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Fluctuations in energy gap and coupling constants between chromophores can play an important role in absorption and energy transfer across a collection of two-level systems. In photosynthesis, light-induced quantum coherence can affect the efficiency of energy transfer to the designated "trap" state. Theoretically, the interplay between fluctuations and coherence has been studied often, employing either a Markovian or a perturbative approximation. In this study, we depart from these approaches to incorporate memory effects by using Kubo's quantum stochastic Liouville equation. We introduce the effects of decay of the created excitation (to the ground state) on the desired propagation and trapping that provides a direction of flow of the excitation. In the presence of light-induced pumping, we establish a relation between the efficiency, the mean survival time, and the correlation decay time of the bath-induced fluctuations. A decrease in the steady-state coherence during the transition from the non-Markovian regime to the Markovian limit results in a decrease in efficiency. As in the well-known Haken–Strobl model, the ratio of the square of fluctuation strength to the rate plays a critical role in determining the mechanism of energy transfer and in shaping the characteristics of the efficiency profile. We recover a connection between the transfer flux and the imaginary part of coherences in both equilibrium and excited bath states, in both correlated and uncorrelated bath models. We uncover a non-monotonic dependence of efficiency on site energy heterogeneity for both correlated and uncorrelated bath models. [ABSTRACT FROM AUTHOR]

Understanding the dynamics of photoinduced processes in complex systems is crucial for the development of advanced energy-conversion materials. In this study, we investigate the nonadiabatic dynamics using time-convolution (TC) and time-convolutionless (TCL) quantum master equations (QMEs) based on treating electronic couplings as perturbation within the framework of multistate harmonic (MSH) models. The MSH model Hamiltonians are mapped from all-atom simulations such that all pairwise reorganization energies are consistently incorporated, leading to a heterogeneous environment that couples to the multiple electronic states differently. Our exploration encompasses the photoinduced charge transfer dynamics in organic photovoltaic carotenoid–porphyrin–C60 triad dissolved in liquid solution and the excitation energy transfer (EET) dynamics in photosynthetic Fenna–Matthews–Olson complexes. By systematically comparing the perturbative TC and TCL QME approaches with exact quantum-mechanical and various semiclassical approximate kernels, we demonstrate their efficacy and accuracy in capturing the essential features of photoinduced dynamics. Our calculations show that TC QMEs generally yield more accurate results than TCL QMEs, especially in EET, although both methods offer versatile approaches adaptable across different systems. In addition, we investigate various semiclassical approximations featuring the Wigner-transformed and classical nuclear densities as well as the governing dynamics during the quantum coherence period, highlighting the trade-off between accuracy and computational cost. This work provides valuable insights into the applicability and performance of TC and TCL QME approaches via the MSH model, offering guidance for realistic applications to condensed-phase systems on the atomistic level. [ABSTRACT FROM AUTHOR]

The electron–phonon scattering plays a crucial role in determining the electronic, transport, optical, and thermal properties of materials. Here, we employ a non-Markovian stochastic Schrödinger equation (NMSSE) in momentum space, together with ab initio calculations for energy bands and electron–phonon interactions, to reveal the phonon-mediated ultrafast hole relaxation dynamics in the valence bands of monolayer black phosphorus. Our numerical simulations show that the hole can initially remain in the high-energy valence bands for more than 100 fs due to the weak interband scatterings, and its energy relaxation follows single-exponential decay toward the valence band maximum after scattering into low-energy valence bands. The total relaxation time of holes is much longer than that of electrons in the conduction band. This suggests that harnessing the excess energy of holes may be more effective than that of electrons. Compared to the semiclassical Boltzmann equation based on a hopping model, the NMSSE highlights the persistence of quantum coherence for a long time, which significantly impacts the relaxation dynamics. These findings complement the understanding of hot carrier relaxation dynamics in two-dimensional materials and may offer novel insights into harnessing hole energy in photocatalysis. [ABSTRACT FROM AUTHOR]

The light-harvesting excitonic properties of poly(phenylene ethynylene) (PPE) extended dendrimers (tree-like π-conjugated macromolecules) involve a directional cascade of local excitation energy transfer (EET) processes occurring from the "leaves" (shortest branches) to the "trunk" (longest branch), which can be viewed from a vibronic perspective as a sequence of internal conversions occurring among a connected graph of nonadiabatically coupled locally excited electronic states via conical intersections. The smallest PPE building block that is able to exhibit EET, the asymmetrically meta-substituted PPE oligomer with one acetylenic bond on one side and two parallel ones on the other side (hence, 2-ring and 3-ring para-substituted pseudo-fragments), is a prototype and the focus of the present work. From linear-response time-dependent density functional theory electronic-structure calculations of the molecule as regards its first two nonadiabatically coupled, optically active, singlet excited states, we built a (1 + 2)-state-8-dimensional vibronic-coupling Hamiltonian model for running subsequent multiconfiguration time-dependent Hartree wavepacket relaxations and propagations, yielding both steady-state absorption and emission spectra as well as real-time dynamics. The EET process from the shortest branch to the longest one occurs quite efficiently (about 80% quantum yield) within the first 25 fs after light excitation and is mediated vibrationally through acetylenic and quinoidal bond-stretching modes together with a particular role given to the central-ring anti-quinoidal rock-bending mode. Electronic and vibrational energy relaxations, together with redistributions of quantum populations and coherences, are interpreted herein through the lens of a nonadiabatic perspective, showing some interesting segregation among the foremost photoactive degrees of freedom as regards spectroscopy and reactivity. [ABSTRACT FROM AUTHOR]

The nonequilibrium Fermi's golden rule (NE-FGR) approach is developed to simulate the electronic transitions between multiple excited states in complex condensed-phase systems described by the recently proposed multi-state harmonic (MSH) model Hamiltonian. The MSH models were constructed to faithfully capture the photoinduced charge transfer dynamics in a prototypical organic photovoltaic carotenoid-porphyrin-C60 molecular triad dissolved in tetrahydrofuran. A general expression of the fully quantum-mechanical NE-FGR rate coefficients for transitions between all pairs of states in the MSH model is obtained. Besides, the linearized semiclassical NE-FGR formula and a series of semiclassical approximations featuring Wigner and classical nuclear sampling choices and different dynamics during the quantum coherence period for the MSH model are derived. The current approach enables all the possible population transfer pathways between the excited states of the triad, in contrast to the previous applications that only addressed the donor-to-acceptor transition. Our simulations for two triad conformations serve as a demonstration for benchmarking different NE-FGR approximations and show that the difference between all levels of approximation is small for the current system, especially at room temperature. By comparing with nonadiabatic semiclassical dynamics, we observe similar timescales for the electronic population transfer predicted by NE-FGR. It is believed that the general formulation of NE-FGR for the MSH Hamiltonian enables a variety of applications in realistic systems. [ABSTRACT FROM AUTHOR]

In this paper, we investigate the time evolution of quantum coherence—the off-diagonal elements of the density matrix of a multistate quantum system—from the perspective of the Wigner–Moyal formalism. This approach provides an exact phase space representation of quantum mechanics. We consider the coherent evolution of nuclear wavepackets in a molecule with two electronic states. For harmonic potentials, the problem is analytically soluble for both a fully quantum mechanical description and a semiclassical description. We highlight the serious deficiencies of the semiclassical treatment of coherence for general systems and illustrate how even qualitative accuracy requires higher order terms in the Moyal expansion to be included. The model provides an experimentally relevant example of a molecular Schrödinger's cat state. The alive and dead cats of the exact two-state quantum evolution collapse into a "zombie" cat in the semiclassical limit—an averaged behavior, neither alive nor dead, leading to significant errors. The inclusion of the Moyal correction restores a faithful simultaneously alive and dead representation of the cat that is experimentally observable. [ABSTRACT FROM AUTHOR]

In this paper, we study the dynamical processes of quantum coherence and correlations for two central qubits system coupled with a transverse Ising spin chain. Suppose the initial state of quantum system is the Werner state and the initial state of environment is the ground state of spin chain, and the corresponding time evolution operator, decoherence factor and reduced density matrix are given. We deduce the analytical expressions of evolution of quantum coherence, entanglement and quantum discord. We find that when the spin chain undergoes quantum phase transition (QPT), the entanglement vanished at time t = t c , and the coherence and discord vanished when the decoherence factor decayed to zero. Besides, we also find that the environmental scale N, coupling strength g and parameter P of Werner state do not change the evolution rules of quantum correlation, but accelerate their decay rate with these parameters' increase. [ABSTRACT FROM AUTHOR]

This review focuses on the history and current state of the art optoelectronic applications of quantum dots involving light emission. We focus mainly on three areas of commercial, or potential commercial interest, including quantum dot light emitting devices (QLEDs, sometimes called QD-LEDs), lasing applications, and quantum computing applications. The main connection between these areas is the development of the science and engineering needed to achieve electrical excitation of the quantum dot in an optoelectronic device in order to achieve emission with characteristics particularly suited to the application in question. Due to the special physics of quantum dots, these materials are particularly well suited for both existing commercial applications, and potentially for future applications, such as single photon sources, spin cubits, or polarized emission. We conclude with an analysis of the future prospects for these exciting materials. Given 30 years of progress since the Nobel Prize winning work on monodisperse samples of QDs, our goal is to highlight the current start of the art, discuss the current issues for each technology, and suggest future goals for the next 30 years for quantum dot research. [ABSTRACT FROM AUTHOR]

The classical properties of thermal light fields were instrumental in shaping our early understanding of light. Before the invention of the laser, thermal light was used to investigate the wave-particle duality of light. The subsequent formulation of the quantum theory of electromagnetic radiation later confirmed the classical nature of thermal light fields. Here, we fragment a pseudothermal field into its multiparticle constituents to demonstrate that it can host multiphoton dynamics mediated by either classical or quantum properties of coherence. This is shown in a forty-particle system through a process of scattering mediated by twisted paths endowed with orbital angular momentum. This platform enables accurate projections of the scattered pseudothermal system into isolated multiphoton subsystems governed by quantum dynamics. Interestingly, the isolated multiphoton subsystems exhibiting quantum coherence produce interference patterns previously attributed to entangled optical systems. As such, our work unveils novel mechanisms to isolate quantum systems from classical fields. This possibility opens new paradigms in quantum physics with enormous implications for the development of robust quantum technologies. [ABSTRACT FROM AUTHOR]

Electron spin qubits are becoming an important research direction in the field of quantum computing and information storage. However, the quantum decoherence has seriously hindered the development of this field. So far, few qubits exhibit long phase memory time (Tm), and even fewer qubits that can reach room temperature. Some reports show that the coherence times of radicals are generally long, so radicals may be the preferred spin carriers for qubits. Here, we demonstrate the qubit properties of a photogenerated radical (1 a) based on 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine (tpt, 1). More importantly, the photogenerated radical is a spin self‐diluting complex, which the dilution is generally used in the investigation of qubits to reduce the interference of environment on qubits in order to overcome the decoherence of qubits. It is surprised that radical tpt has a stable Tm=1.1 μs above 20 K, even keep it to room temperature. In addition, the tpt‐film prepared by the vacuum evaporation is significantly increase the T1 and Tm at low temperature. [ABSTRACT FROM AUTHOR]

The quantum uncertainty relation characterizes the restriction of the quantum coherence on different measurement bases. The skew information of coherence is a coherence measure both operationally and informatically. We study the quantum uncertainty relation for the skew information of coherence under any two orthonormal bases. In qubit and qutrit systems, we derive the quantum uncertainty relations with the lower bounds in the factorized forms by the purity of quantum states and the incompatibility between two orthonormal bases. Especially the lower bound in qubit systems is strictly positive for non-maximally mixed states and incompatible orthonormal bases. These quantum uncertainty relations reveal the intrinsic relation among the coherence, the purity and the incompatibility between two orthonormal bases quantitatively. The advantages of these quantum uncertainty relations are illustrated by some specific examples. This method we developed here is beneficial to some other quantum uncertainty relations. [ABSTRACT FROM AUTHOR]

Quantum Reservoir Computing (QRC) offers potential advantages over classical reservoir computing, including inherent processing of quantum inputs and a vast Hilbert space for state exploration. Yet, the relation between the performance of reservoirs based on complex and many-body quantum systems and non-classical state features is not established. Through an extensive analysis of QRC based on a transverse-field Ising model we show how different quantum effects, such as quantum coherence and correlations, contribute to improving the performance in temporal tasks, as measured by the Information Processing Capacity. Additionally, we critically assess the impact of finite measurement resources and noise on the reservoir's dynamics in different regimes, quantifying the limited ability to exploit quantum effects for increasing damping and noise strengths. Our results reveal a monotonic relationship between reservoir performance and coherence, along with the importance of quantum effects in the ergodic regime. Quantum Reservoir Computing leverages the quantum properties of physical systems for solving temporal tasks. This study shows the importance of quantum effects, such as coherence and superposition, in the reservoir's performance for different dynamical regimes, while considering the impact of finite measurements and noisy environments. [ABSTRACT FROM AUTHOR]

With rational designability, versatile tunability, and quantum coherence, molecular electron spin qubits could offer new opportunities for quantum information science, enabling simplified implementation of quantum algorithms and chemical‐specific quantum sensing. The development of these transformative technologies relies on coherent addressing of single molecular electron spin qubits with high initialization, manipulation, and readout fidelities. This is unfeasible to conventional electron spin resonance spectroscopy, which is widely used for coherent addressing of ensemble electron spins, due to its low initialization efficiency and readout sensitivity. Taking advantage of single spin detectability of single‐molecule spectroscopy, scanning tunneling microscopy, atomic force microscopy, and quantum metrology, several strategies have been developed to empower electron spin resonance spectroscopy with single qubit addressability. In this Emerging Topic, we introduce principles and technical implementation of strategies for coherent addressing of single molecular electron spin qubits, discuss their potential applicability in quantum technologies, and point out their challenges in terms of scalability, molecular design, and/or decoherence suppression. We discuss future directions to overcome these challenges and to improve single qubit addressing technologies, which will facilitate the advancement of molecular quantum information science. [ABSTRACT FROM AUTHOR]

Efforts to harness quantum hardware relying on quantum mechanical principles have been steadily progressing. The search for novel material platforms that could spur the progress by providing new functionalities for solving the outstanding technological problems is however still active. Any physical property presenting two distinct energy states that can be found in a long-lived superposition state can serve as a quantum bit (qubit), the basic information processing unit in quantum technologies. Molecular systems that can feature electron and/or nuclear spin states together with optical transitions are one of the material platforms that can serve as optically addressable qubits. The attractiveness of molecular systems for quantum technologies relies on the fact that molecular structures of atomically defined nature can be obtained in endless diversity of chemical compositions. Crucially, by harnessing the molecular design protocols, the optical and spin (electronic and nuclear) properties of molecules can be tailored, aiding the design of optically addressable spin qubits and quantum sensors. In this contribution, we present a concise and collective discussion of optically addressable spin-bearing molecules – namely, organic molecules, transition metal (TM) and rare-earth ion (REI) complexes – and highlight recent results such as chemical tuning of optical and electron spin quantum coherence, optical spin initialization and readout, intramolecular quantum teleportation, optical coherent storage, and photonic-enhanced optical addressing. We envision that optically addressable spin-carrying molecules could become a scalable building block of quantum hardware for applications in the fields of quantum sensing, quantum communication and quantum computing. [ABSTRACT FROM AUTHOR]

Quantum energy teleportation (QET) protocol illustrates that through local operations and classical communication, the local energy of the ground state of a many-body quantum system can be extracted. Unlike classical energy transmission, dissipation effects are greatly reduced in quantum energy teleportation. Energy extraction only requires classical information and local operations about the measurements. Quantum resources play a key role in this protocol, giving QET protocol quantum advantages over classical energy transmission. In this paper, we investigate the role of quantum resources in quantum energy teleportation. We find that quantum resources can improve the energy extraction efficiency of QET, and find the necessary and sufficient conditions for the minimal QET. We construct a quantum circuit for simulation of the minimal QET model and provide the numerical results of QET in Gibbs state and spin-chain system to verify our conclusions. [ABSTRACT FROM AUTHOR]

AtGRP2 is a glycine-rich, RNA-binding protein that plays pivotal roles in abiotic stress response and flowering time regulation in Arabidopsis thaliana. AtGRP2 consists of an N-terminal cold shock domain (CSD) and two C-terminal CCHC-type zinc knuckles interspersed with glycine-rich regions. Here, we investigated the structure, dynamics, and nucleic acid--binding properties of AtGRP2-CSD. The 2D [¹H,15N] heteronuclear single quantum coherence spectrum of AtGRP2-CSD1--79 revealed the presence of a partially folded intermediate in equilibrium with the folded state. The addition of 11 residues at the C terminus stabilized the folded conformation. The three-dimensional structure of AtGRP2-CSD1--90 unveiled a β-barrel composed of five antiparallel β-strands and a 310 helical turn, along with an ordered C-terminal extension, a conserved feature in eukaryotic CSDs. Direct contacts between the C-terminal extension and the β3--β4 loop further stabilized the CSD fold. AtGRP2-CSD1--90 exhibited nucleic acid binding via solvent-exposed residues on strands β2 and β3, as well as the β3--β4 loop, with higher affinity for DNA over RNA, particularly favoring pyrimidine-rich sequences. Furthermore, DNA binding induced rigidity in the β3--β4 loop, evidenced by 15N-{¹H} NOE values. Mutation of residues W17, F26, and F37, in the central b-sheet, completely abolished DNA binding, highlighting the significance of π-stacking interactions in the binding mechanism. These results shed light on the mechanism of nucleic acid recognition employed by AtGRP2, creating a framework for the development of biotechnological strategies aimed at enhancing plant resistance to abiotic stresses. [ABSTRACT FROM AUTHOR]

We explore the use of fractional controlled-not gates in quantum thermodynamics. The Nth-root gate allows for a paced application of two-qubit operations. We apply it in quantum thermodynamic protocols for charging a quantum battery. Circuits for three (and two) qubits are analysed by considering the generated ergotropy and other measures of performance. We also perform an optimisation of initial system parameters, e.g.,the initial quantum coherence of one of the qubits strongly affects the efficiency of protocols and the system's performance as a battery. Finally, we briefly discuss the feasibility for an experimental realization. [ABSTRACT FROM AUTHOR]

There exist quantum states for which the specific measure of quantum coherence remain unaffected by noise. In case of single qubit, subjected to Markovian bit-flip and bit+phase-flip noise, the l 1 norm of coherence is found to be frozen for states ( n 1 , 0 , n 3 ) in Bloch sphere representation. In present work, we searched for qutrit states that would show invariance of coherence in quantum channel by analyzing various cross-sections of the qutrit Bloch sphere. We found several geometric sections in state space that exhibit frozen phenomenon for quantum coherence under different noisy channels. [ABSTRACT FROM AUTHOR]

A thorough understanding of the lignin–carbohydrate complex (LCC) structure has a significant meaning in the high-value utilization of lignocellulose. In this work, the complex (DHPKGC) was obtained by an addition reaction between konjac glucomannan (KGM) and quinone methides generated in the synthesis of dehydrogenation polymers (DHPs) to simulate the formation of LCCs. The effect of pH on the prepared DHPKGC was investigated. The structure of the DHPKGC was characterized by Fourier Transform Infrared (FTIR), 13C-Nuclear Magnetic Resonance (13C-NMR), and two-dimensional Heteronuclear Single Quantum Coherence Nuclear Magnetic Resonance (2D HSQC NMR) analyses. The results indicated the pH of 4.0 was conducive to the polymerization reaction between DHPs and oxidized KGM by the TEMPO/NaClO/NaBr system. In addition, the resultant DHPKGC was connected by benzyl ester linkages. Overall, this study aims to gain greater insight into the process of LCC formation in plants. [ABSTRACT FROM AUTHOR]

This paper presents a localized treatment of quantum Rényi entropy. Specifically, based on the localized characteristics of Local Quantum Bernoulli Noises (LQBNs), a new definition of quantum Rényi entropy, that is, quantum Rényi entropy with localization characteristics, is given through the local density operator constructed by local conservative operators l k ∘ . We also verify that this new definition possesses properties such as unitary invariance, additivity, monotonicity, and weak subadditivity. Furthermore, through the monotonicity of the local quantum Rényi entropy, we derive the local quantum Rényi minimum entropy and the local quantum Rényi maximum entropy. The local quantum Rényi entropy can be used to study quantum entanglement and coherence. For instance, in the contexts of quantum phase transitions and quantum state transmission, the local quantum Rényi entropy can provide important insights into the flow of information and interactions within quantum systems. [ABSTRACT FROM AUTHOR]

In order to valorize the enzymatic hydrolysis residues (EHR) from the bioethanol industry, this work studies the effects on the structure, properties as well as shear resistance of EHR‐based phenol formaldehyde (EPF) adhesives prepared from EHR instead of commercial phenol. 2D heteronuclear signal quantum coherence NMR (2D HSQC NMR) and 31P NMR analysis reveal that lignin in EHR (EHL) possesses a high amount of G and H units which contain 1.9 mmol g−1 active sites (reaction site with formaldehyde). Fourier‐transform infrared (FT‐IR) characterization shows that the instead proportions of EHR with 5–30% in EPF adhesives do not show great influence on the chemical structure type and main functional groups of the prepared adhesives. The shear strength measurement results show that the strength of the 10%‐EPF adhesive is significantly improved by 29% compared to phenol‐formaldehyde (PF) adhesive, which is due to EHL in adhesives enhanced the cross‐linking of polymer chains. This work emphasizes the potential benefits of using industrial EHR to develop cost‐effective phenol formaldehyde adhesive preparation schemes, therefore giving an additional value to waste from biorefineries. [ABSTRACT FROM AUTHOR]

We present an analytical solution for a quantum system characterized by a double Λ five-level atom interacting with an intensity-dependent coupling regime, influenced by a nonlinear Kerr-like medium. We also derive the constants of motion through Heisenberg's equations. Furthermore, the dynamical evolution of the entanglement and quantum coherence between the atom and the field is discussed using linear entropy and l 1 -norm of coherence. Through a comprehensive examination of the quantum system, it is observed that both the detuning and the Kerr-like parameters exert a significant impact on the degree of entanglement and coherence. However, the impacts of detuning and the Kerr effect become less pronounced when the photon multiplicity is high. In addition, we conduct a comparison between the five-level atomic system and a four-level system, revealing that the number of energy levels has a profound impact on the behavior of entanglement and coherence. These findings highlight the importance of atomic structure and photon multiplicity in controlling and optimizing quantum processes, particularly in applications involving quantum communication and information processing. [ABSTRACT FROM AUTHOR]

Topological defects are discontinuities of a system protected by global properties, with wide applications in mathematics and physics. While previous experimental studies mostly focused on their classical properties, it has been predicted that topological defects can exhibit quantum superposition. Despite the fundamental interest and potential applications in understanding symmetry-breaking dynamics of quantum phase transitions, its experimental realization still remains a challenge. Here, we report the observation of quantum superposition of topological defects in a trapped-ion quantum simulator. By engineering long-range spin-spin interactions, we observe a spin kink splitting into a superposition of kinks at different positions, creating a "Schrodinger kink" that manifests nonlocality and quantum interference. Furthermore, by preparing superposition states of neighboring kinks with different phases, we observe the propagation of the wave packet in different directions, thus unambiguously verifying the quantum coherence in the superposition states. Our work provides useful tools for nonequilibrium dynamics in quantum Kibble-Zurek physics. [ABSTRACT FROM AUTHOR]

Measurement-induced state disturbance is a major challenge in obtaining quantum statistics at multiple time points. We propose a method to extract dynamic information from a quantum system at intermediate time points, namely snapshotting quantum dynamics. To this end, we apply classical post-processing after performing the ancilla-assisted measurements to cancel out the impact of the measurements at each time point. Based on this, we reconstruct a multi-time quasi-probability distribution (QPD) that correctly recovers the probability distributions at the respective time points. Our approach can also be applied to simultaneously extract exponentially many correlation functions with various time-orderings. We provide a proof-of-principle experimental demonstration of the proposed protocol using a dual-species trapped-ion system by employing 171Yb+ and 138Ba+ ions as the system and the ancilla, respectively. Multi-time measurements are performed by repeated initialization and detection of the ancilla state without directly measuring the system state. The two- and three-time QPDs and correlation functions are reconstructed reliably from the experiment, negativity and complex values in the QPDs clearly indicate a contribution of the quantum coherence throughout dynamics. Sequential incompatible measurements on a quantum state would need a full multi-time generalisation of quasiprobability in order to be adequately described. Here, the authors propose such a framework, and test it on a trapped-ion system measuring up to three-time correlation functions. [ABSTRACT FROM AUTHOR]

Maintaining quantum coherence and entanglement in the presence of environmental noise, particularly within non-Markovian contexts, represents a significant challenge for the progression of quantum information science and technology. This study offers a substantial advancement by investigating the dynamics of a two-qubit system subjected to diverse noise conditions, encompassing relaxation, dephasing, and their cumulative effects. By employing quantum-state-diffusion equations specifically crafted for non-Markovian environments, we introduce an innovative strategy to counteract the detrimental influences of environmental noise on quantum teleportation fidelity and entanglement concurrence. Our results underscore the potential for external interventions to markedly improve the resilience of quantum information processing tasks over prolonged durations, especially in settings where dephasing noise prevails. A key revelation is the intricate relationship between dephasing noise and the initial state of entanglement, which profoundly impacts the occurrence of entanglement sudden death. This research not only deepens our comprehension of quantum system dynamics under noisy circumstances but also furnishes practical directives for engineering robust quantum systems, a necessity for the development of scalable quantum technologies. [ABSTRACT FROM AUTHOR]

Diamond has superlative material properties for a broad range of quantum and electronic technologies. However, heteroepitaxial growth of single crystal diamond remains limited, impeding integration and evolution of diamond-based technologies. Here, we directly bond single-crystal diamond membranes to a wide variety of materials including silicon, fused silica, sapphire, thermal oxide, and lithium niobate. Our bonding process combines customized membrane synthesis, transfer, and dry surface functionalization, allowing for minimal contamination while providing pathways for near unity yield and scalability. We generate bonded crystalline membranes with thickness as low as 10 nm, sub-nm interfacial regions, and nanometer-scale thickness variability over 200 by 200 μm2 areas. We measure spin coherence times T2 for nitrogen vacancy centers in 150 nm-thick bonded membranes of up to 623 ± 21 μs, suitable for advanced quantum applications. We demonstrate multiple methods for integrating high quality factor nanophotonic cavities with the diamond heterostructures, highlighting the platform versatility in quantum photonic applications. Furthermore, we show that our ultra-thin diamond membranes are compatible with total internal reflection fluorescence (TIRF) microscopy, which enables interfacing coherent diamond quantum sensors with living cells while rejecting unwanted background luminescence. The processes demonstrated herein provide a full toolkit to synthesize heterogeneous diamond-based hybrid systems for quantum and electronic technologies. Development of diamond-based quantum and electronic technologies requires heterogeneous integration, which has remained challenging. This work realizes direct bonding of single crystal diamond membranes to a broad range of technology-relevant substrates while maintaining quantum coherence for hosted qubits. [ABSTRACT FROM AUTHOR]

Quantum coherence serves as a crucial physical resource, with its quantification emerging as a focal point in contemporary research. Superadditivity constitutes one of the most fundamental attributes in characterizing the coherence distribution in multipartite quantum systems. In this paper, we provide a way to derive tighter superadditivity inequalities of l 1 -norm coherence measure for arbitrary multiqubit states. We present a category of superadditivity relations related to the α th (α ≥ 2) power of l 1 -norm coherence C l 1 under certain conditions. Our results are better than the existing ones and are illustrated in detail with examples. [ABSTRACT FROM AUTHOR]

We report the effect of surface plasmons on the spatial correlations in frequency degenerate photons. It is found that the second-order degree of spatial coherence of the biphotons is manipulated due to the coupling of surface plasmons with the initial biphotons in a metallic subwavelength double-slit. Our results demonstrate that the second-order interference pattern in the resulting beam depends on slit parameters, coupling constant, and spatial coherence of the input beam. This suggests the possibility of amplifying spatial coherence in photonic qubits with an increase in coupling constant and a proper selection of slit separation. The comparison between surface plasmon-enhanced first-order and second-order interference patterns shows a significant increment in the amplitude of intensity for first-order as compared to the latter with an increase in coupling constant. We also illustrate the practical application of this research in material sensing. Furthermore, the study is anticipated to be beneficial in comprehending multi-particle quantum dynamics at the slit and finding applications in the regulation of spatial coherence in qubits for propagation through atmospheric turbulence, quantum sensing, and quantum imaging purposes. [ABSTRACT FROM AUTHOR]

We investigate the behavior of various measures of quantum coherence and quantum correlation in the spin-1/2 Heisenberg XYZ model with added Dzyaloshinsky-Moriya (DM) and Kaplan–Shekhtman–Entin-Wohlman–Aharony (KSEA) interactions at a thermal regime described by a Gibbs density operator. We aim to understand the restricted hierarchical classification of different quantum resources, where Bell nonlocality ⊆ quantum steering ⊆ quantum entanglement ⊆ quantum discord ⊆ quantum coherence. This hierarchy highlights the increasingly stringent conditions required as we move from quantum coherence to more specific quantum phenomena. In order to enhance quantum coherence, quantum correlation, and fidelity of teleportation, our analysis encompasses the effects of independently provided sinusoidal magnetic field control as well as DM and KSEA interactions on the considered system. The results reveal that enhancing the entanglement or quantum correlation of the channel does not always guarantee successful teleportation or even an improvement in teleportation fidelity. Thus, the relationship between teleportation fidelity and the channel's underlying quantum properties is intricate. Our study provides valuable insights into the complex interplay of quantum coherence and correlation hierarchy, offering potential applications for quantum communication and information processing technologies. [ABSTRACT FROM AUTHOR]

Brewer's spent grains (BSG) offer valuable opportunities for valorization beyond its conventional use as animal feed. Among its components, lignin—a natural polymer with inherent antioxidant properties—holds significant industrial potential. This work investigates the use of microwave-assisted extraction combined with acidic natural deep eutectic solvents (NaDESs) for efficient lignin recovery, evaluating three different NaDES formulations. The results indicate that choline chloride–lactic acid (ChCl-LA), a NaDES with superior thermal stability as confirmed via thermogravimetric analysis (TGA), is an ideal solvent for lignin extraction at 150 °C and 15 min, achieving a balance of high yield and quality. ChCl-LA also demonstrated good solubility and cell disruption capabilities, while microwaves significantly reduced processing time and severity. Under optimal conditions, i.e., 150 °C, 15 min, in the presence of ChCl-LA NaDES, the extracted lignin achieved a purity of up to 79% and demonstrated an IC50 (inhibitory concentration 50%) of approximately 0.022 mg/L, indicating a relatively strong antioxidant activity. Fourier transform infrared (FTIR) and 2D-HSQC NMR (heteronuclear single quantum coherence nuclear magnetic resonance) spectroscopy confirmed the successful isolation and preservation of its structural integrity. This study highlights the potential of BSG as a valuable lignocellulosic resource and underscores the effectiveness of acidic NaDESs combined with microwave extraction for lignin recovery. [ABSTRACT FROM AUTHOR]

Polariton lasing via Bose‐Einstein condensation (BEC) provides a peculiar method to achieve low threshold coherent light sources. Until now, the cryogenic operating temperature required for polariton lasers has hampered the development of polaritonics. Here, a novel approach is first reported to realize the ultra‐narrow linewidth polariton lasing under quasi‐3D quantum confinement at room‐temperature (RT). The potential trap landscape is constructed by ring‐shaped optical excitation, wherein the continuum polariton dispersion is modulated into discrete simple harmonic oscillator (SHO) states. The coherent condensation lasing of trapped polaritons occurs beyond the threshold power. Benefiting from the horizontal quantum confinement, the trapped polariton lasing exhibits an ultra‐narrow linewidth (0.7 meV) and excellent quality factor (Q = 3510). Moreover, the second‐order quantum coherence properties of trapped polariton condensation are determined to reveal the quantum phase transition of Bosonic system. The results offer a feasible route for realizing a low‐threshold ultra‐narrow linewidth polariton laser at RT, which significantly facilitates the fabrication of polariton laser and switches on opportunities for future applications. [ABSTRACT FROM AUTHOR]

Abstract The classical properties of thermal light fields were instrumental in shaping our early understanding of light. Before the invention of the laser, thermal light was used to investigate the wave-particle duality of light. The subsequent formulation of the quantum theory of electromagnetic radiation later confirmed the classical nature of thermal light fields. Here, we fragment a pseudothermal field into its multiparticle constituents to demonstrate that it can host multiphoton dynamics mediated by either classical or quantum properties of coherence. This is shown in a forty-particle system through a process of scattering mediated by twisted paths endowed with orbital angular momentum. This platform enables accurate projections of the scattered pseudothermal system into isolated multiphoton subsystems governed by quantum dynamics. Interestingly, the isolated multiphoton subsystems exhibiting quantum coherence produce interference patterns previously attributed to entangled optical systems. As such, our work unveils novel mechanisms to isolate quantum systems from classical fields. This possibility opens new paradigms in quantum physics with enormous implications for the development of robust quantum technologies.

Abstract We present an analytical solution for a quantum system characterized by a double $$\Lambda$$ Λ five-level atom interacting with an intensity-dependent coupling regime, influenced by a nonlinear Kerr-like medium. We also derive the constants of motion through Heisenberg’s equations. Furthermore, the dynamical evolution of the entanglement and quantum coherence between the atom and the field is discussed using linear entropy and $$l_{1}$$ l 1 -norm of coherence. Through a comprehensive examination of the quantum system, it is observed that both the detuning and the Kerr-like parameters exert a significant impact on the degree of entanglement and coherence. However, the impacts of detuning and the Kerr effect become less pronounced when the photon multiplicity is high. In addition, we conduct a comparison between the five-level atomic system and a four-level system, revealing that the number of energy levels has a profound impact on the behavior of entanglement and coherence. These findings highlight the importance of atomic structure and photon multiplicity in controlling and optimizing quantum processes, particularly in applications involving quantum communication and information processing.

Abstract Ergotropy, which represents the maximum amount of work that can be extracted from a quantum system, has become a focal point of interest in the fields of quantum thermodynamics and information processing. In practical scenarios, the interaction of quantum systems with their surrounding environment is unavoidable. Recent studies have increasingly focused on analyzing open quantum systems affected by non-stationary environmental fluctuations due to their significant impact on various physical scenarios. While much research has concentrated on work extraction from these systems, it often assumes that the environmental degrees of freedom are substantial and that the environment is effectively in equilibrium. This has led us to explore work extraction from quantum systems under non-stationary environmental conditions. In this work, the dynamics of ergotropy will be investigated in a non-equilibrium environment for both Markovian and non-Markovian regime. In this study, both the coherent and incoherent parts of the ergotropy will be considered. It will be shown that for a non-equilibrium environment, the extraction of work is more efficient compared to when the environment is in equilibrium.

In this article, we present a quantum model of the two-qutrit (T-Q) in the Λ-type configuration interacting with a field mode initially in a coherent state of power lower potential. We analyze the dynamical characteristics of this quantum system, taking into account the influences of both the T-Q initial state and the field parameters. We investigate the entanglement between the T-Q and field, the Q–Q state entanglement, as well as the T-Q quantum coherence. We quantify the nonclassical properties of the power lower potential field based on the evolution of the Mandel parameter. The effects of power lower potential parameters on the evolution of quantum measures such as negativity, quantum coherence, von Neumann entropy, and the Mandel parameter are analyzed when the T-Q are initially in the upper and Bell states. Our findings indicate that the system exhibits a quasi-periodic occurrence of maximum entanglement and coherence when the T-Q are initially in the Bell state.

We study the electron-induced ion-pair dissociation to gas-phase oxygen molecules using a state-of-the-art velocity-map ion-imaging technique. The analysis is entirely based on the conical time-gated wedge-shaped velocity slice images of O−/O2 nascent anionic fragments, and the resulting observations are in favor of Van Brunt et al.'s report [R. J. Van Brunt and L. J. Kieffer, J. Chem. Phys. 60, 3057 (1974)]. A new image reconstruction method, Jacobian over parallel slicing, is introduced to overcome the drawback of ion exaggeration in determining the kinetic energy distribution from the time-gated parallel slicing technique, which offers an alternative approach to the wedge slicing method. Most importantly, the role of the quintet-heavy Rydberg state has been drawn out to the complex ion-pair formalism. The extracted kinetic energy and angular distributions from the wedge slice images reveal a high momentum transfer during the ion-pair dissociation process, which could be the finest rationale to observe the breakdown of dipole Born approximation driven by multipole moment associated with the incident electron beam. Three distinct dissociative momentum bands have been precisely identified for O− dissociation. However, radiationless Rydberg's predissociation continuum (≥15%) has become an inherent character of electron-induced ion-pair dissociation, which could be dealt with using the beyond Born–Oppenheimer treatment. The incoherent sum of Σ and Π symmetric-associated ion-pair final states has been precisely identified by modeling the angular distribution of O−/O2 for each of the kinetic energy bands. A negligibly small amount of forward–backward asymmetry is observed in the angular distribution of O−/O2, which might be explained by the dissociative state-specific quantum coherence mechanism as reported [Krishnakumar et al., Nat. Phys. 14, 149 (2018); Kumar et al., arXiv:2206.15024 (2022)] by Prabhudesai et al. [ABSTRACT FROM AUTHOR]

The double quantum coherence (DQC) signal in nonlinear spectroscopy gives information about the many-body correlation effects not easily available by other methods. The signal is short-lived, consequently, a significant part of it is generated during the pulse overlap. Since the signal is at two times the laser frequency, one may intuitively expect that the pulse overlap-related artifacts are filtered out by the Fourier transform. Here, we show that this is not the case. We perform explicit calculations of phase-modulated two-pulse experiments of a two-level system where the DQC is impossible. Still, we obtain a significant signal at the modulation frequency, which corresponds to the DQC, while the Fourier transform over the pulse delay shows a double frequency. We repeat the calculations with a three-level system where the true DQC signal occurs. We conclude that with realistic dephasing times, the pulse-overlap artifact can be significantly stronger than the DQC signal. Our results call for great care when analyzing such experiments. As a rule of thumb, we recommend that only delays larger than 1.5 times the pulse length should be used. [ABSTRACT FROM AUTHOR]

Scalable quantum processors require high-fidelity universal quantum logic operations in a manufacturable physical platform. Donors in silicon provide atomic size, excellent quantum coherence and compatibility with standard semiconductor processing, but no entanglement between donor-bound electron spins has been demonstrated to date. Here we present the experimental demonstration and tomography of universal one- and two-qubit gates in a system of two weakly exchange-coupled electrons, bound to single phosphorus donors introduced in silicon by ion implantation. We observe that the exchange interaction has no effect on the qubit coherence. We quantify the fidelity of the quantum operations using gate set tomography (GST), and we use the universal gate set to create entangled Bell states of the electrons spins, with fidelity 91.3 ± 3.0%, and concurrence 0.87 ± 0.05. These results form the necessary basis for scaling up donor-based quantum computers. Donors spins in silicon are coherent, high-performance qubits, but scale-up has been challenging. Here the authors present the first experimental demonstration of exchange-based, entangling two qubit gates between electrons bound to 31P donors in Si. [ABSTRACT FROM AUTHOR]

This investigation delves into the dynamics of quantum correlations and coherence within a two-dimensional electron gas (2DEG) system, taking into account the influence of Rashba spin–orbit coupling (SOC). We utilize metrics such as logarithmic negativity (ℒ ), local quantum uncertainty (LQU ()), and relative entropy of coherence ( r ) to specifically assess these quantum resources among electron spins within non-interacting electron gases. Our study investigates how the separation distance (R) between electrons and the intensity of Rashba SOC (α), impact the behavior of quantum properties within the 2DEG system. We find that specific strengths of Rashba SOC can effectively regulate quantum correlations and coherence within this system. Particularly significant is our observation that optimal quantum indicators emerge when electron proximity is minimized, underscoring the substantial influence of electron distance on quantum characteristics. Conversely, as electron separation increases, these quantum metrics diminish. Therefore, by adjusting the Rashba parameter, we can enhance the resilience of these quantum measurements against increasing electron separations, providing valuable insights into the potential for controlling and manipulating quantum behavior in similar 2DEG systems. [ABSTRACT FROM AUTHOR]

This research investigates the time-fractional dynamics of two interacting dipolar spins in the presence of the Dzyaloshinsky-Moriya (DM) and Kaplan-Shekhtman-Entin-Wohlman-Aharony (KSEA) interactions, alongside a uniform external magnetic field. The main subject is to employ the time-fractional Schrödinger equation in order to examine the time-fractional development of quantum resources within the dipolar spin system, initially prepared in either a separable or partially entangled state. The study employs the ℓ 1 norm of coherence, logarithmic negativity, and local quantum uncertainty to evaluate quantum coherence, entanglement and nonclassical correlations, respectively. This examination encompasses various parameters including the fractional derivative order, initial state configurations, strengths of DM and KSEA interactions, and dipolar coupling. Our main findings reveal that these quantifiers increase over time and evolve towards states of maximal coherence, regardless of whether the system is initially in a separable or partially entangled state. Lower values of the fractional derivative parameter are observed to enhance or steady the memory of the produced fractional state, which demonstrates the significant influence of fractional time dynamics. Additionally, strong DM and KSEA interactions significantly enhance the levels of quantum correlations and coherence of the system, a trend mirrored by the dipolar coupling constants. [ABSTRACT FROM AUTHOR]

In a multi-level quantum system Fano coherences stand for the formation of quantum coherences due to the interaction with the continuum of modes characterizing an incoherent process. In this paper we propose a V-type three-level quantum system on which we certify the presence of genuinely quantum traits underlying the generation of Fano coherences. We do this by determining work conditions that allows for the loss of positivity of the Kirkwood-Dirac quasiprobability distribution of the stochastic energy changes within the discrete system. We also show the existence of nonequilibrium regimes where the generation of Fano coherences leads to a non-negligible excess energy given by the amount of energy that is left over with respect to the energy of the system at the beginning of the transformation. Excess energy is attained provided the initial state of the discrete system is in a superposition of the energy eigenbasis. We conclude the paper by studying the thermodynamic efficiency of the whole process. [ABSTRACT FROM AUTHOR]

We investigate quantum non-equilibrium refrigerators with one- and two-qubit systems in a squeezed thermal bath. We characterise their performances in the presence of squeezed heat baths, in terms of their coefficients of performance, cooling rates and figures of merit. Our results show that the performance of the refrigerators is strongly influenced by the squeezing parameter and the number of qubits. The performance of the two-qubit refrigerator (TQR) is found to be better than that of the one-qubit refrigerator (OQR) under the same operating conditions. Our findings suggest that a squeezed thermal bath can be a promising resource for the design of efficient quantum refrigerators in the non-equilibrium regime. [ABSTRACT FROM AUTHOR]

This article begins with an interdisciplinary review of a hydrodynamic approach to understanding the origins and nature of macroscopic quantum phenomena in high-temperature superconductivity, superfluidity, turbulence and biological systems. Building on this review, we consider new theoretical insights into the origin and nature of pointer states and their role in the emergence of quantum systems. The approach includes a theory of quantum coherence underpinned by turbulence, generated by a field of pointer states, which take the form of recirculating, spin-1/2 vortices (toroids), interconnected via a cascade of spin-1 vortices. Decoherence occurs when the bosonic network connecting pointer states is disrupted, leading to their localisation. Building further on this work, we explore how quantum particles (in the form of different vortex structures) could emerge as the product of a causal dynamic process, within a turbulent (fractal) spacetime. The resulting particle structures offer new insights into intrinsic spin, the probabilistic nature of the wave function and how we might consider pointer states within the standard "point source" representation of a quantum particle, which intuitively requires a more complexed description. [ABSTRACT FROM AUTHOR]

Purpose: Sodium triple quantum (TQ) signal has been shown to be a valuable biomarker for cell viability. Despite its clinical potential, application of Sodium TQ signal is hindered by complex pulse sequences with long scan times. This study proposes a method to approximate the TQ signal using a single excitation pulse without phase cycling. Methods: The proposed method is based on a single excitation pulse and a comparison of the free induction decay (FID) with the integral of the FID combined with a shifting reconstruction window. The TQ signal is calculated from this FID only. As a proof of concept, the method was also combined with a multi‐echo UTE imaging sequence on a 9.4 T preclinical MRI scanner for the possibility of fast TQ MRI. Results: The extracted Sodium TQ signals of single‐pulse and spin echo FIDs were in close agreement with theory and TQ measurement by traditional three‐pulse sequence (TQ time proportional phase increment [TQTPPI)]. For 2%, 4%, and 6% agar samples, the absolute deviations of the maximum TQ signals between SE and theoretical (time proportional phase increment TQTPPI) TQ signals were less than 1.2% (2.4%), and relative deviations were less than 4.6% (6.8%). The impact of multi‐compartment systems and noise on the accuracy of the TQ signal was small for simulated data. The systematic error was <3.4% for a single quantum (SQ) SNR of 5 and at maximum <2.5% for a multi‐compartment system. The method also showed the potential of fast in vivo SQ and TQ imaging. Conclusion: Simultaneous SQ and TQ MRI using only a single‐pulse sequence and SQ time efficiency has been demonstrated. This may leverage the full potential of the Sodium TQ signal in clinical applications. [ABSTRACT FROM AUTHOR]

Quantum coherence is a crucial resource in numerous quantum processing tasks. The robustness of coherence provides an operational measure of quantum coherence, which can be calculated for various states using semidefinite programming. However, this method depends on convex optimization and can be time-intensive, especially as the dimensionality of the space increases. In this study, we employ machine learning techniques to quantify quantum coherence, focusing on the robustness of coherence. By leveraging artificial neural networks, we developed and trained models for systems with different dimensionalities. Testing on data samples shows that our approach substantially reduces computation time while maintaining strong generalizability. [ABSTRACT FROM AUTHOR]

The uncertainty relation reveals the intrinsic difference between the classical world and the quantum world. We investigate the quantum uncertainty relation of quantum channel in qubit systems. Under two general measurement bases, we first derive the quantum uncertainty relation for quantum channels with respect to the relative entropy of coherence. Then we obtain the quantum uncertainty relation for unitary channels with respect to the l 1 norm of coherence. Some examples are given in detail. [ABSTRACT FROM AUTHOR]

In this study, we explore the ground state phase diagram of the spin-1/2 XX chain model, which features X Z Y - Y Z X -type three-spin interactions (TSIs). This model, while seemingly simple, reveals a rich tapestry of quantum behaviors. Our analysis relies on several key metrics. The ' l 1 -norm of coherence' helps us identify coherent states within the phase diagram, which represent states capable of superposition and interference. We employ the 'spin squeezing parameter' to pinpoint unique coherent states characterized by isotropic noise in all directions, making them invaluable for quantum metrology. Additionally, we utilize the 'entanglement entropy' to determine which of these coherent states exhibit entanglement, indicating states that cannot be fully described by local variables. Our research unveils diverse regions within the phase diagram, each characterized by coherent, squeezed, or entangled states, offering insights into the quantum phenomena underling these systems. We also study the critical scaling versus the system size for the mentioned quantities. [ABSTRACT FROM AUTHOR]

This study investigates the dynamics of quantum coherence and entanglement in the spin‐1 Heisenberg XXZ model. Particularly, the effects of the Heitler‐London (HL) coupling and the Dzyaloshinskii‐Moriya (DM) interaction are examined. By utilizing tools from quantum information theory, the concept of quantum correlated coherence and negativity are explored. The results show intrinsic decoherence leads to a decay of both correlated coherence and negativity. Interestingly, it is found that a small value of the Dzyaloshinskii‐Moriya interaction can significantly enhance coherence and entanglement. Various factors influence the system dynamics, including the initial state, anisotropy parameter, and the coupling distance between spins. It is shown that, by fixing the anisotropy parameter, the isotropic Heisenberg models XX and XXX can be easily recovered. Ultimately, the findings highlight that the system maintains a coherent temporal evolution despite decoherence. [ABSTRACT FROM AUTHOR]

Extracellular diffusion coupled with degradation is considered a dominant mechanism behind the establishment of morphogen gradients. However, the fundamental nature of these biophysical processes, visa viz, the Bicoid (Bcd) morphogen gradient, remains unclear. Fluorescence correlation spectroscopy has recently revealed multiple modes of Bcd transport at different spatial and temporal locations across the embryo. Here, we show that these observations are best fitted by a model fundamentally based on quantum mechanics. It is thus hypothesized that the transient quantum coherences in collaboration with unitary noise are responsible for the observed dynamics and relaxation to a non-equilibrium steady-state of the Bcd morphogen gradient. Furthermore, simulating the associated probability distribution for the model shows that the observed non-zero concentration of the Bcd molecules in the posterior-most parts of the embryo is a result of non-Gaussian distribution characteristic to quantum evolution. We conclude that with the Bcd gradient being essentially a one-dimensional problem, a simple one-dimensional model suffices for its analysis. [ABSTRACT FROM AUTHOR]