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Raman spectroscopy of bromine chains inside the one-dimensional channels of AlPO4-5 single crystals.
- Source :
-
Journal of Raman Spectroscopy . Apr2015, Vol. 46 Issue 4, p413-417. 5p. - Publication Year :
- 2015
-
Abstract
- Raman spectroscopy of the one-dimensional atomic or molecular chains, which are the attractive building blocks of advanced nanoscale materials, is crucial in understanding the physical properties of the one-dimensional atomic or molecular chains. Here, we introduce the bromine into the one-dimensional channels of AlPO4-5 single crystals through a physical vapor diffusion method. Raman spectroscopy indicates that the confined bromine structures mainly exist as (Br2)n chains, individual Br2 molecules, and a small amount of Br3− chains inside the channels of AlPO4-5 single crystals. Polarized Raman spectra demonstrate that the bromine molecular chains are approximately parallel to the channel direction of AlPO4-5 single crystals. Copyright © 2015 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03770486
- Volume :
- 46
- Issue :
- 4
- Database :
- Academic Search Index
- Journal :
- Journal of Raman Spectroscopy
- Publication Type :
- Academic Journal
- Accession number :
- 101966342
- Full Text :
- https://doi.org/10.1002/jrs.4664