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The Existence of Tricyanomethane.
- Source :
-
Angewandte Chemie International Edition . Nov2015, Vol. 54 Issue 46, p13775-13776. 2p. - Publication Year :
- 2015
-
Abstract
- Calcium tricyanomethanide reacts with hydrogen fluoride under formation of tricyanomethane and Ca(HF2)2. Tricyanomethane is stable below −40 °C and was characterized by IR, Raman, and NMR spectroscopy. The vibrational spectra were compared to the quantum-chemical frequencies at the PBE1PBE/6-311G(3df,3dp) level of theory and confirm the predicted C3 v symmetry of the molecule with regular CH (109.8 pm), CC (146.7 pm), and CN (114.7 pm) bonds. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ACETONITRILE
*AIR pollutants
*NITRILES
*HYDROGEN fluoride
*FLUORIDES
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 54
- Issue :
- 46
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 110673980
- Full Text :
- https://doi.org/10.1002/anie.201506753