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Is Octavalent Pu(VIII) Possible? Mapping the Plutonium Oxyfluoride Series PuOnF8-2n (n = 0-4).
- Source :
-
Inorganic Chemistry . 9/8/2015, Vol. 54 Issue 17, p8825-8831. 7p. - Publication Year :
- 2015
-
Abstract
- While the oxidation state Pu(VIII) is shown to be less stable than Pu(V) in the PuO4 molecule, it is not clear if the more electronegative fluorine can help to stabilize Pu(VIII). Our calculations on PuOnF8-2n (n = 0-4) molecules notably confirm that PuO2F4 has both ¹D4h and 5C2v minima with the oxidation states Pu(VIII) and Pu(V), respectively, with the latter having lower energy. The hybrid-DFT, CCSD(T), and CASSCF methods all give the same result. The results conform to a superoxide ligand when n ≥ 2. PuF8 in a ¹Oh state can decompose to PuF6 and F2, and PuOF6 in a ¹C2v state also can break down to PuF6 and 1/2 O2. The Pu(VIII) anion PuO2F5- does have a D5h minimum, which also lies above a 5C2v Pu(V) peroxide structure. However, the energy differences between the different minima are not large, indicating that metastable species with oxidation states higher than Pu(V) cannot be completely excluded. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PLUTONIUM
*FLUORINE
*OXIDATION
*METASTABLE states
*OXYFLUORIDES
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 54
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 109947591
- Full Text :
- https://doi.org/10.1021/acs.inorgchem.5b01540