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Unified synthesis of tirandamycins and streptolydigins.
- Source :
-
Chemical Communications . 12/11/2015, Vol. 51 Issue 95, p17004-17007. 4p. - Publication Year :
- 2015
-
Abstract
- The asymmetric total syntheses of tirandamycins A–D and tirandalydigin as well as the synthesis of the left-hand fragment of streptolydiginone and streptolydigin from a common intermediate are described. The comprehensive approach features the highly enantio- and diastereoselective assembly of the anti,anti,syn-stereotetrad unit which relies on a cinchona alkaloid-catalyzed asymmetric Morita–Baylis–Hillman reaction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 95
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 111007270
- Full Text :
- https://doi.org/10.1039/c5cc07749d