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Site count: is a high-pressure quenched-flow reactor suitable for kinetic studies of molecular catalysts in ethylene polymerization?
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . 2013, Vol. 42 Issue 25, p9049-9057. 9p. - Publication Year :
- 2013
-
Abstract
- Understanding the kinetics of olefin polymerization with Ziegler–Natta and related catalysts means identifying the main kinetic parameters such as kp and concentration of active sites. The high-pressure quenched-flow technique could be an absolute method for counting active sites and for activation studies of molecular catalysts. A kinetic study of metallocene catalysts and a phenoxy-imine titanium catalyst in the first instants of polymerization is presented in this paper. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ETHYLENE
*POLYMERIZATION
*CATALYSTS
*METALLOCENE catalysts
*TITANIUM catalysts
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 42
- Issue :
- 25
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100892569
- Full Text :
- https://doi.org/10.1039/c3dt33004d