In order to accomplish significant primary energy saving and GHG (greenhouse gas) emissions reduction, CHP (combined heat and power) technology can be adopted largely for industrial and civil sectors. Waiting for the cutting-edge appliances (i.e. Fuel Cell) wide deployment, ICEs (internal combustion engines) fuelled with an environmentally-friendly fuel, such as H 2 NG (hydrogen-natural gas mixtures) could represent the bridge technology towards the forthcoming pure hydrogen economy. This paper deals with the results of an experimental campaign carried out on a Single Cylinder ICE, fuelled with NG (natural gas) and H 2 NG @ 15% vol. In detail, energy performances were assessed at rated and partial loads. From data analysis, it emerged that the electrical efficiency increased up to 2.28%, at the expense of the heat recovery one, having added hydrogen. Additionally, due to the higher water content in exhaust gas when H 2 NG is burned, it was investigated on how heat recovery efficiency has been affected by condensing operating conditions. Finally, to estimate this benefit, an expeditious procedure was developed building three maps for H 2 NG blends condensing properties from 0% up to 30% vol. of H 2 . Their outputs provided the condensation efficiency value and the absolute gain of heat recovery one with varying exhaust gas temperatures and hydrogen fraction in the mixture. [ABSTRACT FROM AUTHOR]