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Pillar-layered Zn–triazolate–carboxylate frameworks tuned by the bend angles of ditopic ligands.
- Source :
-
Inorganic Chemistry Communications . Mar2015, Vol. 53, p84-87. 4p. - Publication Year :
- 2015
-
Abstract
- In the utilization of three ditopic ligands with different bend angles as pillars, we reported herein three pillar-layered Zn–triazolate–carboxylate frameworks, namely, [Zn 2 (ATRZ) 2 (BDC)] n ( 1 ), [Zn 2 (ATRZ) 2 (TPDC)] n ·2 n DMF ( 2 ) and [Zn 2 (ATRZ) 2 (ADDC)] n ( 3 ) (ATRZ = 3-amino-1,2,4-triazole, H 2 BDC = 1,4-benzenedicarboxylic acid, H 2 TPDC = 2,5-thiophenedicarboxylic acid, and H 2 ADDC = 1,3-adamantanedicarboxylic acid). Single crystal structural analyses demonstrate that different geometries of ditopic carboxylate pillars not only result in Zn–ATRZ layers adopting various corrugated configurations, but also give rise to 3,4-connected self-interpenetrated net of 1 and non-interpenetrated nets of 2 and 3 . All these compounds exhibit high thermal stability and blue photoluminescence. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13877003
- Volume :
- 53
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100820147
- Full Text :
- https://doi.org/10.1016/j.inoche.2015.01.025