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Regiospecific Intermolecular Aminohydroxylation of Olefins by Photoredox Catalysis.
- Source :
-
Chemistry - A European Journal . Aug2015, Vol. 21 Issue 33, p11677-11680. 4p. - Publication Year :
- 2015
-
Abstract
- A simple and regiospecific aminohydroxylation of olefins by photoredox catalysis has been developed. N-protected 1-aminopyridinium salts are the key compounds and serve as amidyl radical precursors by the action of Ir photocatalysts, fac-[Ir(ppy)3] and [Ir(ppy)2(dtbbpy)](PF6) (ppy=2-pyridylphenyl, dtbbpy=4,4′-di- tert-butyl-2,2′-bipyridine). The present photocatalytic system allows for synthesis of vicinal aminoalcohol derivatives from olefins with various functional groups under mild reaction conditions with easy handling. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 21
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 108698724
- Full Text :
- https://doi.org/10.1002/chem.201501590