ChemInform Abstract: Pd-Catalyzed Enantiodivergent and Regiospecific phospha-Michael Addition of Diphenylphosphine to 4-Oxo-Enamides: Efficient Access to Chiral Phosphinocarboxamides and Their Analogues.

Authors :: Chew, Renta Jonathan
Li, Xi‐Rui
Li, Yongxin
Pullarkat, Sumod A.
Leung, Pak‐Hing
Source :: ChemInform. Aug2015, Vol. 46 Issue 31, pno-no. 1p.
Publication Year :: 2015
Abstract: The first catalytic asymmetric phospha-Michael addition of diphenylphosphine to 4-oxo-enamide using a palladacycle catalyst is developed. [ABSTRACT FROM AUTHOR]

Subjects :: *PHOSPHORUS compounds
*PALLADIUM catalysts
*MICHAEL reaction
*DIPHENYLPHOSPHINE
*CARBOXAMIDES
*CHIRALITY
*PALLADACYCLES

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