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Regioselective synthesis and molecular structure of the first derivative of praseodymium-containing metallofullerenes.

Authors :
Qin Zhou
Hui Li
Yongfu Lian
Mitsuaki Suzuki
Takeshi Akasaka
Lipiao Bao
Wenting Cai
Xing Lu
Weiwei Wang
Shigeru Nagase
Source :
Chemical Communications. 2014, Vol. 50 Issue 69, p9876-9878. 3p.
Publication Year :
2014

Abstract

Regioselective cycloaddition of adamantylidene carbene to Pr@C2v(9)-C82 affords the first derivative of praseodymium-containing metallo-fullerenes. Single-crystal X-ray crystallographic data in combination with theoretical studies demonstrate that the addition is dictated by the single metal ion encapsulated inside the fullerene cage. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
50
Issue :
69
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100136719
Full Text :
https://doi.org/10.1039/c4cc02949f