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Controllable Perovskite Crystallization by Water Additive for High-Performance Solar Cells.
- Source :
-
Advanced Functional Materials . Nov2015, Vol. 25 Issue 42, p6671-6678. 8p. - Publication Year :
- 2015
-
Abstract
- A key issue for perovskite solar cells is the stability of perovskite materials due to moisture effects under ambient conditions, although their efficiency is improved constantly. Herein, an improved CH3NH3PbI3− xCl x perovskite quality is demonstrated with good crystallization and stability by using water as an additive during crystal perovskite growth. Incorporating suitable water additives in N, N-dimethylformamide (DMF) leads to controllable growth of perovskites due to the lower boiling point and the higher vapor pressure of water compared with DMF. In addition, CH3NH3PbI3− xCl x · nH2O hydrated perovskites, which can be resistant to the corrosion by water molecules to some extent, are assumed to be generated during the annealing process. Accordingly, water additive based perovskite solar cells present a high power conversion efficiency of 16.06% and improved cell stability under ambient conditions compared with the references. The findings in this work provide a route to control the growth of crystal perovskites and a clue to improve the stability of organic-inorganic halide perovskites. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SOLAR cells
*PEROVSKITE
*CRYSTALLIZATION
*MOISTURE
*VAPOR pressure
Subjects
Details
- Language :
- English
- ISSN :
- 1616301X
- Volume :
- 25
- Issue :
- 42
- Database :
- Academic Search Index
- Journal :
- Advanced Functional Materials
- Publication Type :
- Academic Journal
- Accession number :
- 111071495
- Full Text :
- https://doi.org/10.1002/adfm.201503559