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A N-self-doped carbon catalyst derived from pig blood for oxygen reduction with high activity and stability.

Authors :
Zhang, Jian
Li, Qidong
Zhang, Chenyu
Mai, Liqiang
Pan, Mu
Mu, Shichun
Source :
Electrochimica Acta. Apr2015, Vol. 160, p139-144. 6p.
Publication Year :
2015

Abstract

A new pig blood-derived N-self-doped carbon catalyst is successfully fabricated with aid of metal iron in the synthetic process. The prepared catalyst shows an excellent oxygen reduction reaction (ORR) performance with high onset potential (E onset = −0.04 V) and half-wave potential (E 1/2 = −0.16 V), which very approaches that of the commercial Pt/C catalyst (E onset = −0.03 V, E 1/2 = −0.14 V) in alkaline electrolytes. Particularly, the catalyst possesses a significantly superior stability and immunity for methanol crossover and CO poisoning than that of Pt/C. The synthetic method is simple and cost-effective, providing a great opportunity to produce an eco-friendly and cheaper non-platinum fuel cell catalyst by using abundant natural biological resources. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00134686
Volume :
160
Database :
Academic Search Index
Journal :
Electrochimica Acta
Publication Type :
Academic Journal
Accession number :
101926963
Full Text :
https://doi.org/10.1016/j.electacta.2015.01.200