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Robust Molecular Bowl-Based Metal-Organic Frameworks with Open Metal Sites: Size Modulation To Increase the Catalytic Activity.
- Source :
-
Inorganic Chemistry . 4/20/2015, Vol. 54 Issue 8, p3719-3721. 3p. - Publication Year :
- 2015
-
Abstract
- Herein, two stable lead(II) molecular-bowl-based metal-organic frameworks and their micro- and nanosized forms with open metal sites were presented. These materials could act as Lewis acid catalysts to cyanosilylation reaction. Moreover, the catalytic performances are size-dependent, with the catalyst with nanosized form being 1 order of magnitude more efficient than those with micro- and millisized forms. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 54
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 102663666
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.5b00185