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Cooperation of Coordinative and π···π Interaction in Directing Two-fold Interpenetrated Architecture of Two Eu/Dy(III) 2-Sulfoterephthalate Complexes with 4,4′-Bipyridine.
- Source :
-
Zeitschrift für Anorganische und Allgemeine Chemie . Mar2015, Vol. 641 Issue 3/4, p525-528. 4p. - Publication Year :
- 2015
-
Abstract
- Two novel lanthanide coordination polymers, {[Ln(stp)(bipy)(H2O)] ·(H2O)} n [Ln = Eu ( 1) and Dy ( 2)], were synthesized by hydrothermal reactions of 2-sulfoterephthalate (stp) and 4,4′-bipyridine (bipy) ligands with europium/dysprosium(III) salts. Structural analyses show that both complexes 1 and 2 are isomorphic and crystallize in the monoclinic crystal system with space group P21/ n. Complex 1 exhibits a two-dimensional grid-like structure from europium(III) ions bridged by the carboxyl and sulfonate groups of stp ligands. Notably, the stretching 4,4′-bipyridine ligands besides the 2D grid-like layers form π ···π interactions and interpenetrate into the empty voids of another adjacent layer into a twofold interpenetrated structure. Fluorescence analysis show that the emission of two complexes exhibit the characteristic peaks of lanthanide ions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00442313
- Volume :
- 641
- Issue :
- 3/4
- Database :
- Academic Search Index
- Journal :
- Zeitschrift für Anorganische und Allgemeine Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 101590072
- Full Text :
- https://doi.org/10.1002/zaac.201400488