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Theoretical analyses of chemical dissolution-front instability in fluid-saturated porous media under non-isothermal conditions.
- Source :
-
International Journal for Numerical & Analytical Methods in Geomechanics . Jun2015, Vol. 39 Issue 8, p799-820. 22p. - Publication Year :
- 2015
-
Abstract
- This paper mainly deals with the theoretical aspects of chemical dissolution-front instability problems in two-dimensional fluid-saturated porous media under non-isothermal conditions. In the case of the mineral dissolution ratio (that is defined as the ratio of the dissolved-mineral equilibrium concentration in the pore fluid to the molar concentration of the dissolvable mineral in the solid matrix of the fluid-saturated porous medium) approaching zero, the corresponding critical condition has been mathematically derived when temperature variation effects are considered. As a complementary tool, the computational simulation method is used to simulate the morphological evolution of chemical dissolution fronts in two-dimensional fluid-saturated porous media under non-isothermal conditions. The related theoretical and numerical results have demonstrated that: (i) a temperature increase in a non-isothermal chemical dissolution system can have some influence on the propagation speed of the planar chemical dissolution front in the system. Generally, the chemical dissolution front in the non-isothermal chemical dissolution system propagates slower than that in the counterpart isothermal chemical dissolution system when the temperature of the non-isothermal chemical dissolution system is higher than that of the counterpart isothermal chemical dissolution system; (ii) a temperature increase in the non-isothermal chemical dissolution system can stabilize the chemical dissolution front propagating in the system, because it can cause a decrease in the Zhao number of the system but does not affect the critical Zhao number of the system; and (iii) the temperature gradient in the upstream direction of a chemical dissolution front is smaller than that in the downstream direction of the chemical dissolution front when the non-isothermal chemical dissolution system is supercritical. Copyright © 2014 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03639061
- Volume :
- 39
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- International Journal for Numerical & Analytical Methods in Geomechanics
- Publication Type :
- Academic Journal
- Accession number :
- 102077830
- Full Text :
- https://doi.org/10.1002/nag.2332