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Surface decoration of WO3 architectures with Fe2O3 nanoparticles for visible-light-driven photocatalysis.
- Source :
-
CrystEngComm . 2014, Vol. 16 Issue 16, p3289-3295. 7p. - Publication Year :
- 2014
-
Abstract
- Zero-dimensional Fe2O3 nanoparticles were successfully decorated on three-dimensional WO3 architectures to constitute a photocatalyst of Fe2O3@WO3 heterojunction. The obtained samples were characterized in detail by X-ray diffraction, scanning electron microscopy, elemental mapping, X-ray photoelectron spectroscopy and UV-Vis absorption spectra. The results indicate that rhombohedral α-Fe2O3 nanoparticles are homogeneously decorated on the surface of monoclinic WO3 architectures, and the constituted n+-n heterojunction results in "redshift" of the optical absorption. The photocatalyst of 1%Fe2O3@WO3 annealed at 400 °C exhibits the highest photocatalytic activity for degradation of Rhodamine B under visible light irradiation. The degradation obeys first-order reaction kinetics with an apparent rate constant of 0.057 min-1. It is suggested that the potential-energy difference between Fe2O3 and WO3 accelerates the separation of photogenerated electron-hole pairs, dominating the enhanced photocatalytic activity. The results presented herein provide new insight for development of a novel visible-light-driven photocatalyst and its potential application in harmful pollutant degradation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 16
- Issue :
- 16
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 100092842
- Full Text :
- https://doi.org/10.1039/c3ce42410c