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Acid-Catalyzed Synthesis of α-Trifluoromethylthiolated Carbonyl Compounds.
- Source :
-
European Journal of Organic Chemistry . Jul2015, Vol. 2015 Issue 21, p4607-4610. 4p. - Publication Year :
- 2015
-
Abstract
- The α-trifluoromethylthiolation of carbonyl compounds in soft acidic conditions has been developed. With this method only mono-trifluoromethylthiolation was selectively observed. Base-sensitive ketones can then be trifluoromethylthiolated. More sensitive aldehydes are also trifluoromethylthiolated under these conditions with good yields. This work provides a new route towards the synthesis of various valuable trifluoromethylthiolated molecules. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2015
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 108392842
- Full Text :
- https://doi.org/10.1002/ejoc.201500710