A versatile and highly efficient post-functionalization method for grafting organic molecules onto Anderson-type polyoxometalates.

Authors :: Vanhaecht, Stef
Jacobs, Jeroen
Van Meervelt, Luc
Parac-Vogt, Tatjana N.
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 11/28/2015, Vol. 44 Issue 44, p19059-19062. 4p.
Publication Year :: 2015
Abstract: A new azide functionalized Anderson polyoxometalate was synthesized, fully characterized and subsequently used as a building block for further POM post-functionalization with organic compounds through a copper catalyzed azide–alkyne cycloaddition (CuAAC) reaction. Optimization of the reaction conditions led to an efficient, fast, convenient and versatile POM coupling method. [ABSTRACT FROM AUTHOR]

Subjects :: *POLYOXOMETALATES
*MOLECULAR physics
*COORDINATION compounds
*METALLIC oxides
*RING formation (Chemistry)

Language :: English
ISSN :: 14779226
Volume :: 44
Issue :: 44
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 110703421
Full Text :: https://doi.org/10.1039/c5dt03559g

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