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Two solvent-dependent manganese(ii) supramolecular isomers: solid-state transformation and magnetic properties.
- Source :
-
CrystEngComm . 2013, Vol. 15 Issue 27, p5412-5416. 5p. - Publication Year :
- 2013
-
Abstract
- Two new MnII supramolecular isomers, [Mn2(pbt)2(H2O)2·2H2O]n (1) and [Mn2(pbt)2(H2O)2·DMF]n (2) (H2pbt = 5′-(pyridin-2-yl)-2H,4′H-3,3′-bi(1,2,4-triazole), DMF = N,N-dimethylformamide), have been solvothermally synthesized in different solvent systems. Compound 1 exhibits a (3,4)-connected net with the point symbol of (6.82)4(62.82.102), whereas 2 exhibits a rare 3D lvt-42·84 net. Moreover, an irreversible solid-state transformation from 2 to 1 was observed, and their magnetic properties were also investigated and discussed in detail. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 15
- Issue :
- 27
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 100903164
- Full Text :
- https://doi.org/10.1039/c3ce40565f