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Stochastic Lineshape Theory for Multistate, Non-Markovian Frequency Fluctuations#.
- Source :
-
Bulletin of the Korean Chemical Society . Mar2015, Vol. 36 Issue 3, p906-913. 1p. - Publication Year :
- 2015
-
Abstract
- A stochastic lineshape theory is formulated for the non-Markovian and multistate frequency modulation model. The frequency of the stochastic oscillator undergoes non-Markovian modulations between multiple states, and the transition processes are described by arbitrary waiting-time distributions. By incorporating stationarity into the stochastic process in a proper way, we calculate the propagator and the relaxation function. It is shown that a stationary distribution among the oscillator states satisfies a generalized detailed balance condition even in the non-Markovian case. We find an exact expression for the lineshape function, which contains the Markovian case as a special limit. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 02532964
- Volume :
- 36
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Bulletin of the Korean Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 103345352
- Full Text :
- https://doi.org/10.1002/bkcs.10169