Back to Search
Start Over
Nickel-catalyzed direct thiolation of unactivated C(sp3)–H bonds with disulfides.
- Source :
-
Chemical Communications . 4/30/2015, Vol. 51 Issue 34, p7341-7344. 4p. - Publication Year :
- 2015
-
Abstract
- The first nickel-catalyzed thiolation of unactivated C(sp3)–H bonds with disulfides was described. This transformation uses (dppp)NiCl2 as a catalyst and BINOL as a ligand, which are efficient for the thiolation of β-methyl C(sp3)–H bonds of a broad range of aliphatic carboxamides. The reaction provides an efficient synthetic pathway to access diverse thioethers. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 34
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 102111845
- Full Text :
- https://doi.org/10.1039/c5cc01436k