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Manganese-centered ten-vertex germanium clusters: the strong field Ge 10 ligand encapsulating a transition metal.
- Source :
-
Journal of Coordination Chemistry . Oct2015, Vol. 68 Issue 19, p3485-3497. 13p. 3 Color Photographs, 2 Black and White Photographs, 3 Diagrams. - Publication Year :
- 2015
-
Abstract
- The experimental realization of pentagonal prismatic structures for M@(M = Co, Fe) containing interstitial transition metal atoms makes of interest the chemistry of corresponding manganese derivatives Mn@. The neutral Mn@Ge10may be regarded as a complex of a polyhedralligand with an interstitial Mn in the +2 oxidation state. However, the lowest energy Mn@Ge10structure with the expected sextet spin state for high-spin d5Mn(II) lies ~23 kcal mol−1in energy above the lowest energy isomer thereby suggesting that such germanium polyhedra function as strong field ligands for encapsulated transition metals. The lowest energy structures for the Mn@anions (z = −1 to −5) are all centered pentagonal prisms. Higher energy Mn@structures have outer Ge10polyhedra based on the tetracapped trigonal prism similar to the lowest energy Co@structure and on the bicapped square antiprism similar to the B10deltahedron. Other Mn@structures have outer Ge10polyhedra with four or five quadrilateral faces as well as six or eight triangular faces, respectively. Bioctahedral (Ge5)2Mn5−structures were also found for the pentaanion with a manganese vertex common to two MnGe5octahedra. The cationic species Mn@was found to have a more complicated potential surface than the anions. Tetracapped trigonal prismatic and bicapped square antiprismatic structures as well as a variety of more open structures were found for Mn@. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 68
- Issue :
- 19
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 109441882
- Full Text :
- https://doi.org/10.1080/00958972.2015.1073267