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A New Double-Decker Lu(III) Diphthalocyanine with Eight Peripheral Benzo(15-crown-5) Units.
- Source :
-
Synthesis & Reactivity in Inorganic & Metal-Organic Chemistry . Oct2003, Vol. 33 Issue 9, p1527-1533. 7p. - Publication Year :
- 2003
-
Abstract
- In the present study we describe a lutetium(III) bis(phthalocyaninate) complex which contains eight acetylbenzo(15-crown-5) units. The starting compound was diethyl (3,4-dicyanophenyl)acetoxybenzo(15-crown-5)malonate (1). The synthesis of the desired compound was accomplished by the reaction of the o-dicyano compound (1) with lutetium acetate in hexanol in the presence of 1,8-diazabicyclo[5,4,0]undec-7-ene (DBU) as a strong base. The ESR spectrum confirmed the radical nature of the complex. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00945714
- Volume :
- 33
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Synthesis & Reactivity in Inorganic & Metal-Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 11110139
- Full Text :
- https://doi.org/10.1081/SIM-120025438