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Composite electrolyte membranes incorporating viscous copolymers with cellulose for high performance lithium-ion batteries.
- Source :
-
Journal of Membrane Science . Jan2016, Vol. 497, p259-269. 11p. - Publication Year :
- 2016
-
Abstract
- A novel composite electrolyte membrane (CEM), consisting of a viscous PEGMEM-co-SMA copolymer, lithium salt and cellulose matrix, has been prepared as a new class of electrolyte for high performance lithium-ion batteries (LIBs). This CEM exhibits a wide electrochemical stability window (>5 V vs. Li/Li + ), reasonably high ionic conductivity and thermal stability up to 315 °C. At temperature above the melting temperature (31.98–35.71 °C), the viscous flow nature of the copolymer is beneficial to fully infiltrate the electrode materials like liquid electrolyte to maintain uniform contact with electrode surfaces during charge/discharge process. The interfacial resistance ( R intf ) of the fresh cell based on this CEM is extremely low (3.8 Ω cm −2 ) and the Li/LiFePO 4 cell deliveries a discharge capacity as high as 156.9 mA h g −1 with a current density of 1 C at 80 °C. It is anticipated that this work provides a new insight for designing advanced electrolyte materials for LIBs with enhanced interfacial contact and excellent cycling performance. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03767388
- Volume :
- 497
- Database :
- Academic Search Index
- Journal :
- Journal of Membrane Science
- Publication Type :
- Academic Journal
- Accession number :
- 110576796
- Full Text :
- https://doi.org/10.1016/j.memsci.2015.09.056