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Direct carboxylation of allylic halides with carbon dioxide in the presence of indium.
- Source :
-
Chemical Communications . 2014, Vol. 50 Issue 25, p3285-3287. 3p. - Publication Year :
- 2014
-
Abstract
- A highly regioselective indium-mediated allylation of carbon dioxide starting from simple allylic halides (X = I, Br, Cl) has been developed. No transition metal catalyst is needed and an inert atmosphere is not necessary. The reaction tolerates a wide range of synthetically attractive functional groups with a very high branched regioselectivity. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 50
- Issue :
- 25
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100164480
- Full Text :
- https://doi.org/10.1039/c4cc00148f