterns of social organization, social and ethnic identities, fictive kinship, postmarital residence, gender roles and relations, detailed life courses, responses to climate stress, and pathways of disease transmission. As bioarchaeology continues to contribute to mobility and migration studies, human skeletal data should be further contextualized by the archaeological record and linked to anthropological, archaeological, and bioarchaeological theoretical frameworks as part of more holistic attempts to explain the diversity and dynamics of human movement, interaction, and identity construction among communities in the past. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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8. Illness and inclusion: Mobility histories of adolescents with leprosy from Anglo‐Scandinavian Norwich (Eastern England).
- Author
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Filipek, Kori Lea, Roberts, Charlotte A., Gowland, Rebecca L., Montgomery, Janet, and Evans, Jane A.
- Subjects
- *
HANSEN'S disease , *STABLE isotope analysis , *MOLARS , *SOCIAL stigma , *SOCIAL marginality - Abstract
Leprosy is one of the most notorious diseases in history, widely associated with social stigma and exclusion. This study builds on previous work to reevaluate the medicohistorical evidence for social stigma in relation to leprosy. This is achieved by isotopic and palaeopathological analyses of adolescent skeletons (10–25 years old) from the Anglo‐Scandinavian (10th–11th centuries AD) parish cemetery of St. John at the Castle Gate in Norwich (Eastern England/East Anglia). Core enamel samples from premolar and molar teeth from 10 young individuals with diagnostic lesions for leprosy were selected for radiogenic strontium (87Sr/86Sr) and oxygen (δ18O) stable isotope analyses. Isotope data did not exclude anyone from the regional range. Palaeopathological data and archaeological contexts suggest that those with visible signs of leprosy were buried with their local community and in a normative manner, thus challenging the notion of social exclusion experienced by people with leprosy throughout the Medieval Period. This study underscores the importance of bioarchaeological data in challenging broad medicohistorical and archaeological narratives. [ABSTRACT FROM AUTHOR]
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- 2021
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9. Dental caries and breastfeeding in early childhood in the late Medieval and Modern populations from Radom, Poland.
- Author
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Tomczyk, Jacek, Szostek, Krzysztof, Lisowska‐Gaczorek, Aleksandra, Jelec, Paweł, Trzeciecki, Maciej, Zalewska, Marta, and Olczak‐Kowalczyk, Dorota
- Subjects
- *
DENTAL caries , *ANIMAL weaning , *BREAST milk , *TOOTH eruption , *DECIDUOUS teeth , *ISOTOPIC analysis - Abstract
Studies of dental caries on the deciduous dentition can be a source of information about changes in diet, which can be correlated with the time of eruption of the deciduous and permanent teeth. In this respect, the moment of transition from the maternal diet (mother's milk) to solid food is particularly interesting. The aim of this study was to assess changes in the diet of children who inhabited Radom, Poland, in the late Medieval/early Modern (LMP, 14th–17th c.) and Modern (MP, 18th–19th c.) periods by applying odontological and physicochemical methods. We analyzed the dental remains of 104 nonadult individuals (1.0–2.5 years, 3.0–5.5 years, and 6.0–8.0 years), with a total of 1044 deciduous and 108 permanent teeth. The concentration of stable δ15N isotopes in collagen isolated from the femur bones was assessed in 63 individuals (27 children, 36 adults). The diagnosis of dental caries was carried out through visual, radiographic, and fluorescent techniques. Dental caries were recorded in 30% (68/224) of the deciduous teeth in the LMP and 39% (321/820) of the deciduous teeth in the MP. Dental caries were found more often in the two earliest age groups of children in the MP than in the LMP. Early childhood caries (ECC) were diagnosed in 18% of the deciduous dentition of children from the MP. Isotopic analyses showed that the start of weaning occurred in the MP group almost 4 months earlier than in the LMP group (1.1 years in LMP vs. 0.7 years in MP). The final weaning of children from maternal milk in the LMP group took place at 2.5 years of age, whereas in the MP group it took place at 3.2 years of age. The study shows that the period of feeding children exclusively with the mother's milk in the MP was shorter. This means a faster introduction of solid food products to the diet. This could explain the increase in dental caries in primary teeth. [ABSTRACT FROM AUTHOR]
- Published
- 2021
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10. Dental caries and isotope studies in the population of Radom (Poland) between the 11th and 19th centuries.
- Author
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Tomczyk, Jacek, Szostek, Krzysztof, Lisowska‐Gaczorek, Aleksandra, Mnich, Barbara, Zalewska, Marta, Trzeciecki, Maciej, and Olczak‐Kowalczyk, Dorota
- Subjects
- *
DENTAL caries , *NINETEENTH century , *ISOTOPIC analysis , *AGRICULTURAL intensification , *DENTITION , *DENTAL calculus - Abstract
This study aims to assess changes in the diet of individuals from Radom (Poland) by applying odontological and physicochemical methods. We evaluated the intensity of dental caries and quality of diet through isotope analyses (δ13C and δ15N). Three consecutive time periods were selected: the early Medieval (EMP, 11th to 12th c.), late Medieval/early Modern (LMP, 14th to 17th c.) and Modern (MP, 18th to19th c.) periods. The dental remains of 247 adult individuals comprising a total of 3,850 permanent teeth were analysed. The intensity of dental caries increased in subsequent historical periods (EMP 38%, LMP 47% and MP 47%). The lowest proportion of terrestrial C3 diet was noted in the oldest EMP population. The LMP and MP were similar in terms of the type of diet. The proportion of the terrestrial C3 component of the diet was 82% and 79% for LMP and MP, respectively. It can be supposed that the EMP population had such a varied diet that cariogenic products (e.g., cereals) were not the basic source of food, thus slowing down the development of dental caries. Later, there was a clear increase in the cariogenic factor(s) between the EMP and LMP, and this may have been related to the intensification of agricultural production. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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11. When alien catfish meet—Resource overlap between the North American Ictalurus punctatus and immature European Silurus glanis in the Arno River (Italy).
- Author
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Haubrock, Phillip Joschka, Azzini, Martina, Balzani, Paride, Inghilesi, Alberto Francesco, and Tricarico, Elena
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CHANNEL catfish , *CATFISHES , *INTRODUCED species , *GASTROINTESTINAL contents , *HABITAT partitioning (Ecology) , *FOOD chains - Abstract
Due to the increasing globalisation and ongoing introduction of alien species specifically regarding European freshwater ecosystems, native and already present alien species will be confronted with competitors with unknown outcomes. One such case is the situation of the European catfish Silurus glanis introduced in the Arno River (Central Italy), a species sought after by anglers, which is facing competition from the later introduced alien North American channel catfish Ictalurus punctatus. Large catfish species are highly valued among anglers, but their interspecific interactions and potential ecosystem‐level impacts are still poorly known. We used stomach contents and stable isotope analyses to study niche partitioning between these two alien catfish species, coexisting in the Arno River. The results suggest partial niche segregation, with immature S. glanis showing a narrower dietary and isotopic niche and a slightly higher trophic position than I. punctatus. Monitoring the catfish population sizes, trophic niches and effects on lower trophic levels are essential for future management and mitigation of their potential impacts on invaded freshwater ecosystems. [ABSTRACT FROM AUTHOR]
- Published
- 2020
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12. Automated Event Sampling and Real-Time data Access Within Hydrological Measuring Networks by Means of Low-Earth-Orbiting Satellites
- Author
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Stadler, Hermann, Leis, Albrecht, Plieschnegger, Markus, Skritek, Paul, Woletz, Kurt, Farnleitner, Andreas, Golinska, Paulina, editor, Fertsch, Marek, editor, and Marx-Gómez, Jorge, editor
- Published
- 2011
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13. A late Quaternary paleoenvironmental record in sand dunes of the northern Atacama Desert, Chile.
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Finstad, Kari M., Pfeiffer, Marco, Mcnicol, Gavin, Tuite, Michael, Williford, Kenneth, and Amundson, Ronald
- Subjects
- *
PALEOENVIRONMENTAL studies , *SAND dunes , *ANHYDRITE , *RADIOCARBON dating , *ORGANIC compounds - Abstract
This paper reports a previously unidentified paleoenvironmental record found in sand dunes of the Atacama Desert, Chile. Long-term aeolian deflation by prevailing onshore winds has resulted in the deposition of sand on the irregular surface of a Miocene-aged anhydrite outcrop. Two deposits ~25 km apart, along the prevailing wind trajectory, were hand excavated then analyzed for vertical (and temporal) changes in physical and chemical composition. Radiocarbon ages of organic matter embedded within the deposits show that rapid accumulation of sediment began at the last glacial maximum and slowed considerably after the Pacific Ocean attained its present post-glacial level. Over this time period, grain sizes are seen to increase while accumulation rates simultaneously decrease, suggesting greater wind speeds and/or a change or decrease in sediment supply. Changes in δ34S values of sulfate in the sediment beginning ~10 ka indicate an increase in marine sources. Similarly, δ2H values from palmitic acid show a steady increase at ~10 ka, likely resulting from aridification of the region during the Holocene. Due to the extreme aridity in the region, these sand dunes retain a well-preserved chemical record that reflects changes in elevation and coastal proximity after the last glacial maximum. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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14. The Origin of Culturally Diversified Individuals Buried in the Early Iron Age Barrow Cemetery at Chultukov Log-1 (Upper Altai) in Light of the Analysis of Stable Oxygen Isotopes.
- Author
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Oleszczak, Łukasz, Borodovskiy, Andriey P., Lisowska-Gaczorek, Aleksandra, Pawlyta, Jacek, Koziel, Slawomir, Tur, Svietlana S., Cienkosz-Stepańczak, Beata, and Szostek, Krzysztof
- Subjects
PAZYRYK culture ,CEMETERIES ,ARCHAEOLOGICAL human remains ,CULTURE ,OXYGEN isotopes - Abstract
Copyright of Collegium Antropologicum is the property of Croatian Anthropological Society and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2018
15. A FISHY TALE ABOUT A SHEEP AND A DOG - ISOTOPE STUDIES AND MEDIEVAL SÁMI MOBILITY AND HUSBANDRY IN INNER FINNMARK, NORTHERN NORWAY.
- Author
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Spangen, Marte and Fjellström, Markus
- Subjects
ANALYSIS of bones ,ISOTOPIC analysis ,DOG food - Abstract
Datings of sheep and dog bone samples from a so-called 'Sámi circular offering site' at Bealjalgnai in Karasjok Municipality, Finnmark, Norway, show that they were deposited in the Middle Ages. They are among the earliest dated bones from such structures, and the sheep is the oldest known example from this part of inland Finnmark. Isotope analyses show that the dog lived primarily on aquatic foodstuffs, with a substantial marine intake. The sheep's nitrogen and carbon values indicate that it had eaten protein from animals quite high up in the food chain, mainly from freshwater and terrestrial sources, though with a certain intake of marine fodder as well. Two methods were employed to establish the amount of different nutrients eaten by these individuals and the potential marine and freshwater reservoir effects on their datings. Despite several potential sources of error, the results raise intriguing questions about mobility patterns and husbandry among medieval inland North Sámi groups. The cultural historical context of the finds is discussed, suggesting some possible scenarios that may have led to the surprising isotope analysis results. [ABSTRACT FROM AUTHOR]
- Published
- 2018
16. Social identity and geographic origin of Maya burials at Actun Uayazba Kab, Roaring Creek Valley, Belize.
- Author
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Wrobel, Gabriel D., Freiwald, Carolyn, Michael, Amy, Helmke, Christophe, Awe, Jaime, Kennett, Douglas J., Gibbs, Sherry, Ferguson, Josalyn M., and Griffith, Cameron
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- *
ARCHAEOLOGICAL human remains , *CAVES , *GROUP identity , *TAPHONOMY - Abstract
Bioarchaeological investigations at Actun Uayazba Kab (AUK), in west-central Belize, sought to characterize the nature of the site’s mortuary use by reconstructing aspects of social identity. Skeletal analyses provided data related to the age, sex, health, diet, and geographic origins of individuals buried within the rockshelter-like entrance to AUK. Changes in the site’s ritual use were contextualized with current archaeological data from the surrounding region, demonstrating that burial activity was initiated in the Late Preclassic and was likely by a local kin group. Cessation of primary burial sometime around the 3 rd century AD generally coincides with the construction of monumental civic-ceremonial architecture in the area, after which activity at the site appears to have shifted to rituals pertaining to the propitiation of rain. While small cave and rockshelter sites typically receive little research attention in Mesoamerica, the data from AUK illustrate how ritual activities at small, non-elite sites are indeed dynamic and can inform broader models of social and political organization. [ABSTRACT FROM AUTHOR]
- Published
- 2017
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17. Mapping the spatio-temporal risk of lead exposure in apex species for more effective mitigation.
- Author
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Mateo-Tomás, Patricia, Olea, Pedro P., Jiménez-Moreno, María, Camarero, Pablo R., Sánchez-Barbudo, Inés S., Martín-Doimeadios, Rosa C. Rodríguez, and Mateo, Rafael
- Subjects
- *
SYMPATRIC speciation , *SPECIES hybridization , *MENDEL'S law , *CROSSBREEDING , *CHROMOSOME substitution - Abstract
Effective mitigation of the risks posed by environmental contaminants for ecosystem integrity and human health requires knowing their sources and spatio-temporal distribution. We analysed the exposure to lead (Pb) in griffon vulture Gyps fulvus-an apex species valuable as biomonitoring sentinel. We determined vultures' lead exposure and its main sources by combining isotope signatures and modelling analyses of 691 bird blood samples collected over 5 years. We made yearlong spatially explicit predictions of the species risk of lead exposure. Our results highlight elevated lead exposure of griffon vultures (i.e. 44.9% of the studied population, approximately 15% of the European, showed lead blood levels more than 200 ng ml21) partly owing to environmental lead (e.g. geological sources). These exposures to environmental lead of geological sources increased in those vultures exposed to point sources (e.g. lead-based ammunition). These spatial models and pollutant risk maps are powerful tools that identify areas of wildlife exposure to potentially harmful sources of lead that could affect ecosystem and human health. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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18. Diet and mobility in early medieval coastal Belgium: Challenges of interpreting multi-isotopic data
- Author
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Rachèl Spros, Maura Pellegrini, Anton Ervynck, Hannah F. James, Philippe Claeys, Bart Lambert, Christophe Snoeck, Analytical, Environmental & Geo-Chemistry, Chemistry, Doctoraatsbegeleiding, Multidisciplinary Archaeological Research Institute, Earth System Sciences, Brussels Centre for Urban Studies, History, Archeology, Arts, Philosophy and Ethics, Brussels Interdisciplinary Research centre on Migration and Minorities, and Historical Research into urban transformation processes
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Isotope analyses ,Archeology ,Belgian coast ,bioarchaeology ,Early medieval period ,archaeology ,diet ,Marine fishing ,mobility - Abstract
During the early medieval period (5th–9th century CE), the North Sea coastal societies were involved in long distance maritime trade relations, which resulted in a pronounced mobility of individuals throughout the North Sea area. This work presents the first isotope data from human remains on diet and mobility from early medieval Belgian coastal populations. A total of 23 out of 51 excavated individuals from the archaeological site of Koksijde, Belgium (7th–8th century AD), was selected for isotope and elemental analyses (δ13Ccol, δ15N, δ18OP, δ13Cap, δ18OC, 87Sr/86Sr and [Sr]). The high δ15N values of part of the individuals buried at Koksijde indicate that high trophic level ranked fish was included in their diets, suggesting an intensive exploitation of marine food sources. The δ18O values are not compatible with the predicted ‘local’ values while the strontium isotope ratios have values close to that of seawater (0.7092). Either the actual oxygen isotope values in early medieval Belgium are offset by 1 or2‰ compared to the current meteoric water predictions, or the population came from somewhere else. Whether or not this was linked to the population's mobility is difficult to assess based on their δ18O and 87Sr/86Sr values. Nonetheless, the study of the population at Koksijde provides new insights into the lives of the early medieval coastal Belgian societies.
- Published
- 2022
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19. Monthly variations in the shell structure of two freshwater ostracod (Crustacea) species in Karapınar Spring (Bolu, Turkey).
- Author
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KÜLKÖYLÜOĞLU, Okan, PALACIOS-FEST, Manuel R., BARON, Dirk, and SARI, Necmettin
- Subjects
- *
OSTRACODA , *FRESHWATER animals , *COMPARATIVE studies , *BIOLOGICAL specimens , *CHEMICAL stability - Abstract
The variations of environmental conditions (T °C, pH, δ13C, δ18O, Mg/Ca, and Sr/Ca) for two ostracod species (Psychrodromus olivaceus, Potamocypris similis) were analyzed and compared to identify the controls of environmental parameters on the chemical and isotopic composition of their valves. The specimens were collected from Karapınar Spring (Bolu, Turkey) between October 2009 and November 2010. The species were observed throughout the year. Psychrodromus olivaceus showed relatively constant Mg/Ca ratios during the study period, whereas those of P. similis showed more variability. The ratio was also significantly different (P < 0.05) between the two species. We did not find significant correlation between water temperature and either of the species' Mg/Ca ratios. The stable isotope record for P. similis was very patchy, showing a small range of values consistent with the groundwater source, similar to the behavior of Sr/Ca. The Sr/Ca ratio displayed little variation throughout the year, suggesting hydrochemical stability over time, most likely in response to the groundwater source. The stable isotope data displayed pronounced variability for P. similis but little for P. olivaceus, suggesting that the former may be responding to seasonality, whereas the latter responds to groundwater. [ABSTRACT FROM AUTHOR]
- Published
- 2015
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20. Oxalate Patinas on Stone Monuments in the Venetian Lagoon: Characterization and Origin.
- Author
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Bonazza, Alessandra, Sabbioni, Cristina, Ghedini, Nadia, Natali, Claudio, and Vaccaro, Carmela
- Subjects
ARCHITECTURAL details ,ISOTOPES ,BIOMINERALIZATION ,CHURCH building design & construction ,POLLUTANTS ,LICHENS - Abstract
Calcium oxalate patinas have been sampled on architectural elements of two ancient churches located on Torcello Island (Venetian Lagoon) and subsequently analyzed. The site had been selected presenting patinas of exceptional amount and thickness, elsewhere generally found as thin alteration layers covering stone surfaces or within black crusts on monuments in urban environments. Optical and mineralogical analyses suggest that these patinas are not the result of a simple deposition process, but originate as surface “transformations” of the substrate, and are mainly composed of dihydrate calcium oxalate (weddellite) and gypsum. Among the experimental techniques, isotope analyses (C and S) have been specifically carried out aiming at achieving a better understanding of their origin and possible causes of formation. The observed carbon isotopic fingerprint reveals in fact a strong biological fractionation recorded in the oxalate patina (δ13C ranging from −22.3‰ to −28.0‰), almost exclusively attributable to C3 pathway photosynthesis processes. Slightly negative sulfur isotope ratio values seem to be inversely correlated with patina exposure to atmospheric agents and pollutants. The results obtained prove that calcium oxalate originates from a biomineralization process induced by lichen colonization in specific environmental conditions. [ABSTRACT FROM PUBLISHER]
- Published
- 2015
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21. Origin and contacts of people buried at the LBK graveyard at Kleinhadersdorf, Austria
- Author
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Christine Neugebauer-Maresch and Eva Lenneis
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Early Neolithic in Central Europe ,isotope analyses ,mobility of people ,procurement of raw materials ,Archaeology ,CC1-960 - Abstract
In this article we present first information on results of analyses of the Linearbandkeramik (LBK) graveyard of Kleinhadersdorf carried out in recent years. First, we briefly present the excavations and main characteristics of the burials. Analyses of C-, N- and Sr- isotopes, executed with- in a large-scale international project, showed that most of the people were born and lived in the area and gathered food nearby. Only three individuals came from a geologically different region, i.e. the gneiss-granite zone of the Bohemian massif. Adzes and some quern stones were also obtained in this area, while flint raw materials and Spondylus shells for ornaments were procured from other regions.
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- 2013
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22. Origins and mobility patterns of Stone Age humans from the Donkalnis and Spiginas burial grounds according to strontium isotope analysis
- Author
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Gytis Piličiauskas, Edvardas Simčenka, Justina Kozakaitė, Žydrūnė Miliauskienė, Giedrė Piličiauskienė, and Harry Kenneth Robson
- Subjects
Mobility ,Isotope analyses ,Kapinynai. Pilkapiai / Barrow. Burials ,Lietuva (Lithuania) ,Izotopiniai tyrimai ,Mobilumas ,Akmens amžius / Stone Age ,Donkalnis ,Migracija / Migration - Abstract
Priešistorinių žmonių palaikų stroncio izotopų santykio analizė (87Sr/86Sr) leidžia įvertinti jų mobilumą ir identifikuoti pirmos kartos imigrantus, tačiau jos potencialas stipriai priklauso nuo tiriamo regiono geologijos heterogeniškumo ir biologiškai prieinamo stroncio 87Sr/86Sr santykio variacijos pažinimo. Lietuvos archeologijoje stroncio izotopų analizė pirmą kartą panaudota tik 2019–2020 m. Šiame straipsnyje aptarsime šio metodo taikymo galimybes pietryčių Baltijos regione, kurias iliustruosime Donkalnio ir Spigino akmens amžiaus kapinynų buvusiose Biržulio ežero salose tyrimu. Whilst the analysis of strontium isotope ratios (87Sr/86Sr) of human remains enables mobility patterns and migration events to be identified archaeologically, its potential is dependent on the heterogeneity of the underlying geology in the research area, and the knowledge of 87Sr/86Sr ratio variation in the biologically available strontium. In Lithuanian archaeology, strontium isotope analysis has only been relatively recently undertaken (2019–2020). In this paper we discuss the potential of the method, and its application to materials from the Stone Age burial grounds of Donkalnis and Spiginas located on former islands in the Lake Biržulis region, western Lithuania.
- Published
- 2021
23. Viking Mobility in the Baltic Sea Region
- Author
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Hedenstierna-Jonson, Charlotte, Linderholm, Anna, Kjellström, Anna, Hedenstierna-Jonson, Charlotte, Linderholm, Anna, and Kjellström, Anna
- Abstract
Tough mobility and migration could be regarded as diagnostic features of the Viking Age, it is not possible to generalize and treat the Viking World as a homogenous society. Patterns of mobility and migration were linked to social structures and contexts. Studying the composition of the material culture within a site or individual context has been the prevailing method within archaeology to approach issues of mobility. Although this approach has acknowledged restrictions, it has been the method at hand. However, migration and mobility are not necessarily reflected in the material culture, meaning other approaches are called for. The first question to ask is: what variations in mobility patterns between urban and rural contexts are there, and are there indications of significant differences between various geographical regions? Even between sites characterized as trading posts (i.e. not rural), with similar material evidence of long-distance trade and advanced crafts, we might have significant differences, relating to the seasonal or permanent character of the site. In the following paper, we present the results from strontium isotope analyses on archaeological materials from a number of Viking-Age sites within present-day Sweden. The results of the analyses conducted within the ATLAS project will be compared to other isotope studies from Scandinavia, and discussed in relation to local, regional and supra-regional contexts. On a more local level, the possible cultural influence of migrants is investigated.
- Published
- 2020
24. A reassessment of the presumed Neandertal remains from San Bernardino Cave, Italy.
- Author
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Benazzi, Stefano, Peresani, Marco, Talamo, Sahra, Fu, Qiaomei, Mannino, Marcello A., Richards, Michael P., and Hublin, Jean-Jacques
- Subjects
- *
NEANDERTHALS , *HUMAN beings , *MORPHOMETRICS , *ANTHROPOLOGY , *SPELEOLOGY , *PALEONTOLOGY - Abstract
Abstract: In 1986–1987, three human remains were unearthed from macro-unit II of San Bernardino Cave (Berici Hills, Veneto, Italy), a deposit containing a late Mousterian lithic assemblage. The human remains (a distal phalanx, a lower right third molar and a lower right second deciduous incisor) do not show diagnostic morphological features that could be used to determine whether they were from Homo neanderthalensis or Homo sapiens. Despite being of small size, and thus more similar to recent H. sapiens, the specimens were attributed to Neandertals, primarily because they were found in Mousterian layers. We carried out a taxonomic reassessment of the lower right third molar (LRM3; San Bernardino 4) using digital morphometric analysis of the root, ancient DNA analysis, carbon and nitrogen isotope analyses, and direct accelerator mass spectrometry (AMS) radiocarbon dating of dentine collagen. Mitochondrial DNA analysis and root morphology show that the molar belongs to a modern human and not to a Neandertal. Carbon 14 (14C) dating of the molar attributes it to the end of the Middle Ages (1420–1480 cal AD, 2 sigma). Carbon and nitrogen isotope analyses suggest that the individual in question had a diet similar to that of Medieval Italians. These results show that the molar, as well as the other two human remains, belong to recent H. sapiens and were introduced in the Mousterian levels post-depositionally. [Copyright &y& Elsevier]
- Published
- 2014
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25. Bulk stable carbon and deuterium isotope analyses of bitumen artifacts from Hacinebi Tepe, Turkey: reconstructing broad economic patterns of the Uruk expansion
- Author
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Schwartz, Mark and Hollander, David
- Subjects
- *
DEUTERIUM , *BITUMEN , *ANTIQUITIES , *CARBON , *ASPHALTENE - Abstract
Abstract: This research addresses issue of inter-regional trade for the world''s first colonial trading system, the economic expansion of state societies from southern Mesopotamia into southwest Iran and southeast Anatolia, through the use of stable carbon and deuterium isotope analyses of bitumen artifacts. The key goal of the project was to get beyond simply the identification of trade (Schwartz, M., Hollander, D., Stein, G., 1999. Paléorient 25 (1), 67–82) and examine broad regional patterns in the exchange system. To this end, the methodological approach of this research was focused on the reconstruction of general exchange patterns using a large sample set. The results of these analyses suggest the utility of bulk isotopic analyses in the identification of broad regional patterns, serving as a complement to detailed isotopic and molecular work on asphaltene extractions of bitumen (Connan, J., Nishiaki, Y., 2003. Vol. II: Chalcolithic Technology and Subsistence. The University Museum – The University of Tokyo, Tokyo, pp. 283–306). Some of the data indicate changes in the organization of trade at the site of Hacinebi in southeast Turkey and suggest large economic changes in Anatolia associated with the Uruk expansion. [Copyright &y& Elsevier]
- Published
- 2008
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26. Taxonomy, biogeography and ecology of quaternary Benthic Ostracoda (Crustacea) from circumpolar deep water of the Emerald Basin (Southern Ocean) and the S Tasman Rise (Tasman Sea).
- Author
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Mazzini, Ilaria
- Abstract
Benthic Ostracoda were recovered from 19 box core samples collected during the cruise SO 136 of the German R/V SONNE in the Tasman Sea and Southern Ocean (SW Pacific sector). The detailed taxonomic study of more than 10.000 specimens recovered from eleven box-corer samples from circumpolar deep water of the Emerald Basin (Southern Ocean) and the S Tasman Rise (Tasman Sea) led to the recognition of 34 genera and 63 species, of which 9 new to science. Additionally, ten key cosmopolitan and endemic taxa were re-studied and re-illustrated from type material from the Natural History Museum (London), the Utrecht Micropaleontological Collection, the Senckenberg Museum (Frankfurt) and the University of Canterbury (New Zealand). Oxygen and carbon isotopic values were measured on specimens from 17 samples from the Campbell Plateau and the S Tasman Rise. In particular, four podocopid ostracod genera were analysed: the in-faunal Krithe and die epifaunal Fallacihowella, Poseidonamicus and Bradleya. The stable isotopes proxies provided useful indications about the microhabitats, the diets and the temperature sensitivity of each tax-on. Additionally, different calcification rates and different microhabitats were claimed to explain the different isotopic signature of adults and juveniles of Krithe. Statistical analyses were performed on the relative abundance in percentages of 73 species identified in 19 sediment samples. Both species (R-mode) and samples (Q-mode) were grouped by cluster analyses and detrended correspondence analyses (DCA) using the software package PAST (ver. 0.94). Q-mode cluster analyses partially supported the observations made by previous authors that the ostracod specific thresholds are controlled by the water mass characteristics. Q- and R-mode detrended correspondence analyses, on the contrary, indicated that distribution patterns must be driven by factors other than the water mass characteristics. Seven assemblages are recognised and the characteristic or most abundant species are discussed for their ecological demands. Bottom topography, sediment type, CaC0 content, and flux of organic carbon interplay with the water mass characteristics creating a complex network of ecological gradients. Within each of the identified assemblages the species specific thresholds are not identical and often the range of the ecological gradients of the most abundant species do not include that of the characteristic species. Most likely, dynamics of co-occurring species take place which could involve Ostracoda and other benthic animals belonging to the same trophic groupings. [ABSTRACT FROM AUTHOR]
- Published
- 2005
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27. Dental caries and isotope studies in the population of Radom (Poland) between the 11th and 19th centuries
- Author
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Jacek Tomczyk, Maciej Trzeciecki, Aleksandra Lisowska-Gaczorek, Barbara Mnich, Marta Zalewska, Krzysztof Szostek, and Dorota Olczak-Kowalczyk
- Subjects
Archeology ,education.field_of_study ,Geography ,Isotope ,isotope analyses ,Anthropology ,Radom ,Population ,dental caries ,education ,diet ,Demography - Published
- 2020
28. When alien catfish meet—Resource overlap between the North American Ictalurus punctatus and immature European Silurus glanis in the Arno River (Italy)
- Author
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Haubrock, P. J., Azzini, M., Balzani, P., Inghilesi, A. F., and Tricarico, E.
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alien species ,dietary analysis ,interactions ,isotope analyses ,niche overlap ,niche partitioning - Published
- 2020
29. Climate deteriorations and Neanderthal demise in interior Iberia
- Author
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Nature Publishing Group, Wolf, Daniel, Kolb, Thomas, Alcaraz-Castaño, Manuel, Heinrich, Susann, Baumgart, Philipp, Calvo, Ruben, Sánchez, Jésus, Ryborz, Karolin, Schäfer, Imke, Bliedtner, Marcek, Zech, Roland, Zöller, Ludwig, Faust, Dominik, Nature Publishing Group, Wolf, Daniel, Kolb, Thomas, Alcaraz-Castaño, Manuel, Heinrich, Susann, Baumgart, Philipp, Calvo, Ruben, Sánchez, Jésus, Ryborz, Karolin, Schäfer, Imke, Bliedtner, Marcek, Zech, Roland, Zöller, Ludwig, and Faust, Dominik
- Abstract
Time and circumstances for the disappearance of Neanderthals and its relationship with the advent of Modern Humans are not yet sufficiently resolved, especially in case of the Iberian Peninsula. Reconstructing palaeoenvironmental conditions during the last glacial period is crucial to clarifying whether climate deteriorations or competition and contacts with Modern Humans played the pivotal role in driving Neanderthals to extinction. A high-resolution loess record from the Upper Tagus Basin in central Spain demonstrates that the Neanderthal abandonment of inner Iberian territories 42 kyr ago coincided with the evolvement of hostile environmental conditions, while archaeological evidence testifies that this desertion took place regardless of modern humans’ activities. According to stratigraphic findings and stable isotope analyses, this period corresponded to the driest environmental conditions of the last glacial apart from an even drier period linked to Heinrich Stadial 3. Our results show that during Marine Isotope Stages (MIS) 4 and 2 climate deteriorations in interior Iberia temporally coincided with northern hemisphere cold periods (Heinrich stadials). Solely during the middle MIS 3, in a period surrounding 42 kyr ago, this relation seems not straightforward, which may demonstrate the complexity of terrestrial climate conditions during glacial periods.
- Published
- 2018
30. Diet in Lithuania from 4500-1200 cal BC based on data from bulk isotopic analyses of food residue on pottery
- Author
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Piličiauskas, Gytis, Skipitytė, Raminta, and Heron, Carl
- Subjects
Isotope analyses ,Lietuva (Lithuania) ,Izotopiniai tyrimai ,Pottery ,Keramika ,Archeologiniai tyrinėjimai / Archaeological investigations ,Cheminiai tyrimai ,Chemical analyses ,Gyvenvietės (archeologija) / Settlements (Archaeology) ,Diet - Abstract
Straipsnyje pristatome maisto liekanų keramikoje cheminių ir stabiliųjų anglies bei azoto izotopų tyrimų, vykdytų 2014-2017 m., rezultatus. Lietuvoje tai dar menkai išnaudotas informacijos apie priešistorinių žmonių mitybų šaltinis ir dar visai nauja tyrimų kryptis, pradėta vystyti kartu su Jungtinės Karalystės mokslininkais Lietuvos mokslo tarybai parėmus du projektus, todėl greta pirmųjų įžvalgų, hipotezių, išvadų siekiame atskleisti naujų metodų potencialų priešistorinių visuomenių tyrimuose. Gauti rezultatai stebėtinai gerai dera su archeologiniais, zooarcheologiniais, kaulo kolageno stabiliųjų izotopų duomenimis, daro priešistorinės ekonomikos ir mitybos paveikslų gerokai išsamesnį ir labiau pagrįstų. Šie tyrimai patvirtina ryškų pokytį nuo vandeninio maisto prie sausuminio - nuo žvejybos prie gyvulių auginimo daugelyje Lietuvos vietų vykus maždaug 2500 cal BC, kartu su Virvelinės keramikos kultūros žmonių pasirodymu. Svarbu tai, kad pajūrio gyvenvietėse net ir Virvelinės keramikos periodu vandeninio maisto resursų svarba ir toliau išliko didelė. The article presents the results of chemical and stable isotope (carbon and nitrogen) analyses conducted between 2014-2017 on visible deposits of food residue found on pottery. Information about the diet of prehistoric populations has so far been applied sporadically in Lithuania and represents a new research opportunity, the development of which was begun in collaboration with UK scientists after the Research Council of Lithuania supported two projects. As a consequence, alongside the initial insights, hypotheses, and conclusions, an effort was made to reveal the potential of new methods in the investigation ofprehistoric societies. The results obtained are a surprisingly goodfit with the archaeological, zooarchaeological, and bone collagen stable isotope data and help to build a more comprehensive picture of the prehistoric economy and diet. This investigation confirms a distinct transition from aquatic to terrestrial food, i.e. from fishing to husbandry at many locations in Lithuania circa 2500 cal вс, together with the appearance of the peoples of the Corded Ware culture. It is important to note that the exploitation of aquatic food resources still remained high in coastal settlements even in the period of the Corded Ware culture.
- Published
- 2018
31. Interactive Catalog of the Results on the Human Remains from the Neolithic Graveyard al-Buhais 18 (BHS18, UAE) - Archaeological, Osteological and Isotopic Data
- Author
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Kutterer, Adelina, Kutterer, Johannes, and Uerpmann, Hans-Peter
- Subjects
Graveyard ,Al Buhais 18 ,Umm Al Quwain ,South East Arabia ,Dibba ,BHS 18 ,stomatognathic diseases ,Umm An Nar ,Osteology ,Archaeology ,UAQ 2 ,Archäologie , Katalog , Isotop , Osteologie , Arabien , Neolithikum , Friedhof , Gräberfeld ,Sharjah ,Catalog ,Neolithic ,Isotope Analyses ,Sasanian - Abstract
The Neolithic graveyard site of BHS18, located in the Emirate of Sharjah (UAE) yielded nearly 500 human skeletons. The results of the osteological analyses, such as age and sex determinations and pathologies, as well as information on the burial types and the orientation of the graves as well as the available photographs are presented in this catalog. This data was collected in the years between 1996 and 2005. Later on, isotope values for Strontium, Oxygen and Carbon, obtained from tooth enamel of selected individuals from BHS18 and some comparative sites were added and are also listed in the catalog., Der neolithische Friedhof BHS18, im Emirat Sharjah (VAE) gelegen, erbrachte menschliche Skelette von beinahe 500 Individuen. Im vorliegenden Katalog werden die Ergebnisse der osteologischen Analysen, wie Pathologien und Alters- und Geschlechtsbestimmungen, sowie auch die archäologischen Informationen zu den individuellen Bestattungen präsentiert. Diese Daten stammen aus den Jahren 1996-2005. Falls verfügbar, sind auch Fotographien zu den Skeletten gespeichert. In den darauf folgenden Jahren wurden zusätzlich Isotopenmessungen (Strontium, Sauerstoff und Carbonat) an Enamelproben von einigen Individuen aus BHS18 und Vergleichsfundstellen durchgeführt. Die Ergebnisse sind ebenfalls im Katalog aufgeführt.
- Published
- 2017
- Full Text
- View/download PDF
32. Oxalate Patinas on Stone Monuments in the Venetian Lagoon: Characterization and Origin
- Author
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Alessandra Bonazza, Cristina Sabbioni, Claudio Natali, Nadia Ghedini, and Carmela Vaccaro
- Subjects
Gypsum ,010504 meteorology & atmospheric sciences ,Visual Arts and Performing Arts ,Calcium oxalate ,Geochemistry ,Conservation ,010501 environmental sciences ,engineering.material ,lichen ,01 natural sciences ,Oxalate ,chemistry.chemical_compound ,Isotopic signature ,oxalate patina ,Architecture ,Substrate (aquarium) ,0105 earth and related environmental sciences ,biomineralization ,cultural heritage ,isotope analyses ,Ambientale ,Archaeology ,chemistry ,engineering ,Deposition process ,Geology ,Biomineralization ,Weddellite - Abstract
Calcium oxalate patinas have been sampled on architectural elements of two ancient churches located on Torcello Island (Venetian Lagoon) and subsequently analyzed. The site had been selected presenting patinas of exceptional amount and thickness, elsewhere generally found as thin alteration layers covering stone surfaces or within black crusts on monuments in urban environments. Optical and mineralogical analyses suggest that these patinas are not the result of a simple deposition process, but originate as surface “transformations” of the substrate, and are mainly composed of dihydrate calcium oxalate (weddellite) and gypsum. Among the experimental techniques, isotope analyses (C and S) have been specifically carried out aiming at achieving a better understanding of their origin and possible causes of formation. The observed carbon isotopic fingerprint reveals in fact a strong biological fractionation recorded in the oxalate patina (δ13C ranging from −22.3‰ to −28.0‰), almost exclusively attributable to C...
- Published
- 2014
- Full Text
- View/download PDF
33. Resonance Photo-ionisation Mass Spectrometry Techniques for the Analysis of Heavy Noble Gas Isotopes in Extra-terrestrial Samples
- Author
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Nottingham, Mark Christopher and Gilmour, James
- Subjects
Isotope analyses ,Calcium Aluminium rich Inclusions ,Cosmic ray exposure ,Krypton ,Four-wave mixing ,Resonance Ionisation ,RIMSKI ,Early Solar System ,Mass Spectrometry - Abstract
Resonance Photo-ionisation Mass Spectrometry Techniques for the Analysis of Heavy Noble Gas Isotopes in Extra-terrestrial Samples.The field of noble gas mass spectrometry is a rapidly developing one. There is a sustained requirement for continuous development of instrumentation in order to allow researchers to answer critical questions facing their respective fields. Within planetary science, the question of whether our solar system is ‘typical’, has been a driving force behind many lines of research. This project sought to build upon the strong instrumental base of the Isotope Geochemistry and Cosmochemistry group of the University of Manchester, in order to develop the Resonance Ionisation Mass Spectrometer for Krypton Isotopes. From that basis, it then sought to develop techniques and protocols for the analysis of extra-terrestrial samples, particularly those of very low mass. The thesis is broken down into three studies. The first involved the development of the mechanisms used to fill the Xe-Ar four-wave mixing cell. This section covers the development, implementation, and characterisation of the newly installed mass flow controllers. The additional control over the mixing ratio granted allowed an eightfold increase to the sensitivity of the instrument. The reproducibility of the gas ratio is consistently shown throughout, and has ultimately reduced the tuning time of the instrument from a number of weeks to a day. The second section details the required procedures involved in data reduction, and the development of protocols and software for the RIMSKI instrument. A range of approaches are assessed, including a novel approach to cosmic ray exposure age calculations. The methods are discussed and implemented on extra-terrestrial samples, the Stannern eucrite and the Bereba eucrite. Finally, the analytical limits of the RIMSKI instrument are expanded via the measurement of the krypton systems of individual calcium-aluminium-rich inclusions. It is observed that Allende CAIs show a trapped component, Br-derived Kr, as well as an anomalous ‘heavy Kr’ component (one that is enriched in 86Kr). It is additionally noted that there is a lack of cosmogenic krypton to be found in all but one of the measured inclusions. The implications of these findings are discussed. A spreadsheet attachment used for data reduction, additionally it includes a full copy of the raw unprocessed data of this thesis.
- Published
- 2017
34. Mapping the spatio-temporal risk of lead exposure in apex species for more effective mitigation
- Author
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Patricia Mateo-Tomás, R.C. Rodríguez Martín-Doimeadios, Pedro P. Olea, María Jiménez-Moreno, Inés S. Sánchez-Barbudo, Rafael Mateo, Pablo R. Camarero, Gobierno de Aragón, and Fundação para a Ciência e a Tecnologia (Portugal)
- Subjects
0106 biological sciences ,Isotope analyses ,Population ,Big game hunting ,010501 environmental sciences ,Biology ,Ecotoxicology ,010603 evolutionary biology ,01 natural sciences ,Risk Assessment ,General Biochemistry, Genetics and Molecular Biology ,Gyps fulvus ,Spatio-Temporal Analysis ,biology.animal ,Environmental monitoring ,Biomonitoring ,Animals ,Ecosystem ,Species distribution models ,education ,Falconiformes ,0105 earth and related environmental sciences ,General Environmental Science ,Vulture ,Pollutant ,education.field_of_study ,General Immunology and Microbiology ,Ecology ,General Medicine ,biology.organism_classification ,Lead ,Environmental Pollutants ,General Agricultural and Biological Sciences ,Risk assessment ,Research Article ,Environmental Monitoring - Abstract
Effective mitigation of the risks posed by environmental contaminants for ecosystem integrity and human health requires knowing their sources and spatio-temporal distribution. We analysed the exposure to lead (Pb) in griffon vulture Gyps fulvus—an apex species valuable as biomonitoring sentinel. We determined vultures’ lead exposure and its main sources by combining isotope signatures and modelling analyses of 691 bird blood samples collected over 5 years. We made yearlong spatially explicit predictions of the species risk of lead exposure. Our results highlight elevated lead exposure of griffon vultures (i.e. 44.9% of the studied population, approximately 15% of the European, showed lead blood levels more than 200 ng ml) partly owing to environmental lead (e.g. geological sources). These exposures to environmental lead of geological sources increased in those vultures exposed to point sources (e.g. lead-based ammunition). These spatial models and pollutant risk maps are powerful tools that identify areas of wildlife exposure to potentially harmful sources of lead that could affect ecosystem and human health., The Regional Government of Aragón funded this study. P.M.-T. was funded under the Portuguese FCT grant SFRH/BPD/112437/2015.
- Published
- 2016
35. Mapping the spatio-temporal risk of lead exposure in apex species for more effective mitigation
- Author
-
Gobierno de Aragón, Fundação para a Ciência e a Tecnologia (Portugal), Mateo-Tomás, Patricia, Olea, Pedro P., Camarero, Pablo R., Sánchez-Barbudo, Inés S., Mateo, Rafael, Gobierno de Aragón, Fundação para a Ciência e a Tecnologia (Portugal), Mateo-Tomás, Patricia, Olea, Pedro P., Camarero, Pablo R., Sánchez-Barbudo, Inés S., and Mateo, Rafael
- Abstract
Effective mitigation of the risks posed by environmental contaminants for ecosystem integrity and human health requires knowing their sources and spatio-temporal distribution. We analysed the exposure to lead (Pb) in griffon vulture Gyps fulvus—an apex species valuable as biomonitoring sentinel. We determined vultures’ lead exposure and its main sources by combining isotope signatures and modelling analyses of 691 bird blood samples collected over 5 years. We made yearlong spatially explicit predictions of the species risk of lead exposure. Our results highlight elevated lead exposure of griffon vultures (i.e. 44.9% of the studied population, approximately 15% of the European, showed lead blood levels more than 200 ng ml) partly owing to environmental lead (e.g. geological sources). These exposures to environmental lead of geological sources increased in those vultures exposed to point sources (e.g. lead-based ammunition). These spatial models and pollutant risk maps are powerful tools that identify areas of wildlife exposure to potentially harmful sources of lead that could affect ecosystem and human health.
- Published
- 2016
36. Kaolin deposits from the northern sector of the Cunene anorthosite complex (southern Angola)
- Author
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Umberto Pieruccini, Emidio Tertulliano Lopes da Silva, Maurizio Violo, and G. Saviano
- Subjects
Supergene (geology) ,Fracture (mineralogy) ,Geochemistry ,angola ,Soil Science ,Mineralogy ,Feldspar ,cunene anorthosite complex ,Anorthosite ,Geochemistry and Petrology ,clay-forming fluids ,Earth and Planetary Sciences (miscellaneous) ,Kaolinite ,kaolin ,Water Science and Technology ,geography ,geography.geographical_feature_category ,Gabbro ,isotope analyses ,Massif ,visual_art ,kaolin mafic rocks ,visual_art.visual_art_medium ,mafic rocks ,Clay minerals ,Geology - Abstract
The Mevaiela kaolin deposits are located in the northern part of the anorthositic-gabbro massif within the Cunene complex (southern Angola) and were formed by the alteration of basic anorthosites and gabbros. The Mevaiela area is part of an elevated region which is located between two extensive NNW-SSE fracture systems. Several kaolinite samples were collected from a quarry (main excavation) and from drill-holes as well as from surficial occurrences in the Cunene complex. Chemical analyses, X-ray diffraction, differential thermal analysis, scanning electron microscopy and isotope analyses were performed in order to model the kaolinite occurrences. The alteration of the anorthosite to kaolin approaching the main excavation is characterized by significant decrease in alkaline-earth and transition metals (Ca, Mg, Fe, Co, Ni and Mn) between the average anorthosite and the kaolin. The crystallinity indices suggest that the kaolin contains kaolinite with a reasonably well ordered structure and near the transition between T (triclinic) and pM (pseudo monoclinic). Mineral exploration tools have been evaluated during this study to assist in future kaolin exploration in the Cunene anorthosite complex. Isotopic analysis of O and D indicates that Ca-feldspar alteration is essentially due to meteoric fluids, over a different range of temperatures. Furthermore, the presence of quartz-feldspar veinlets in the kaolinite bodies could be the result of hydrothermal activity linked to post-anorthosite granite intrusions of the so-called ‘red granite’. Kaolinite from Cunene plots on or close to the kaolinite line into the ‘warm temperature in tropical region’ area (surficial samples). Samples from drill-holes plot on the left and show the largest displacement from the KS line; these samples also have a relatively reduced dD range of values (−65 to −98%). However, if supergene processes take place in the presence of waters of meteoric origin at temperatures similar to typical surface temperatures, the clays thus formed should plot either in the vicinity of the KS line or be displaced towards lower dO18 and higher dD, depending on both the temperature and relative proportion of clay to water.
- Published
- 2005
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37. Calcite-aragonite mineral separation using staining method for micro-scale isotopic analyses
- Subjects
Meigen's solution ,isotope analyses ,Staining method ,Feigl's solution ,calcite ,aragonite - Abstract
Mineral separation in carbonate group of minerals is a difficult task, and often resolved by staining technique. Feigl's solution and Meigen's solution are commonly used for distinguishing aragonite from the carbonate, the former stains black and the latter stains purple on the aragonite surface, while calcite and other carbonate species are changeless during staining treatment with each solution. Hence, we report a refined staining technique to separate aragonite from calcite using Meigen's solution. This method has advantage in obtaining 100% pure mineral separation for high precision of micro scale isotope analyses. As an example, we analyzed calcite-aragonite pairs from carbonate chimneys and found interesting isotopic results. Especially, radiocarbon activity in coexisting calcite and aragonite is significantly different, and this result suggests the presence of entirely different fluid source for calcite and aragonite precipitation.
- Published
- 2001
38. Transport et dégradation de pesticides en zones humides : une approche multi-échelles
- Author
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Maillard, Elodie, Laboratoire d'Hydrologie et de Géochimie de Strasbourg (LHyGeS), École Nationale du Génie de l'Eau et de l'Environnement de Strasbourg (ENGEES)-Université de Strasbourg (UNISTRA)-Institut national des sciences de l'Univers (INSU - CNRS)-Ecole et Observatoire des Sciences de la Terre (EOST), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Université de Strasbourg, and Gwenaël Imfeld
- Subjects
Conditions hydrologiques ,Hydrological conditions ,Enantiomeric analyses ,Isotope analyses ,Produits de dégradation ,Analyses isotopiques ,Conditions d’oxydo-réduction ,[SDU.STU]Sciences of the Universe [physics]/Earth Sciences ,Emerging pesticides ,Analyses chirales ,Zones humides ,Chiral molecules ,Redox conditions ,Wetland systems ,Molécules chirales ,Degradation products ,Pesticides émergents - Abstract
A mechanistic understanding of transport and degradation processes of modern agricultural pesticides, including chiral pesticides, is critical for predicting their fate in the environment. In agricultural landscapes, wetlands can intercept pesticide-contaminated runoff or groundwater and improve water quality through various retention and degradation processes, which remain unknown. In a downscaling approach, three different wetlands receiving agricultural runoff were used as ‘natural laboratories’ to investigate the fate of widely used pesticides. Overall, our results showed that dynamics of hydrological and redox conditions largely influenced pesticide sorption mechanisms and their distribution over time within wetland compartments, thereby controlling degradation processes. While large-scale studies provide integrative information on pesticide dissipation and distribution patterns with respect to wetland functioning, small-scale investigations using novel methods such as isotope and enantiomer analyses characterize underlying molecular processes governing pesticide degradation.; La compréhension des mécanismes de transport et de dégradation des pesticides émergents est primordiale pour prédire leur devenir dans l’environnement. Les zones humides peuvent intercepter des eaux de ruissellement ou des souterraines contaminées par les pesticides et les traiter par le biais de processus de rétention et de dégradation, encore peu connus. Dans une approche multi-échelles, trois zones humides recevant des eaux polluées par les pesticides ont été utilisées comme des « laboratoires naturels » pour étudier le devenir de pesticides couramment utilisés. Cette thèse souligne l’influence des conditions hydrologiques et redox sur la distribution des pesticides au sein des différents compartiments des zones humides ainsi que sur leur potentiel de dégradation. Alors que les études à grande échelle fournissent des informations intégratives sur la dissipation et la rétention des pesticides en lien avec le développement de la végétation, les études à petite échelle utilisant des techniques innovantes telles que les analyses isotopiques et énantiomériques permettent l’exploration des processus moléculaires de dégradation des pesticides.
- Published
- 2014
39. Transport and degradation of pesticides in wetland systems : a downscaling approach
- Author
-
Maillard, Elodie, Laboratoire d'Hydrologie et de Géochimie de Strasbourg (LHyGeS), École Nationale du Génie de l'Eau et de l'Environnement de Strasbourg (ENGEES)-Université de Strasbourg (UNISTRA)-Institut national des sciences de l'Univers (INSU - CNRS)-Ecole et Observatoire des Sciences de la Terre (EOST), Institut national des sciences de l'Univers (INSU - CNRS)-Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Université de Strasbourg, and Gwenaël Imfeld
- Subjects
Conditions hydrologiques ,Hydrological conditions ,Enantiomeric analyses ,Isotope analyses ,Produits de dégradation ,Analyses isotopiques ,Conditions d’oxydo-réduction ,[SDU.STU]Sciences of the Universe [physics]/Earth Sciences ,Emerging pesticides ,Analyses chirales ,Zones humides ,Chiral molecules ,Redox conditions ,Wetland systems ,Molécules chirales ,Degradation products ,Pesticides émergents - Abstract
A mechanistic understanding of transport and degradation processes of modern agricultural pesticides, including chiral pesticides, is critical for predicting their fate in the environment. In agricultural landscapes, wetlands can intercept pesticide-contaminated runoff or groundwater and improve water quality through various retention and degradation processes, which remain unknown. In a downscaling approach, three different wetlands receiving agricultural runoff were used as ‘natural laboratories’ to investigate the fate of widely used pesticides. Overall, our results showed that dynamics of hydrological and redox conditions largely influenced pesticide sorption mechanisms and their distribution over time within wetland compartments, thereby controlling degradation processes. While large-scale studies provide integrative information on pesticide dissipation and distribution patterns with respect to wetland functioning, small-scale investigations using novel methods such as isotope and enantiomer analyses characterize underlying molecular processes governing pesticide degradation.; La compréhension des mécanismes de transport et de dégradation des pesticides émergents est primordiale pour prédire leur devenir dans l’environnement. Les zones humides peuvent intercepter des eaux de ruissellement ou des souterraines contaminées par les pesticides et les traiter par le biais de processus de rétention et de dégradation, encore peu connus. Dans une approche multi-échelles, trois zones humides recevant des eaux polluées par les pesticides ont été utilisées comme des « laboratoires naturels » pour étudier le devenir de pesticides couramment utilisés. Cette thèse souligne l’influence des conditions hydrologiques et redox sur la distribution des pesticides au sein des différents compartiments des zones humides ainsi que sur leur potentiel de dégradation. Alors que les études à grande échelle fournissent des informations intégratives sur la dissipation et la rétention des pesticides en lien avec le développement de la végétation, les études à petite échelle utilisant des techniques innovantes telles que les analyses isotopiques et énantiomériques permettent l’exploration des processus moléculaires de dégradation des pesticides.
- Published
- 2014
40. Chromium isotopic signature of naturally Cr (VI) contaminated spring waters from Western Tuscany
- Author
-
Chiarantini, L., Agostini, A., Baneschi, I., Natali, Claudio, and Tonarini, S.
- Subjects
Chromium ,isotope analyses - Published
- 2014
41. Sedimentology and Geochemistry of the Tufa Deposits and associated Spring Waters emerging along a normal Fault Zone, Honaz, Denizli, SW Turkey
- Author
-
Özkul, Mehmet, Gökgöz, Ali, and Horvatinčić, Nada
- Subjects
tufa ,Turkey ,isotope analyses ,geochemistry - Abstract
The Denizli basin in the extensional province of western Turkey is well known by its travertine and tufa occurances. The southeast margin of the basin was bounded the by the active Honaz normal fault. In this study, sedimentology and geochemistry of the tufa deposits and associated spring waters were investigated at the Honaz area. The site is located to the western end of the Honaz fault trending east-west direction. The tufa deposits were exposed on the hangingwall of the fault. The studied area is consisted of Kayaaltı , Değ irmenler and Colossae sites. The first two sites are adjacent to each other, whereas the third one is about 5 km to the northeast near the Colossae ancient city in the Aksu streem valley. The tufa mass of the Kayaaltı -Değ irmenler sites was developed as a steep tufa cliff in the north-northeast direction and pinches out in both sides. The upper part of the tufa cliff has been formed in waterfall facies, on the other hand, the lower part represented distal slope was typified by horizontally bedded and detrital tufas. The Kayaaltı tufa deposits are covered by a flat surface at the top. This landscape indicates a perched springline tufa morphology reached up in maturity stage. Most of the deposits are passive apart from the northeast corner of the tufa body at the Değ irmenler site which is the former water mills area. The Pı narbaşı karstic spring waters have been emerging from an altitude of 492 m in the Honaz fault zone. The aquifer rocks are mainly composed of Mesozoic carbonates in the catchment area on the footwall of the fault to the south. The tufa-precipitating waters today run to the Değ irmenler active tufa site in a distance of 1395 m from the spring area by a concrete channel. The waters of spring and accompanying two wells have a flow rate of about 1200 l/s. The water chemistry of the karstic spring is quite different relative to some well-known tufa sites. The waters are certainly enriched in Ca, Mg, HCO3 and SO4. It was classified as Ca-HCO3-SO4 water and supersaturated with respect to CaCO3. The water temperatures of the spring and associated two wells are 18.6, 20.0 and 23.9º C, respectively. The pH values range from 6.6 at the spring to 8.2 at the Değ irmenler active site. The SO4: 122-239 and HCO3: 236-443 in ppm. The chemical and isotopic composition of the tufa deposits as follows: The Sr content is considerably higher with a range from 729.8 to 2780 ppm. The 14C activities are lower (min.: 7.5, mean: 20.0 and max.: 39.5 pMC). The δ 13C values are between -0.40 to +3.45 (VPDB ‰ ), while the δ 18O values are from +20.55 and +22.92 (VSMOW ‰ ). The positive values of the carbon isotopes indicate predominantly mineral origin of carbon. Consequently, studied tufa deposits have a position close boundary between tufa and travertine in geochemical and isotopic composition. Although the spring carbonates investigated were precipitated from the deeply circulated waters with a certain meteoric contribution along the fault zone. However, they were regarded as tufa rather than travertine based on their depositional morphology and field scale features.
- Published
- 2009
42. Comparison of Pb purification by anion-exchange resin methods and assessment of long-term reproducibility of Th/U/Pb ratio measurements by quadrupole ICP-MS
- Author
-
Kamber, Balz, Gladu, Annette, Kamber, Balz, and Gladu, Annette
- Abstract
A comparison between HBr-HCl and HBr-HNO(3) based anion chemistry is presented to test the efficiency of Pb purification in the preparation of samples for isotope ratio measurement by ICP-MS. It was found that the small advantages in yield and blank offered by the HNO(3)-based method were more than compensated by the more effective matrix removal of the HCl-based method. Apart from very zinc rich matrices (e.g., sphalerite), a careful single pass purification using HBr and HCl removed more than 99.9% of the matrix. In preparation for the isotope ratio analysis, a small (2-5% m/v) liquid sample aliquot was analysed to determine U, Th and Pb concentrations by solution quadrupole ICP-MS. This allowed accurate prediction of the expected ion signal and permitted optimal spiking with Tl, if desired, for mass bias correction. Long-term results for international rock reference materials showed reproducibilities of better than 1% (Th/U) and 1.5% (U/Pb). For most geological applications, such analyses obviate the need for isotope dilution concentration measurements.
- Published
- 2009
43. Taxonomy, biogeography and ecology of Quaternary benthic Ostracoda (Crustacea) from circumpolar deep water of the Emerald Basin (Southern Ocean) and the S Tasman Rise (Tasman Sea)
- Author
-
Mazzini and Ilaria
- Subjects
Isotope analyses ,Pacific Ocean ,genetic structures ,Ecology ,Quaternary Ostracoda ,Systematics ,Statistics - Abstract
[object Object]
- Published
- 2005
44. 微量同位体比測定のための染色法による方解石-霰石の分離法
- Author
-
加藤 和浩, 和田 秀樹, 加藤 和浩, and 和田 秀樹
- Abstract
Mineral separation in carbonate group of minerals is a difficult task, and often resolved by staining technique. Feigl's solution and Meigen's solution are commonly used for distinguishing aragonite from the carbonate, the former stains black and the latter stains purple on the aragonite surface, while calcite and other carbonate species are changeless during staining treatment with each solution. Hence, we report a refined staining technique to separate aragonite from calcite using Meigen's solution. This method has advantage in obtaining 100% pure mineral separation for high precision of micro scale isotope analyses. As an example, we analyzed calcite-aragonite pairs from carbonate chimneys and found interesting isotopic results. Especially, radiocarbon activity in coexisting calcite and aragonite is significantly different, and this result suggests the presence of entirely different fluid source for calcite and aragonite precipitation., publisher
- Published
- 2001
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