Co3O4-based binder-free cathodes for lithium–oxygen batteries with improved cycling stability.

A novel binder-free electrode for lithium–oxygen batteries has been prepared by electrodepositing a Co3O4 layer onto a pretreated TiO2 fiber mesh, formed on nickel foam by an electrospinning method. The Co3O4 depositing layer is composed of Co3O4 nanoflakes, forming a uniform flower-like porous structure. The Co3O4 nanoflakes within the depositing layer provide a large amount of catalytic active sites for oxygen evolution and reduction reactions. The three-dimensional porous network of the Co3O4 depositing layer can not only facilitate the transportation of ions and electrolyte within the electrode, but also provide plenty of space to accommodate Li2O2 species formed during the discharge process. The Co3O4 spheres embedded in the TiO2 fiber mesh, formed by the treatment of a suspension of cobaltammine precipitate, function as anchors to prevent the detachment of the Co3O4 layer from the current collector, resulting in excellent structural and cycling stability. Only a slight specific capacity decay is observed at full discharge/charge after 80 cycles. This work demonstrates the important factors in the preparation of binder-free cathodes for high performance lithium–oxygen batteries. [ABSTRACT FROM AUTHOR]