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Effect of NO on the catalytic removal of N2O over FeZSM-5. Friend or foe
- Source :
-
Catalysis Communications . Jul2003, Vol. 4 Issue 7, p333. 6p. - Publication Year :
- 2003
-
Abstract
- Selective catalytic reduction (SCR) of N2O with C3H8 over FeZSM-5 under excess oxygen is strongly inhibited by NO. The assistance of the hydrocarbon in N2O reduction vanishes at high partial NO pressures, approaching the activity of the N2O + NO system at molar NO/N2O ratios of 1.5–2, with N2O/C3H8=1. This effect differs from the NO promotion in direct N2O decomposition over Fe-zeolite catalysts. The negative effect of NO on the N2O reduction has a significant impact in the design and operation of catalytic reactors in tail-gases of nitric acid plants and other sources where NO comes along with N2O. [Copyright &y& Elsevier]
- Subjects :
- *CHEMICAL reduction
*HYDROCARBONS
Subjects
Details
- Language :
- English
- ISSN :
- 15667367
- Volume :
- 4
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Catalysis Communications
- Publication Type :
- Academic Journal
- Accession number :
- 10176448
- Full Text :
- https://doi.org/10.1016/S1566-7367(03)00083-9