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Nickel-catalyzed thiolation of unactivated aryl C–H bonds: efficient access to diverse aryl sulfides.
- Source :
-
Chemical Communications . 2015, Vol. 51 Issue 19, p4069-4072. 4p. - Publication Year :
- 2015
-
Abstract
- A nickel-catalyzed thiolation of unactivated C(sp2)–H bonds with disulfides employing the PIP directing group was described. This process uses a catalytic nickel catalyst and no metallic oxidants or cocatalysts are required. The reaction tolerates various important functional groups and heteroarenes, providing an efficient synthetic pathway to access diverse diaryl sulfides. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 19
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 101107515
- Full Text :
- https://doi.org/10.1039/c4cc10446c