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This paper established a three-dimensional transient MHD model of a high-current multi-component vacuum arc under a transverse magnetic field (TMF) to simulate the dynamic characteristics of plasma parameters in the uniform motion mode of a contracted arc under lower TMF. The model considered the ionization–recombination process among the multi-components and used the P1 model to calculate the thermal radiation losses. The simulation results show that the ion number density of The TMF arc is on the order 1024 m−3, and when the plasma temperature reaches 4.3 eV, the effects of thermal radiation cannot be ignored. The majority of the plasma from the cathode and anode undergo acceleration and then deceleration before finally intersecting at the center of the arc, creating an extreme value of the density and the pressure, where a large amount of kinetic energy is converted into internal energy. The arc will be bent and deflected under the action of the ampere force, and the deflection of Cu3+ is especially obvious. The TMF affects the collision strength of the jet in the intersection area and, thus, affects the ion density, in which the change of Cu2+ is dominant. The ionization–recombination process of ions is mainly determined by the electron temperature, which is affected by the arc current. As the current decreases, Cu1+ increases and Cu2+ and Cu3+ decrease, and the change in ionization rate is the main reason for the change in the proportion of each ionic component; the heat flux density to the anode and cathode is on the order of 1010 W/m2, which heats the front of the arc and ensures the stable movement of the arc. Meanwhile, due to the high ion number density, the ion heat flux accounts for the main part of the heat flux, and the anode exhibits a higher proportion of ion heat flux. [ABSTRACT FROM AUTHOR]

A nanosecond Nd:YAG laser was used to study the laser ablation of aluminum foil in the phase explosion regime at a laser intensity range of 0.63–3.61 × 10 12 W / cm 2. Laser ablation and plasma characteristics were studied using microscopic ablation crater images, plasma emission spectra, and plasma plume images. Measured plasma density using a Stark width of Al I (396.2 nm) showed a strong linear correlation with crater size, with a Pearson correlation coefficient (r) of 0.97. To understand the origin of this linear correlation, plasma temperature was estimated using Bremsstrahlung emission from 512 to 700 nm. The estimated plasma temperature and aspect ratio of the plasma plume were negatively correlated, having r = − 0.76. This negative correlation resulted from a laser-plasma interaction, which heated the plasma and increased its hydrodynamic length. The percentages of laser energy used for plasma heating ( E p / E L ) and Al foil ablation ( E Al / E L ) were estimated from plasma temperature. Increased E Al / E L , such as crater size, with increasing laser intensity, confirms that greater mass ablation is the fundamental reason for the strong linear correlation between crater size and plasma density. [ABSTRACT FROM AUTHOR]

The long-term storage performance of energetic multilayer nanofilms is of great significance for their applications. In this paper, it is proposed to add a 10 nm Cu barrier layer between Al/CuO composite films to increase their storage stability. The Al/CuO composite film and Al/Cu/CuO composite film were aged for 14 days in an environment with a relative humidity of 40% and a temperature of 71 °C. Scanning electron microscopy and differential scanning calorimetry were used to analyze the microstructure and thermodynamic properties of the energetic films before and after aging, and the electrical detonation performance and ignition ability of energy-containing semiconductor bridges were studied. The results indicate that after aging for 14 days in an environment with a relative humidity of 40% and a temperature of 71 °C, the Al layer of the Al/CuO composite film becomes thinner, the Al2O3 interface layer increases, and the heat release decreases. The interlayer microstructure of the Al/Cu/CuO energetic multilayer nanofilms did not change significantly, and the addition of a 10 nm Cu layer formed a low-temperature Al–Cu alloy, reducing the reaction initiation temperature from 626 to 570 °C. The critical ignition time and critical ignition energy of the Al/CuO-energetic semiconductor bridge (ESCB) increased, the flame duration shortened from 440 to 300 μs, the flame size decreased by 50%, the plasma temperature decreased, and aging had no significant effect on the electrical explosion performance of Al/Cu/CuO-ESCB. After aging for 14 days in an environment with a relative humidity of 40% and a temperature of 71 °C, the maximum ignition gap of B/KNO3 for Al/CuO-ESCB decreased from 1.4 to 1.2 mm, while the maximum ignition gap for Al/Cu/CuO-ESCB remained at 1.6 mm, which significantly improved the ignition performance and long storage performance of the energetic semiconductor bridge. [ABSTRACT FROM AUTHOR]

Understanding the behavior of intrinsic defects and helium (He) in tungsten oxides is useful for the application of tungsten (W) in a fusion environment because of the oxidation of W surfaces. The formation and diffusion energies of intrinsic defects and He in monoclinic γ-WO3 have been investigated using first-principles density functional theory calculations. The formation energy and diffusion activation energy of O defects are lower than W defects. O vacancy prefers to diffuse along the ⟨ 001 ⟩ direction, then followed by ⟨ 010 ⟩ and ⟨ 100 ⟩ directions; however, the W vacancy is immobile at temperatures lower than 2000 K. The stability of Schottky defects (SDs) is sensitive to their geometry and orientation. W interstitials prefer to move along the [100] direction, while O interstitials jump around W atoms rather than through the W quasi-cubic centers. He interstitial atoms are predicted to have a high solubility and an anisotropic diffusion mechanism in γ-WO3. In addition, the effect of biaxial strain on the solubility and diffusivity of He interstitials was investigated. He interstitials prefer to reside at individual sites rather than clusters. He atoms are weakly trapped by single vacancies or SDs. Vacancies assist the local migration of nearby He. Correspondingly, He self-clustering and bubble formation are less likely to form in γ-WO3 relative to bcc W. The energetics obtained in this work can be used to predict the microstructure evolution of the WO3 layer on a W substrate exposed to He plasmas at different temperatures. [ABSTRACT FROM AUTHOR]

Spherical powders are required for many advanced manufacturing techniques due to their inherent requirement of flowability, either within feed tubes or during powder spreading. As advanced manufacturing of magnets continues to develop, new production methods for feedstocks are also sought. Plasma spheroidization is a high-yield method to produce spherical Nd–Fe–B powders from irregularly shaped particles, with advantages including high throughput and a well-controlled size distribution. Highly spherical Nd–Fe–B powders with large scale production (i.e., kg) have been demonstrated using an inductively coupled thermal plasma system; however, the magnetic properties of the output powder display significant degradation. The coercivity was decreased from the initial 8 kOe (636 kA/m) of the as-received to 0.7 kOe (55 kA/m) for spheroidized powders. Microstructural investigation reveals 6% Nd depletion caused by the extreme temperatures of the plasma, leading to the formation of low-coercivity α-Fe and a subsequent decrease in energy product. Post-spheroidization heat treatments with Nd can partially mitigate the coercivity degradation, increasing to 1.7 kOe (135 kA/m), potentially offering a pathway toward spherical powders for a range of applications. [ABSTRACT FROM AUTHOR]

The described method is intended for application as a diagnostic tool for a nonstationary, short-lived plasma (in particular, for the laser-produced plasma). It is based on taking into account the lifetime of a laser-produced plasma, which is so short (several nanoseconds) that it is not enough for the ionization equilibrium to be established. Among mechanisms leading to appearance of an ion with a given charge Z in the plasma, only the electron-collisional ionization is considered, because contributions of other phenomena turn out to be negligible. The method is discussed as an example of a plasma excited on the Xe gas-jet target. The necessary collisional cross sections of ions from+7Xe to+16Xe have been calculated specifically for this study using a quantum-mechanical numerical simulation, with its principles and features being also presented in the paper. To demonstrate capabilities of the method, it has been applied to one of the experimental cases when the plasma was produced by the laser beam focused on the Xe gas-jet target. The time-integrated energy of laser radiation absorbed in the plasma was measured, and the absorption coefficient, μ, was derived from it with a correction for the plasma lifetime, which was several times shorter than the laser pulse. Using the method described here, the values of ⟨ Z ⟩ and then μ were calculated as a function of temperature. The time-averaged plasma temperature, T, in the above-mentioned experiment was believed to be equal to that at which the calculated and experimentally determined values of μ coincided. The following results were obtained: T = 42 eV, ⟨ Z ⟩ = 10.2. [ABSTRACT FROM AUTHOR]

This study explores the effects of chamber pressure on the electrical and thermodynamic characteristics of a low-pressure thermal plasma jet. The investigation focuses on current–voltage characteristics, arc voltage fluctuations, plasma jet temperature, electron density, and velocity within the range of 100–500 A arc current, at chamber pressures of 100 Pa, 1 kPa, and 3 kPa. Spectral analysis of the arc voltage reveals the presence of distinct frequencies, including restrike, Helmholtz, and acoustic modes, which exhibit varying behavior under different chamber pressure conditions. Restrike frequency shows an increase with decreasing chamber pressure, while Helmholtz frequency remains unaffected, and the power density of the acoustic frequency diminishes, eventually disappearing from the spectrum. The transition of the plasma jet from a continuum regime to a frozen state with decreasing chamber pressure is observed along with its shock structures. Optical emission spectroscopy is utilized to map the excitation temperature and electron density profile along the jet axis, demonstrating that the jet temperature and density peaks at the compression zone. Furthermore, Mach probe measurements of the plasma jet velocity at different axial locations, under various chamber pressure conditions, illustrate that the plasma jet maintains a supersonic state, regardless of chamber pressure. However, after the formation of a Mach disk, the jet velocity becomes subsonic. The highest velocity is achieved at 100 Pa chamber pressure, reaching Mach 2.9 at 50 mm from the anode exit. This research enhances our understanding of thermal plasma jets under low-pressure conditions, contributing to the advancement of knowledge in their applications across various domains. [ABSTRACT FROM AUTHOR]

This paper is devoted to the experimental study of the characteristics of a continuous optical discharge (COD) sustained by high power continuous wave laser radiation at a wavelength λ = 1.08 μ m in high pressure argon. New data on the COD threshold laser power dependence of argon pressure in the range 20–50 bar is obtained. The COD threshold laser power is shown to be in good agreement with the data obtained by other authors and theoretical evaluations provided the contribution of plasma energy loss due to thermal radiation is taken into account properly. The maximum plasma temperature was estimated to be 20–21 kk or higher, favorable to obtain high UV spectral radiance. A study of the convective plume oscillations around COD in argon has been carried out. It is found that in the pressure range 25–35 bars the growth of the laser radiation power leads to a decrease in convection oscillation frequency from 33 to 29 Hz, while the radius of the convective plume grows accordingly. The oscillation frequency ν and characteristic radius of the convective plume r 0 were found to obey the similarity relation ν = 0.5 g / 2 r 0 previously established in experiments with COD in xenon. These results are promising for using COD in argon as a high brightness broadband UV radiation source. [ABSTRACT FROM AUTHOR]

The impact of plasma temperature on the formation and evolution of distinct and unique molecular species recorded as molecular signatures from laser induced plasma (LIP) was examined in this study. A definitive correlation between plasma temperature and the formation of molecular species has been established through a comprehensive temporal analysis of BO and BO2 molecular bands. The utilization of the signal-to-envelope ratio diagrams allowed for pinpointing the optimal temperature range for molecule emission. Notably, the molecule BO exhibited an ideal temperature range of 10,000–11,000 K for the proper formation of molecular emission bands, while BO2 preferred temperatures between 8,000–9,000 K. These optimal temperature ranges remained consistent regardless of the laser irradiation wavelength or ambient gas conditions of Ar, air or He studied in this work. These key findings highlight the significant influence of plasma temperature in shaping the molecular species observed in LIP. [ABSTRACT FROM AUTHOR]

A model for fast electron-driven high-density plasma is proposed to describe the effect of injected fast electrons on the temperature and inner pressure of the plasma in the fast heating process of the double-cone ignition (DCI) scheme. Due to the collision of the two low-density plasmas, the density and volume of the high-density plasma vary. Therefore, the ignition temperature and energy requirement of the high-density plasma vary at different moments, and the required energy for hot electrons to heat the plasma also changes. In practical experiments, the energy input of hot electrons needs to be considered. To reduce the energy input of hot electrons, the optimal moment and the shortest time for injecting hot electrons with minimum energy are analyzed. In this paper, it is proposed to inject hot electrons for a short time to heat the high-density plasma to a relatively high temperature. Then, the alpha particles with the high heating rate and P d V work heat the plasma to the ignition temperature, further reducing the energy required to inject hot electrons. The study of the injection time of fast electrons can reduce the energy requirement of fast electrons for the high-density plasma and increase the probability of successful ignition of the high-density plasma. [ABSTRACT FROM AUTHOR]

An understanding of the behaviour of the D or He fuel used in tokamak discharges is essential in analyses such as modelling edge and divertor transport and the erosion of the vessel walls. However, poor agreement is found between measurements made on the JET tokamak and collisional-radiative models used to predict the hydrogen-like D and He line intensities. The range of temperatures of the plasmas emitting the radiation is also limited, in contrast to that for many impurities for which a wide range is possible. This is particularly so for He II whose line intensities tend to have the same near-constant ratios in most pulses, suggesting that the emission originates in plasma regions with very similar electron temperatures. To gain understanding and to allow quantitative comparisons with theoretical models, extensive observations of the VUV Lyman series have been made, for all discharge scenarios run during three He campaigns. Those for He discharges in both JET ITER-like wall (JET-ILW) and JET C (JET-C) campaigns are presented here. He discharges have the advantage of fewer impurities resulting in less complex spectra than when D is used as the fuel. However, the characteristics of the observed discrepancies are similar in both species, allowing He to be used as a proxy for D in order to gain understanding of the discrepancy. In addition, the study of He avoids the complication of molecular species contributing to the level populations. Opacity effects are also expected to be less severe in He discharges. Nevertheless, so as to ensure that the measurements are not unduly affected by opacity, comparisons have also been made with emission from Balmer and Paschen series members. Measurements of both line intensities and their ratios are presented for all-pulse surveys and for individual pulses. In exceptional cases in which the He emission is intense a dependence on the He II line intensity is demonstrated. The discrepancy between these measurements and the theoretical models is illustrated. [ABSTRACT FROM AUTHOR]

A possibility of studying effects of the main background ions formed by the main elements of inductively coupled plasma (H, N, O, and Ar) at the working parameters of the normal ("hot") plasma mode by thermodynamic modeling is assessed. Such ions, responsible for the strongest spectral interferences in the mass spectra are always observed upon the injection of aqueous ("wet") sample solutions into inductively coupled plasma mass spectrometers (ICP MS). The quantitative composition of the main background ions in an ICP MS is calculated as a function of plasma temperature in the temperature range from 3000 to 8000 K using thermodynamic modeling. The results of modeling were compared with the experimental data on the measured mass spectra of the main background ions and a high degree of correlation between the theoretical and experimental results was shown. The agreement between the results of calculations the experimental data validates the thermodynamic model of thermochemical processes in an ICP MS used and its applicability to subsequent calculations in fulfilling analytical tasks. A possibility of the unambiguous assessment of gas-kinetic plasma temperature is confirmed by comparing the theoretical and experimental mass spectra of the main ICP background ions in a normal mode. It was found that the calculated and experimental data on the concentration of only NO+ ions do not agree with the regularities noticed for the other background ions in the normal ICP mode. [ABSTRACT FROM AUTHOR]

ABSTRACT In this research, animal samples were subjected to skin rejuvenation using the floating electrode dielectric barrier discharge plasma device. Plasma processing was performed on the dorsal area of the rat's neck, covering a surface area of 18 cm2. Biometric assessments, encompassing measurements of skin surface evaporation, moisture content, melanin and erythema levels, as well as skin firmness and elasticity, were conducted before treatment initiation, immediately posttreatment, at the 4th and the 10th week during the follow‐up period. Physical examinations were employed to investigate and record the active species generated by plasma as well as the temperature of the skin surface. The skin ultrasound device was utilized to assess the density and thickness of both the epidermis and dermis. [ABSTRACT FROM AUTHOR]

In this investigation, a spectroscopic optical emission test was used to investigate the characteristics of gold plasmas that were produced in the surrounding environment using an Nd: YAG system at a wavelength of 1064 nm and had an energy output that varied from 400 to 600 mJ. The emission spectrum profiles of (Au) were analyzed and recorded using a spectrometer to aid in the extraction of vital plasma features (i.e., T e and n e ). Plasma temperature was determined using the Boltzmann plot method, and electron density was determined using the Stark broadening method. The temperature was between (0.91 and 0.94) eV, while the electron density ranged between (4.79 and 5.26) × 1 0 1 7 cm − 3 . The rest of the plasma parameters were calculated by the mathematical equations of the method used (Boltzmann Plott). [ABSTRACT FROM AUTHOR]

Flow ultrasound generators are devices that emit high-frequency sound waves due to the hydrodynamic instability of the supersonic flow. In the electric power industry, such generators are used in arc quenching systems of high-voltage gas blast circuit breakers. The design of the flow ultrasound generator includes a nozzle and a hollow cylindrical resonator. Self-oscillations of the sealing waves occur when a supersonic gas jet collides with a resonator. This article is devoted to the analysis of the arrester operation, which has design features of flow ultrasound generators. The paper includes both experimental investigations of the proposed spark gap arrester design and mathematical modeling of the processes occurring in it. A description of the methods used is presented, and a comparison of the time dependences of currents and voltages obtained as a result of experimental studies and as a result of calculations is performed in the next section. The calculation results include oscillograms of the voltage and current, and the plasma temperature distribution in the arrester chamber at different moments of time. The investigations show that the presence of a nozzle and resonator leads to an intensification of the gas dynamic effect on the electric arc. [ABSTRACT FROM AUTHOR]

The poor spectral stability of laser-induced breakdown spectroscopy (LIBS) seriously affects its analytical performance, which is a key obstacle to its further development. To overcome this challenge, an improved spectral standardization method based on plasma image-spectrum fusion (ISS-PISF) was proposed in this study. This method, for the first time, considers and quantifies the influence of plasma morphology on spectral intensity based on the line-integrated intensity formula of LIBS spectra. It recognizes that the spectral fluctuations mainly stem from variations in total number density, plasma temperature, electron number density, and plasma morphology. Therefore, ISS-PISF innovatively utilizes easily accessible features from plasma images and spectra to eliminate the influence of these four plasma parameters, thereby improving the spectral stability and analytical performance of LIBS. To validate the effectiveness of this method, the spectra of aluminum alloy samples obtained under complex detection conditions simulated by varying laser energy and defocusing amount were analyzed. After correction by ISS-PISF, the R2 for Mg I 516.73 nm, Mn II 294.92 nm, and Si I 288.16 nm improved to 0.990, 0.976, and 0.961, and the average RMSE of the validation set decreased by 46.154%, while the average STD of the validation set decreased by 37.405%. These experimental results indicate that this study provides a simple, effective, and physically supported spectral standardization method, which contributes to the further promotion and application of LIBS. [ABSTRACT FROM AUTHOR]

The high‐density transient plasma, streaming from a pulsed plasma accelerator (PPA), was diagnosed with a Triple Langmuir probe (TLP) for spatial mapping of the stream in terms of plasma density and temperature. A contour plot for density and temperature shows a distinct form of a highly dense island of plasma with varied plasma temperatures. The formation of such highly dense islands can be correlated with the formation of distinct plasma structures, as observed in astrophysical plasmas and fusion plasma. The results of TLP were supported by the intensity variation derived from signals of a photodetector system. The plasma stream imaged with high‐speed video camera also showed the density fluctuation inside the plasma stream. The estimated maximum density and temperature were ∼7.2 × 1020 m−3 and ∼28 eV, respectively. [ABSTRACT FROM AUTHOR]

In this study, we have investigated the relationship between the plasma temperature in remote laser-induced breakdown spectroscopy (LIBS) experiments and the hydrophobic properties of silicone rubber insulators (SIRs). Contact angle and LIBS measurements were conducted on both artificially-aged (accelerated aging) and field-aged SIRs. This study reveals a clear connection between plasma temperature and the properties of aged SIRs on artificially-aged SIR specimens. Specifically, the plasma temperature exhibits a consistent increase with the duration of the accelerated aging test. The hydrophobicity of the artificially-aged SIRs was assessed by performing contact angle measurements, revealing a decrease in the hydrophobicity with increased aging test duration. Furthermore, we extended our investigation to the study of nine field-aged SIRs that had been in use on 150 kV overhead transmission lines for 0 to 21 years. We find that the laser absorption and hardness of the material do not relate to the plasma temperature. In summary, we observe a direct connection of plasma temperature to both contact-angle measurements and operation time of the in-service insulators. These results strongly suggest the potential use of LIBS for remotely evaluating the hydrophobicity and aging degree of silicone rubber insulators, thus assessing their real-time on-site operational quality. [ABSTRACT FROM AUTHOR]

One of the most significant medicinal plants used to treat numerous illnesses is Swertia chirayita. The present study demonstrated the compositional analysis of the Swertia chirayita (S. chirayita) plant using an emerging and non-destructive laser-induced breakdown spectroscopy (LIBS) technique. Mg, Ca, K, Fe, Sr, Cr, and Na were verified as necessary elements by the optical emission investigations, while Al, Ti, Si, Ba, Mn, and Li were non-essential. Using the Boltzmann plot technique with stark broadening parameters, plasma temperature and electron number density were calculated in the range of (10,000–12,000) K ±1000 K and (1.5–1.8) × 1017 cm-3, respectively. Finally, compositional analysis was carried out using calibration-free (CF-LIBS) analysis and results were compared with ICP-MS. It was observed that the concentration of Ca and Fe is higher than other detected elements. All the toxic elements are found to be within the safe limit. So, this medicinal plant can be used to cure a variety of diseases that arise due to the deficiency of these elements. [ABSTRACT FROM AUTHOR]

• The effect of temperature on plasma gasification of CPMW is explored experimentally. • A temperature of 1800 °C provides the optimum performance for air-CPMW gasification. • The volume fraction of H 2 and CO increases with the increased reactor temperature. Plasma gasification melting (PGM) provides reliable disposal of toxic medical waste with a low heating value, which is capable of converting waste into energy. This study investigates the performance of experiments on plasma gasification for the treatment of chemical-pharmaceutical medical waste (CPMW) with an air medium. A comparative analysis is performed for gasification characteristics at three reactor temperatures (1000, 1400, and 1800 °C). Moreover, a thermodynamic equilibrium model is developed to assess performance features such as syngas yield, high heating value, and cold gas efficiency in the gasification temperature range of 1000–1800 °C. A comparison of the experiment and computational outcomes shows a good agreement. The results show that the quality of syngas and heating value is improved by increasing the temperature of the plasma gasifier so that at 1800 °C, H 2 , CO, and higher heating value (HHV) are obtained as 41 %, 37 %, and 10 MJ/Nm3, respectively. The obtained syngas is a clean fuel with low sulfur-containing and nitrogen-containing. The experimental results provide an extensive comprehension of CPMW gasification in a plasma reactor and consider a possibility for hydrogen and energy production. [ABSTRACT FROM AUTHOR]

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AbstractThe accuracy of quantitative analysis in soil laser-induced breakdown spectroscopy (LIBS) is frequently compromised by self-absorption. Eliminating this influence is imperative for attaining reliable results. To mitigate the impact of self-absorption upon the determination of Cr in soil, a novel correction model based upon plasma temperature (SAT) is reported grounded in column density-Saha-Boltzmann (CD-SB) theory. This approach calculates plasma temperature using self-absorption spectra, thereby providing a foundation for line intensity calibration. Initially, the electron number density was determined using the full width at half maximum (FWHM) of the Hα 656.27 nm line. Subsequently, the column density of particles at lower energy levels and the plasma temperature were ascertained. Finally, a multi-line method was employed to correct for self-absorption. In comparison to the LIBS calibration curve procedure, the SAT model effectively rectifies self-absorption in the analysis of soil by significantly enhancing the linear determination coefficients (R2) of the Cr I 425.43 nm and Cr I 427.48 nm lines from 0.9569 and 0.9578 to 0.9869 and 0.9819, respectively. The model also reduces the exponential self-absorption factors by 2.1806 and 0.9919, respectively. The results demonstrate that the SAT model effectively rectifies self-absorption, thereby enhancing the accuracy for the quantitative analysis of soil. [ABSTRACT FROM AUTHOR]

The magnetospheric plasma (hot and thin) and the solar wind plasma (cold and dense) are separated by the Earth's magnetopause, in which plasmas of both origins coexist. Different types of plasma diffusions are found due to this plasma mixing, and kinetic Alfvén solitary waves (KASWs) are one of them. In this work, a theoretical approach is taken to study the fundamental properties of heavy ion acoustic KASWs (HIAKASWs) in a magnetized plasma system whose constituents are nonextensive q-distributed two temperature electrons with dynamical heavy ions. The perturbations of the magnetized collisionless plasma system are investigated using the reductive perturbation technique to deduce the Korteweg–de Vries (K–DV) and modified K–DV (MK–DV) equations to determine the fundamental characteristics of small, but finite amplitude HIAKASWs. The presence of nonextensive electrons, magnetic field, obliquity angle (the angle between the external magnetic field and wave propagation), plasma particle number densities, and the temperature of various plasma species are observed to significantly alter the fundamental properties of HIAKASWs. The findings of our present study may be useful for comprehending the nonlinear wave properties in diverse interstellar plasma environments. [ABSTRACT FROM AUTHOR]

We investigate the dynamics of plasma-based acceleration processes with collisionless particle dynamics and non-negligible thermal effects. We aim at assessing the applicability of fluid-like models, obtained by suitable closure assumptions applied to the relativistic kinetic equations, thus not suffering from statistical noise, even in the presence of a finite temperature. The work here presented focuses on the characterization of pressure anisotropies, which crucially depend on the adopted closure scheme, and hence are useful to discern the appropriate thermal fluid model. To this aim, simulation results of spatially resolved fluid models with different thermal closure assumptions are compared with the results of particle-in-cell simulations at changing temperature and amplitude of plasma oscillations. [ABSTRACT FROM AUTHOR]

Considering the effects of non-Maxwellian distributed electrons and the generation of magnetic field on the inertial confinement fusion driven by laser, the quasi-static magnetic field generated by nonlinear magnetization current in laser plasma with super-Gaussian distributed electrons is studied. Based on the kinetic theory, an analytical expression for the spontaneous magnetic field in Fourier space, valid for arbitrary frequencies, has been obtained. According to the existing experimental data, the effects of the frequency, plasma temperature, and super-Gaussian index on the spontaneous magnetic field are analyzed through numerical calculations. It is shown that the strength of the spontaneous magnetic field first decreases and then increases with the increase in the super-Gaussian index when the laser intensity is ∼ 10 12 W / cm 2 . It is about the order of 100 G, which is much smaller than the experimental observation. When the laser intensity is ∼ 10 16 W / cm 2 , the strength of the spontaneous magnetic field increases monotonically with the super-Gaussian index in the low-frequency region, and behaves similarly to the one of the laser intensity ∼ 10 12 W / cm 2 in the high-frequency region. It will be as large as megagauss, which is consistent with the experimental observation results. Moreover, the strength of the spontaneous magnetic field increases with the increase in frequency and the decrease in the electron temperature. [ABSTRACT FROM AUTHOR]

Singly charged background argide ions ArH+, ArN+, ArO+, and Ar2+ create strong spectral interferences in elemental and isotopic analysis by inductively coupled plasma mass spectrometry (ICP MS). In this study, we experimentally investigated the behavior of these ions depending on variations in high-frequency plasma power and argon carrier gas flow rate. Theoretical analysis was performed using thermodynamic modeling to predict the behavior of these argide ions on changes in plasma temperature and argon flow rate. Common patterns in the intensity of these major background ions and changes in their formation efficiency at different working parameters of the ICP are noted. A good agreement between the observed experimental dependences and those derived from thermodynamic models is noted. [ABSTRACT FROM AUTHOR]

In this research, the finite-element numerical software COMSOL Multiphysics is used to simulate the electric pulse rock-breaking process, and the novel numerical model takes into account the multiple fields of electrical, thermal, and mechanical physics. The electric field strength inside the rock under the action of the electric pulse is updated by the full coupling function of COMSOL (version 6.1) software, and the electric damage variable χ is used to describe the process of electric breakdown inside the rock, to simulate the formation of plasma channel in the process of electric pulse rock-breaking. The voltage change curves and plasma channel trajectories in the electric breakdown process of the model in this paper are compared with the literature to verify the accuracy of the model. The formation process of plasma channels captures the temperature and stress changes during the whole process of electric pulse rock-breaking, to reveal the mechanism of the electric pulse rock-breaking process. With the presence of conductive particles inside the rock, the particles can effectively promote the formation of plasma channels, increase the area of electrical damage, and improve rock-breaking efficiency. Before the formation of the plasma channel, the internal temperature of the rock is about 600 K, and the stress is about 10−2 MPa; when the channel is formed, the energy of the electric pulse is mainly concentrated in the plasma channel, and the temperature of the plasma channel rises to 104 K. When the maximum stress exceeds the critical stress of the rock, the rock undergoes fracture. Furthermore, an appropriate increase in the rise time of the electric pulse increases the speed and area of rock-breaking, subsequently improving the efficiency of rock fracture. The results of the numerical modeling in this paper help to better understand the mechanism of the electric pulse rock-breaking process, which is of great engineering significance for the development of new electric pulse rock-breaking technology in the realm of geotechnical engineering. [ABSTRACT FROM AUTHOR]

This work explores microcombustion technologies enhanced by plasma-assisted combustion, focusing on a novel simulation model for a Y-shaped device with a non-premixed hydrogen-air mixture. The simulation integrates the ZDPlasKin toolbox to determine plasma-produced species concentrations to Particle-In-Cell with Monte Carlo Collision analysis for momentum and power density effects. The study details an FE-DBD plasma actuator operating under a sinusoidal voltage from 150 to 325 V peak-to-peak and a 162.5 V DC bias. At potentials below 250 V, no hydrogen dissociation occurs. The equivalence ratio fitting curve for radical species is incorporated into the plasma domain, ensuring local composition accuracy. Among the main radical species produced, H reaches a maximum mass fraction of 8% and OH reaches 1%. For an equivalence ratio of 0.5, the maximum temperature reached 2238 K due to kinetic and joule heating contributions. With plasma actuation with radicals in play, the temperature increased to 2832 K, and with complete plasma actuation, it further rose to 2918.45 K. Without plasma actuation, the temperature remained at 300 K, reflecting ambient conditions and no combustion phenomena. At lower equivalence ratios, temperatures in the plasma area consistently remained around 2900 K. With reduced thermal power, the flame region decreased, and at Φ = 0.1, the hot region was confined primarily to the plasma area, indicating a potential blow-off limit. The model aligns with experimental data and introduces relevant functionalities for modeling plasma interactions within microcombustors, providing a foundation for future validation and numerical models in plasma-assisted microcombustion applications. [ABSTRACT FROM AUTHOR]

There is a lack of information about transforming growth factor beta-1 (TGF-β1) and cytokines contained in pure platelet-rich plasma (P-PRP) and release from pure-platelet-rich gel supernatants (P-PRGS) might be affected by the temperature and time factors; P-PRP from 6 heifers was activated with calcium gluconate. Thereafter, P-PRG and their supernatants (P-PRGS) were maintained at −80, −20, 4, 21, and 37 °C and collected at 3, 6, 12, 24, 48, 96, 144, 192, 240, and 280 h for subsequent determination of TGF-β1, tumor necrosis factor alfa (TNF-α), interleukin (IL)-2, and IL-6; TGF-β1 concentrations were significantly (p < 0.05) higher in PRGS maintained at 21 and 37 °C when compared to PRGS maintained at 4, −20, and −80 °C; PRGS TNF-α concentrations were not influenced by temperature and time factors. However, PRGS maintained at 4 °C showed significantly (p < 0.05) higher concentrations when compared to PRGS maintained at −20, and −80 °C at 144, and 192 h. IL-6 concentrations were significantly (p < 0.05) higher in PRGS stored at −20, and −80 over the first 48 h and at 10 days when compared to PRGS stored at 4, 21, and 37 °C. These results could suggest that P-PRP/P-PRGS could be maintained and well preserved for at least 12 days at room temperature for clinical use in bovine therapeutic massive protocols. [ABSTRACT FROM AUTHOR]

A computationally efficient model is proposed to analyze plasma-assisted combustion using nanosecond repetitive pulsed (NRP) plasmas. The NRP plasma discharge is placed in the oxidizer stream of a counter-flow diffusion flame. The effect of changing the flow rate and the pulse repetition frequency (PRF) of a continuous NRP plasma discharge on the temperature and species profiles of a counter-flow diffusion flame is investigated numerically. The results confirm that oxygen atom and nitrogen vibrational states are the most important species to enhance combustion. The results also show that kinetic effects are much more significant for higher PRF and lower pulse voltage. In addition, when steady plasma profiles are used instead of unsteady plasma profiles, the extinction strain rates increase by 25.8%, 21.1%, and 10.8% for PRF equal to 1, 2, and 4 kHz, respectively. [ABSTRACT FROM AUTHOR]

Plasma‐based CO2 conversion has attracted increasing interest. However, to understand the impact of plasma operation on post‐plasma processes, we studied the effect of adding N2, N2/CH4 and N2/CH4/H2O to a CO2 gliding arc plasmatron (GAP) to obtain valuable insights into their impact on exhaust stream composition and temperature, which will serve as feed gas and heat for post‐plasma catalysis (PPC). Adding N2 improves the CO2 conversion from 4 % to 13 %, and CH4 addition further promotes it to 44 %, and even to 61 % at lower gas flow rate (6 L/min), allowing a higher yield of CO and hydrogen for PPC. The addition of H2O, however, reduces the CO2 conversion from 55 % to 22 %, but it also lowers the energy cost, from 5.8 to 3 kJ/L. Regarding the temperature at 4.9 cm post‐plasma, N2 addition increases the temperature, while the CO2/CH4 ratio has no significant effect on temperature. We also calculated the temperature distribution with computational fluid dynamics simulations. The obtained temperature profiles (both experimental and calculated) show a decreasing trend with distance to the exhaust and provide insights in where to position a PPC bed. [ABSTRACT FROM AUTHOR]

The paper presents the results of the study of tungsten surface structure modification under helium plasma irradiation. It is revealed that during irradiation of samples, surface modification in the form of relief development as a result of irradiation is observed. X‐ray phase analysis showed that no new phases of the W system were found after irradiation, only an increase in the intensity of diffraction lines was observed. There are significant differences in the microstructure of tungsten depending on the temperature of helium plasma irradiation in the above range. It is assumed that the cause of defects is the extremely low solubility of helium in tungsten. Metallographic analysis has shown that at irradiation of tungsten samples in time modes 1 and 1.5 hours, the degree of relief development is not high in comparison with the tungsten sample irradiated in the 0.5‐hour mode. The greatest increase in surface roughness of the sample irradiated for 1 hour was registered, which is associated with the formation of small cracks, bubbles, and pores in the surface layer. At the same time, in the samples irradiated for 1.5 hours, the surface of which is characterized by chaotically located protrusions and depressions of various shapes, the roughness parameter Ra was 0.0603 μm. It was found that at temperature regimes T = 1200°C and T = 1500°C, the microhardness of tungsten increases by 10% and 11%, respectively. [ABSTRACT FROM AUTHOR]

Immunodetection of cardiac isoforms of troponin I (cTnI) and troponin T (cTnT) in blood samples is widely used for the diagnosis of acute myocardial infarction. The cardiac troponin complex (ITC-complex), comprising cTnI, cTnT, and troponin C (TnC), makes up a large portion of troponins released into the bloodstream after the necrosis of cardiomyocytes. However, the stability of the ITC-complex has not been fully investigated. This study aimed to investigate the stability of the ITC-complex in blood samples. A native ITC-complex was incubated in buffer solutions, serum, and citrate, heparin, or EDTA plasma at various temperatures. Western blotting and gel filtration were performed, and troponins were detected using specific monoclonal antibodies. The ITC-complex dissociated at 37 °C in buffers with or without anticoagulants, in citrate, heparin, and EDTA plasmas, and in serum, into a binary cTnI-TnC complex (IC-complex) and free cTnT. In plasma containing heparin and EDTA, the IC-complex further dissociated into free TnC and cTnI. No dissociation was found at 4 °C or at room temperature (RT) in all matrices within 24 h except for EDTA plasma. After incubation at 37 °C in EDTA plasma and serum, dissociation was accompanied by proteolytic degradation of both cTnI and cTnT. The presence of anti-troponin autoantibodies in the sample impeded dissociation of the ITC-complex. The ITC-complex dissociates in vitro to form the IC-complex and free cTnT at 37 °C but is mostly stable at 4 °C or RT. Further dissociation of the IC-complex occurs at 37 °C in plasmas containing heparin and EDTA. [ABSTRACT FROM AUTHOR]

The article describes modern methods for controlling and optimizing the energy mode of melting in electric arc furnaces and units for out-of-furnace steel processing using optical emission spectroscopy systems. These systems enable the determination of melt and slag temperatures, plasma temperatures in the arc combustion area, and slag composition, as well as the analysis of emission intensity from the melt and slag surfaces. The analysis revealed that depending on the range of steel to be smelted and the peculiarities of smelting technology at a particular electric arc steel-making furnace, control systems for smelting monitoring can be developed according to the obtained indicators of one or a combination of the abovementioned parameters. [ABSTRACT FROM AUTHOR]

Intense laser pulses can be employed to generate plasma, carbon aggregates, and nanoparticles. The plasma produced by ns laser pulses impinging on carbon targets in a vacuum generates carbon vapors, atoms nucleation and growth of nano aggregates. Mass quadrupole spectrometry has permitted to analyze the mass of the carbon atoms and molecules produced in a vacuum by laser-generated plasma, discovering that the fullerene C20 and other small carbon aggregates have a high probability of being produced. In this paper, the conditions of C20 aggregate synthetization are presented, and their yield generation is approximately evaluated. It also calculated the process ablation yield, the maximum carbon energy acquired in the plasma, the plasma temperature and density, the adiabatic plasma expansion velocity, and the carbon ion charge state distributions. To this, measurements of time-of-flight (TOF) of ions have been performed using suitable ion collectors and ion energy analyzers. [ABSTRACT FROM AUTHOR]

The study considers a possibility of studying the manifestation of the major background ions derived from the main elements (H, N, O, and Ar) of inductively coupled plasma under low-temperature ("cold") plasma conditions through thermodynamic simulation. These ions, known to induce significant spectral interferences, are always observed when aqueous samples are injected into inductively coupled plasma mass spectrometers (ICP–MS). Using thermodynamic simulation in the temperature range from 2000 to 5000 K, the quantitative composition of the major background ions in ICP–MS was determined as a function of plasma temperature. A comparison of the theoretical calculations and experimental data from mass spectral measurements of the major background ions was conducted, revealing a high degree of correlation between the two sets of the results. This agreement between the calculations and experiments confirms the validity of the thermodynamic model used for thermochemical processes in ICP–MS and its applicability to subsequent calculations in addressing analytical challenges. Additionally, a method is proposed for the unambiguous evaluation of the gas kinetic temperature of the plasma, while simultaneously considering practically all major background ions. [ABSTRACT FROM AUTHOR]

This work presents a technique to obtain wavelength tuning for a fiber laser with a nonthermal plasma‐based temperature regulator system and a fiber Bragg grating (FBG). The plasma effect was generated in a dielectric barrier discharge (DBD) reactor filled with helium as the carrier gas for plasma generation. The temperature characterization of the DBD reactor had shown that the nonthermal heating mechanism of plasma could manipulate gas temperature from 25°C to around 145°C in ~10 min. By exploiting the rapid temperature change of plasma, the reflected wavelength of the FBG can be tuned accordingly. At a discharge voltage of 3 kV, the fiber laser was tuned within a range of 2 nm with 11.9 pm/°C tuning resolution. The fiber laser exhibits a thermally stable emission with very low shifting at a constant temperature value. [ABSTRACT FROM AUTHOR]

The Thermal Helium Beam (THB) is a diagnostic for simultaneously measuring the electron temperature and density profiles of the plasma edge and scrape off layer (SOL). It exploits the line ratio technique of selected He line intensities, emitted by He gas puffed inside the plasma, to locally estimate the plasma properties through a dedicated collisional radiative model (CRM). Standard THB diagnostics used in nuclear fusion devices measure three HeI emission lines: 667.8, 706.5, and 728.1 nm. For the RFP experiment RFX-mod2, a new THB is designed and tested for the first time at the TCV tokamak. It acquires an additional emission line at 501.6 nm, which is exploited to estimate the radiation re-absorption, which is not negligible in regions of large neutral He densities (leading to high re-absorption) and simultaneously low electron density and temperature (lack of other excitation channels). It affects the measurements most strongly at the far SOL, while the significance of re-absorption decreases as it approaches the separatrix. In this paper, plasma density and temperature profiles of the plasma edge at the outboard midplane of TCV, measured with this newly designed THB, are presented. For the first time, the effect of radiation re-absorption on the estimation of electron temperature and density profiles is experimentally measured in a tokamak using the 501 nm line emission intensity. Different CRMs are compared with and without radiation re-absorption, showing good agreement when re-absorption is included and demonstrating how it plays an important role in the far SOL, as expected. [ABSTRACT FROM AUTHOR]

OBJECTIVE: To assess the temperature stability of an autodefrost freezer commonly used in veterinary practices, whether the use of a Styrofoam cooler within the freezer provides temperature stability, and the ease of use of a remote monitoring system for the notification of temperature elevations. ANIMALS: None. METHODS: Temperature in the freezer and 2 Styrofoam coolers were assessed with remote monitoring thermometers every 15 minutes. Temperature values were monitored from October 11 to December 18, 2023 (for a 68-day period). Data analysis focused on temperatures for the freezer exceeding 0 °C and the elevations in temperatures within the coolers relative to the freezer. RESULTS: The freezer had an increase in temperature approximately every 16 hours. Over 68 days, the freezer had a temperature greater than 0 °C 27 times, representing 26 separate elevations. The Styrofoam coolers within the freezer never registered a temperature higher than -5 °C. Elevations in temperature within the freezer were larger in magnitude than temperature elevations within the coolers, which showed smaller-magnitude changes in temperature. [ABSTRACT FROM AUTHOR]

Titanium tetrachloride (TiCl4) is a well-known source of titanium (Ti) for the formation of titanium nitride (TiN) barrier material in the semiconductor interconnection process; however, the reaction of by-products with airborne molecules can cause unexpected pump trips and equipment breakdown from the by-product powder build-up. Plasma scrubbers are used to decompose by-products, but hydrogen chloride (HCl) and nitrogen oxides are produced during and after the process. The process mechanisms change when the temperature and applied power of the heat source change. In this paper, we study the influence of the reactor temperature and applied power to the heat source on the decomposition capacity of TiCl4 in a plasma pretreatment system (PPS). We examine the effect of the temperature and heat source power to understand the reaction mechanisms for the composition and decomposition of gaseous species with chemical reactions through simultaneous methods. We analyzed the system with computational fluid dynamics (CFD) and chemical kinetic simulation to investigate the changes of the system mechanism. Subsequently, we achieved results for the correlation between the temperature of the reactor, power applied to the heat source, composition and decomposition of species, and chemical reaction mechanisms. [ABSTRACT FROM AUTHOR]

An edge-confined single-species plasma will relax to create a potential energy hill that climbs from the boundary. This hill represents a potential well for species of the opposite sign and can be a means to confine the second species. With this ultimate application in mind, we have studied the relation between the plasma temperature, the number of confined particles, and the electrostatic potential well that forms in a fully non-neutral plasma of electrons in a trapping volume with an artificially structured boundary (ASB). An ASB is a structure that produces periodic short-range static electric and magnetic fields for confining a plasma. To perform a detailed analysis on this topic, simulations using a particle-in-cell code have been performed. By varying the configurational elements of the ASB, such as the bias on the boundary electrodes and the internal radius of the structure, coupled with a course thermalization process and a prescribed threshold for particle leakage, potential well values were determined for a range of plasma temperatures and confinement conditions. Maximum well depths were observed below a threshold plasma temperature in each configuration. This study gives insight into the limitations of primary particle confinement with this type of structure and optimal conditions for the formation of a potential well that might be utilized to confine a second species. [ABSTRACT FROM AUTHOR]

In the last decades, to improve the CAP treatment efficiency, its biological effects in combination with other physical modalities have widely investigated. However, the physical insight into most of supposed synergistic effects remained elusive. In this regard, the synergetic effect of cold plasma and magnetic field has been used for different applications, especially due to considerable synergistic in biological media reactivity. In the present paper, using a 420 mT N42 magnet, the effect of the perpendicular external static magnetic field (SMF) on the cold atmospheric pressure plasma (CAP) characteristics, such as electron temperature and density, is investigated based on the optical emission spectroscopy, utilizing the Boltzmann plot method, Saha-Boltzmann equation, and Specair software simulation. Results showed that the rotational and electronic excitational temperatures experienced 100 K and 550 K increases in the presence of SMF, respectively. In contrast, the vibrational and translational temperatures remained constant. Moreover, electron temperature was estimated as 1.04 eV in the absence of SMF and increased up to 1.24 eV in the presence of SMF. In addition, the Saha-Boltzmann equation illustrated that the electron density increased in the presence of the additional SMF. The results of the present study indicated that the magnetic field could be an assistant to the cold plasma effect, beneficial in medical applications due to modifications in plasma temperature and electron density. [ABSTRACT FROM AUTHOR]

In the present study, the objective is to examine the individual effect of varying the composition and SPS conditions on the final mechanical property (hardness) of alumina–zirconia (AZ) composites through their microstructural variations. To this end, AZ composites with varying zirconia (ZrO2) content are prepared vis-à-vis monolithic alumina (Al2O3) and zirconia (ZrO2) ceramics by spark plasma sintering (SPS). The microstructure evolution, phase formation, and hardness for the monolithic ceramics and AZ composites are systematically investigated and a correlation between them is established using various analytical modeling approaches. By altering the SPS temperature, significant variation in grain sizes were produced for the two monolithic ceramics and various AZ composites. In case of the latter, the size and volume fraction of secondary ZrO2 particles vary according to the composition, i.e., higher the ZrO2 content, coarser and numerous are the second phase particles. The monolithic ceramics exhibit comparatively lower hardness than the AZ composites at equivalent grain sizes. The hardness for the AZ composites and monolithic ceramics also vary marginally with the size of the matrix grains/crystallites. The variation in hardness is rather attributed to the volume fraction of the secondary ZrO2 phase in case of the AZ composites. Altogether, the AZ composite with a finer grain size and low volume fraction of secondary ZrO2 phase exhibits the highest hardness, while coarse-grained microstructure and high ZrO2 content contributes to significantly lower hardness. The present study thus emphasizes the synergistic roles of SPS temperature and composite compositions in dictating their microstructure and mechanical response. [ABSTRACT FROM AUTHOR]

The study of ion-acoustic solitons (IASs) in an unmagnetised collisionless plasma system having inertial fluid ions and two temperature hot as well as cold electrons obeying Cairns–Tsallis (CT) distribution is presented. Using reductive perturbation method, the KdV equation is derived. Further, introducing higher-order effects of nonlinearity and dispersion, a nonlinear KdV-type inhomogeneous equation is derived that supports the formation of dressed solitons. The combined effects of higher-order corrections and various plasma parameters are analysed on the characteristics of the different kinds of ion-acoustic solitons with implications to Saturn's magnetosphere. [ABSTRACT FROM AUTHOR]

In this paper, the dust acoustic wave is studied in conditions where the dust temperature is not constant. This model includes negatively charged dust particles and thermal ions. The reductive perturbation technique is used and the new point in this study is the nonuniformity of the plasma temperature. The nonconstancy of the temperature is entered as a first-order perturbation in the calculations, and finally the modified Korteweg–de Vries (mKdV) equation is derived. The solution of the modified KdV equation clarifies the change in soliton shape of the wave when it moves in the perturbation plasma. We show how the soliton wave undergoes deformation and amplitude reduction during propagation when it encounters a region with a different temperature. The output of this research can be effective to better understand the wave behavior in a real plasma with nonuniform temperature. [ABSTRACT FROM AUTHOR]

Oxygen vacancies and heteroatom doping play important role in oxygen reduction activity of metal oxides. Developing efficient modification method is one of the key issues in catalysts research. Room temperature plasma treatment, with the advantages of mild working conditions, no emissions and high efficiency, is a new catalyst modification method developed in recent years. In this work, hydrothermal synthesized α -MnO2 nanorods are treated in NH3 plasma at room temperature. In the reducing atmosphere, oxygen vacancies and N doping are achieved simultaneously on the surface. The NH3 plasma etched MnO2 demonstrate a significant enhanced oxygen reduction activity with half-wave potential of 0.84 V, limiting current density of 6.32 mA cm−2 and transferred electrons number of 3.9. The Mg–air battery with N-MnO2 display a maximum power density of 76.3 mW cm−2 as well as stable discharge performance. This work provides new ideas for preparing efficient and cost-effective method to boost the catalysts activity. [ABSTRACT FROM AUTHOR]

Ammonia (NH3) production is of global concern for today's food supply security and as future energy vector. Plasma technology can add to supply‐chain resilience of fertilizer production and improve the environmental profile using renewable energy; allowing distributed NH3 production. With the objective to provide process intensification of small‐capacity reactors for local supply, a novel micropyramid‐disk plasma reactor operated in micro‐arc mode was developed. NH3 was synthesized from N2, nitrogen, and H2, hydrogen over Ru/MCM‐41 catalyst at atmospheric pressure. The microplasma brings plasma and catalyst surface close together and intensifies the electric field. The arc plasma elevates temperature, 'nonthermal', releasing high‐energy free electrons, known to be effective in converting low‐reactive molecules. The study demonstrates that microplasma, with reduced electrode‐to‐electrode dimensions and a microstructured reaction environment, enhances the performance of the NH3 synthesis and opens novel process windows. This is detailed on the impact of feed ratio (N2/H2), applied voltage, frequency, electrode gap, and the flow distribution by which the gas is fed in. Optical emission spectroscopy (OES) was used to identify vibrationally and other excited species generated by the microplasma and confirms the catalyst is in symbiosis with the radicals. [ABSTRACT FROM AUTHOR]

The growth of chemical vapor deposition diamond in microwave plasma ignited in H2/CH4 gas mixture is investigated using a multiscale approach. The plasma composition and temperatures are determined as a function of the growth conditions using an axial one‐dimensional simulator. The growth process is then studied at the atomic scale using a kinetic Monte‐Carlo simulator developed for (1 0 0), (1 1 1), and (1 1 0) orientations. The calculated growth rates are then injected in a geometric model that predicts the final morphology of the crystal. The simulation of the growth on an etch pit shows that the time necessary to entirely fill the pit is around half an hour. The study of the growth on the three orientations reveals that the surface temperature and methane concentration influence the number, shape, and size of the islands when they appear. On the (1 0 0) surface, the formation of islands may be related to Stranski–Krastanov growth mode, whereas the (1 1 1) surface conducts to Frank–van der Merwe growth mode, and the (1 1 0) surface is governed by Volmer–Weber growth mode. [ABSTRACT FROM AUTHOR]

This paper focuses on the theoretical study of the burning rate of D-T fuel in Z-pinch devices with magneto-inertial confinement. The investigated nuclear fusion process involved fast laser ignition of a mixed D-T fuel contained in a capsule at a temperature of 10 keV, influenced by a strong electromagnetic field. The D-T, D-D, D-3He, 3He-3He, and T-T fusion reactions were employed in the calculations. Based on modern experimental fit data of nuclear fusion reaction rates, the particle and energy balance equations, along with their numerical solutions, were considered, utilizing the ion densities of charged particles such as protons, deuterium, tritium, 3He, and 4He ions. The plasma was in a hot, ultra-dense state, under the quasi-neutrality condition, with initial deuterium and tritium densities of 5 × 10 23 cm−3 and an electron density of 10 × 10 23 cm−3. The ion and electron temperatures were considered equal in this paper. The time dependencies of the ion densities, plasma temperature, energy yield from charged ions and neutrons, fusion power density, and bremsstrahlung radiation loss were investigated. [ABSTRACT FROM AUTHOR]

Calcium silicate ceramics were successfully prepared at various temperatures by spark plasma sintering technique (SPS) using two different compositions, and their morphological and structural characteristics were thoroughly analyzed and compared by scanning electron microscope, X‐ray diffraction, and apparent density measurements. The effect of the sintering method and temperature on microstructural properties has also been studied. The sintered samples prepared by SPS through a heat input of 800°C showed the highest densification as results 800°C was suggested as optimum sintering temperature. Different phases presented in pseudo‐wollastonite, wollastonite, and triclinic Ca3(SiO4)O have been observed in the case of 50C50C with lowest porosity ∼6%$\sim \;6\% $ and highest density 2.6 g/cm3, whereas the composition 10C90S resulted in a fully amorphous material presented in granular microstructure with density of 1.7 g/cm3. [ABSTRACT FROM AUTHOR]