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Excess enthalpies of the ternary mixtures: {tetrahydrofuran + 3-methylpentane + (octane or decane)} at the temperature 298.15 K

Authors :
Wang, Zhaohui
Benson, George C.
Lu, Benjamin C.-Y.
Source :
Journal of Chemical Thermodynamics. Oct2003, Vol. 35 Issue 10, p1635. 10p.
Publication Year :
2003

Abstract

Measurements of excess molar enthalpies at the temperature 298.15 K in a flow microcalorimeter, are reported for the two ternary mixtures {<f>X1</f>C4H8O + <f>X2</f>CH3CH2CH(CH3)CH2CH3 + <f>(1−X1−X2)</f>CH3<f>(CH2)v−2</f>CH3} with <f>v=8</f> and 10. Smooth representations of the results are described and used to construct constant-enthalpy contours on Roozeboom diagrams. It is shown that useful estimates of the ternary enthalpies can be obtained from the Liebermann–Fried model, using only the physical properties of the components and their binary mixtures. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00219614
Volume :
35
Issue :
10
Database :
Academic Search Index
Journal :
Journal of Chemical Thermodynamics
Publication Type :
Academic Journal
Accession number :
10804564
Full Text :
https://doi.org/10.1016/S0021-9614(03)00148-4