1. The spreading of macroscopic droplets
- Author
-
S. Nicolet, Anne-Marie Cazabat, M. A. Cohen Stuart, F. Heslot, and P. Levinson
- Subjects
Self-similarity ,Laboratorium voor Fysische chemie en Kolloïdkunde ,Thermodynamics ,02 engineering and technology ,010402 general chemistry ,01 natural sciences ,Contact angle ,Physics::Fluid Dynamics ,self similarity ,numerical methods ,Life Science ,heterogeneous distribution ,Physical Chemistry and Colloid Science ,contact angle ,drops ,Laplace's equation ,macroscopic contact angle ,wetting ,Chemistry ,Drop (liquid) ,Numerical analysis ,quasi equilibrium ,sessile drops ,Mechanics ,Laplace equation ,hanging drops ,021001 nanoscience & nanotechnology ,0104 chemical sciences ,Rough surface ,[PHYS.HIST]Physics [physics]/Physics archives ,hydrodynamics ,hydrodynamic equations ,Wetting ,0210 nano-technology ,macroscopic foot ,Quasistatic process - Abstract
Some experimental results on the macroscopic spreading of hanging and sessile drops on smooth surfaces are presented. The results for sessile drops nicely corroborate the main aspects of the spreading theory of de Gennes and Joanny. However, it is shown that one assumption of the theory, namely the retainment of a self-similar shape during spreading, which is approximately true for sessile drops, cannot be used for hanging drops, for which no theory is available. We propose a numerical resolution of the hydrodynamic equations which relaxes the necessity of self-similarity. The calculation involves the assumption that the shape of a (sessile or hanging) drop at any given time is in quasi-equilibrium with itself and can therefore be calculated through the Laplace equation. The calculation is indeed capable of describing the spreading of both sessile and hanging drops in detail. Spreading of sessile drops on rough surfaces may also be interpreted in the spirit of the theory of de Gennes and Joanny. Evidence is presented that the kinetics of the macroscopic foot which develops at the edge of a drop spreading on a rough surface is related to the heterogeneous distribution of the macroscopic contact angle and obeys simple equations.
- Published
- 1988
- Full Text
- View/download PDF