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Synthesis, crystal structure, and porosity of 1D coordination polymer of neodymium(III) with isonicotinic acid and dimeric complex of neodymium(III) with nicotinic acid.
- Source :
-
Russian Journal of Coordination Chemistry . Jul2015, Vol. 41 Issue 7, p469-480. 12p. - Publication Year :
- 2015
-
Abstract
- A 1D coordination polymer [Nd(INA)(HO)] ( I) and a dimeric complex with mononuclear asymmetric unit [Nd(NA)(HO)] ( II) (HINA = isonicotinic acid and HNA = nicotinic acid) were synthesized. The compounds were characterized by elemental analyses, infrared spectroscopy and single crystal X-ray diffraction studies (CIF file CCDC nos. 938976 ( I) and 939061 ( II). X-ray crystal structure analysis reveals that both compounds exhibit rich structural chemistry. Compounds I and II belong to the monoclinic system with space group P2/ c. Thermogravimetric analysis has been performed to investigate their thermal stability. The coordination polymer I has meso-porous structure with average diameter of pores (∼4 nm) and BET surface area 13.62 m/g. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 41
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 103382848
- Full Text :
- https://doi.org/10.1134/S1070328415060068