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Highly Efficient Rhodium/Monodentate Phosphoramidite Catalyst and Its Application in the Enantioselective Hydrogenation of Enamides and α-Dehydroamino Acid Derivatives.
- Source :
-
Journal of Organic Chemistry . 5/30/2003, Vol. 68 Issue 11, p4539. 3p. 1 Diagram, 2 Charts. - Publication Year :
- 2003
-
Abstract
- An easily prepared and highly efficient monodentate phosphoramidite ligand derived from BINOL, (S)2,2'-O,O-(1,1'-binaphthyl)-dioxo-N,N-diethylphospholidine, was examined in the hydrogenation of both enamides and α-dehydroamino acid derivatives. The catalyst provided remarkably high enantioselectivities (up to 99.6% ee for enamides and >99.9% ee for α-dehydroamino acid derivatives). [ABSTRACT FROM AUTHOR]
- Subjects :
- *LIGANDS (Chemistry)
*ORGANIC chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 68
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 10019143
- Full Text :
- https://doi.org/10.1021/jo026869c