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The first palladium-catalyzed 1,4-addition of terminal alkenes to acrylate esters.

Authors :
Liu, Pei
Wang, Heng-shan
Pan, Ying-ming
Dai, Wei-long
Liang, Hong
Chen, Zhen-Feng
Source :
Chemical Communications. 2013, Vol. 49 Issue 46, p5295-5297. 3p.
Publication Year :
2013

Abstract

A novel and efficient procedure for the synthesis of δ,γ-alkenyl esters with complete E-stereochemistry by the 1,4-addition of alkenes to acrylate esters in the presence of a catalytic amount of palladium chloride has been developed. This method provides a rapid and efficient access to substituted δ,γ-alkenyl esters. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
49
Issue :
46
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
100865255
Full Text :
https://doi.org/10.1039/c3cc41742e