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Synthesis and characterization of fullerophosphine–Au(I) complexes.
- Source :
-
Journal of Organometallic Chemistry . May2015, Vol. 784, p41-45. 5p. - Publication Year :
- 2015
-
Abstract
- Ligand substitution reaction of the fullerophosphine PPh 2 ( o -C 6 H 4 )(CH 2 NMeCH)C 60 ( 1 ) with AuCl(SC 4 H 8 ) affords AuCl(PPh 2 ( o -C 6 H 4 )(CH 2 NMeCH)C 60 ) ( 2 ) in good yields. In the presence of AgPF 6 , compound 2 reacts with 1 to produce [Au(PPh 2 ( o -C 6 H 4 )(CH 2 NMeCH)C 60 ) 2 ]PF 6 ( 3 ), where the Au(I) ion is coordinated by two molecules of 1 in a dumbbell-shaped feature. On the other hand, compound 1 undergoes a nucleophilic addition to (AuC CPh) n to generate Au(C CPh)(PPh 2 ( o -C 6 H 4 )(CH 2 NMeCH)C 60 ) ( 4 ). The structures of 2 – 4 have been determined by an X-ray diffraction study. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 784
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 101942020
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2014.05.037