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1. Synthesis and Spectroscopic Characterization of the Heterobimetallic Chain Compounds [Mpdl2]N and [Cuptl2]N (M = Co, Ni, Cu, Zn, Pt - L2- = N,N'-Dimethylmonothiooxamido)

Author

Perlepes, S. P., Plakatouras, J. C., and Desseyn, H. O.

Subjects
heterobimetallic complexes, complexes, oxamides, thermal-analysis, planar dithiooxamides, pd(ii), complexes as ligands, design, vibrational-spectra, crystal-structure, vibrational spectra, molecular-based ferromagnet, monothiooxamides
Abstract

By using the ''complexes as ligands'' synthetic strategy and the unique [Pd(LH)2] and [Pt(LH)2] precursors, the novel heterobimetallic polymeric compounds [MPdL2]n and [CuPtL2]n (M = Co, Ni, Cu, Zn, Pt; L2- = the dianion of N,N'-dimethylmonothiooxamide) have been prepared. The vibrational analysis of the complexes is given using various isotopic substitutions. The polymers consist of alternate planar PdO2S2 (or PtO2S2) and tetrahedrally-distorted planar MN4 structural units. Spectroscopy Letters

Published
1993

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