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A Unique Alkylation of Azobenzenes with Allyl Acetates by RhIII-Catalyzed C-H Functionalization.

Authors :
Hong Deng
Hongji Li
Lei Wang
Source :
Organic Letters. May2015, Vol. 17 Issue 10, p2450-2453. 4p.
Publication Year :
2015

Abstract

A novel RhIII-catalyzed direct alkylation of azobenzenes with allyl acetates through C-H activation and functionalization is demonstrated in which the allyl acetates serve as unique alkylation agents. The rhodium-catalyzed alkylation provides a highly efficient and atom-economic approach to a series of azo compounds. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
17
Issue :
10
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
102774817
Full Text :
https://doi.org/10.1021/acs.orglett.5b00957