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Mechanism-based design of labile precursors for chromium(i) chemistry.

Authors :
Akturk, Eser S.
Yap, Glenn P. A.
Theopold, Klaus H.
Source :
Chemical Communications. 10/28/2015, Vol. 51 Issue 84, p15402-15405. 4p.
Publication Year :
2015

Abstract

Dinitrogen complexes of the type TpR,RCr–N2–CrTpR,R are not the most labile precursors for Cr(i) chemistry, as they are sterically protected from obligatory associative ligand substitution. A mononuclear alkyne complex – TptBu,MeCr(η2-C2(SiMe3)2) – proved to be much more reactive. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*CHEMICAL precursors
*LIGANDS (Chemistry)
*CHROMIUM compounds
*ALKYNE synthesis
*CHEMICAL reactions

Details

Language :
English
ISSN :
13597345
Volume :
51
Issue :
84
Database :
Academic Search Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
110209272
Full Text :
https://doi.org/10.1039/c5cc05993c
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