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A new PC(spĀ³)P ligand and its coordination chemistry with low-valent iron, cobalt and nickel complexes.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 2014, Vol. 43 Issue 23, p8595-8598. 4p. - Publication Year :
- 2014
-
Abstract
- A new PC(sp³)P ligand N,N'-bis(diphenylphosphino)dipyrromethane [PCH2P] (1) was prepared and its iron, cobalt and nickel chemistry was explored. Two pincer-type complexes [PCHP]Fe(H)-(PMe3)2 (2) and [PCHP]Co(PMe3)2 (4) were synthesized in the reaction of 1 with Fe(PMe3)4 and Co(Me)(PMe3)4. 1 reacted with Co- (PMe3)4 and Ni(PMe3)4 to afford Co(0) and Ni(0) complexes [PCH2P]Co(PMe3)2 (3) and [PCH2P]Ni(PMe3)2 (5). The structures of complexes 2-5 were determined by X-ray diffraction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 43
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100112492
- Full Text :
- https://doi.org/10.1039/c4dt00639a