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A Pd(ii)-catalyzed asymmetric approach toward chiral [3.3.1]-bicyclic ketals using 2-hydroxyphenylboronic acid as a pro-bis(nucleophile).
- Source :
-
Chemical Communications . 2013, Vol. 49 Issue 32, p3360-3362. 3p. - Publication Year :
- 2013
-
Abstract
- Enantioselective Pd(ii)-catalyzed construction of [3.3.1]-bicyclic ketals from 2-hydroxyphenylboronic acid 1 and enone 3 is reported, yielding enantioenriched [3.3.1]-bicyclic ketals in up to 97% yields and 98% ee. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKOXY compounds
*ACETAL resins
*KETONE derivatives
*BORONIC acids
*CATALYSIS
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 49
- Issue :
- 32
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100864670
- Full Text :
- https://doi.org/10.1039/c3cc00295k