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Modulation of single-molecule magnet behaviour via photochemical [2+2] cycloaddition.
- Source :
-
Chemical Communications . 10/28/2015, Vol. 51 Issue 84, p15358-15361. 4p. - Publication Year :
- 2015
-
Abstract
- The first example of phototunable SMMs has been reported. Upon UV irradiation, variations of the coordination sphere around Dy(iii) ions actually affect the magnetic behaviour of the compound via [2+2] cycloaddition reaction, leading to a magnetic transformation from the SMM behaviour to a field-induced slow relaxation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 84
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 110209286
- Full Text :
- https://doi.org/10.1039/c5cc07073b