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ChemInform Abstract: Asymmetric Tandem 1,5-Hydride Shift/Ring Closure for the Synthesis of Chiral Spirooxindole Tetrahydroquinolines.

Authors :
Cao, Weidi
Liu, Xiaohua
Guo, Jing
Lin, Lili
Feng, Xiaoming
Source :
ChemInform. Jun2015, Vol. 46 Issue 24, pno-no. 1p.
Publication Year :
2015

Abstract

A chiral N,N′-dioxide complex (DPR) in combination with Sc(OTf)2 as catalytic system allows the intramolecular cyclization of various oxindole derivatives to form spirocyclic products with high diastereo- and enantioselectivities. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09317597
Volume :
46
Issue :
24
Database :
Academic Search Index
Journal :
ChemInform
Publication Type :
Academic Journal
Accession number :
103385924
Full Text :
https://doi.org/10.1002/chin.201524107