Novel self-growth photocatalytic rod-like heterojunction for hydrogen production under visible light.

Novel H 3 ONb 3 O 8 –CuNb 3 O 8 (HN–CN) semiconductors with a configuration of rod-like heterojunction were formed through analogous self-growth process, including ion-exchange and crystal structure transition processes. A p-type CuNb 3 O 8 nano-semiconductor was grown on a layer structured rod-like KNb 3 O 8 crystal and the as-prepared HN–CN sample showed a broad absorption range (~800 nm). Especially, the HN–CN sample exhibited an improved photocatalytic activity for hydrogen production, and a model was proposed to explain the improvement in photocatalytic activity. Current study may provide a new way for the preparation of the p–n heterojunction with high performance under visible light. [ABSTRACT FROM AUTHOR]