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X-ray studies of 2-amino-4-(3-nitrophenyl)-5-oxo-4,5-dihydropyrano[3,2- c] chromene-3-carbonitrile and 2-amino-7,7-dimethyl-4-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4 H-chromene-3-carbonitrile.
- Source :
-
Crystallography Reports . Dec2015, Vol. 60 Issue 7, p1136-1141. 6p. - Publication Year :
- 2015
-
Abstract
- Two carbonitrile compounds, 2-amino-4-(3-nitrophenyl)-5-oxo-4,5-dihydropyrano[3,2- c] chromene-3-carbonitrile ( I) and 2-amino-7,7-dimethyl-4-(4-nitrophenyl)-5-oxo-5,6,7,8-tetrahydro-4 H-chromene-3-carbonitrile ( II), were synthesized, and their crystal structures were determined by X-ray diffraction technique. The crystals are triclinic, a = 7.7970(12), 8.2171(7), b = 9.0390(10), 9.2238(7), c = 15.148(2), 14.5585(11) Å, α = 81.439(10)°, 74.895(6)°, β = 75.194(12)°, 87.392(6)°, γ = 76.151(11)°, 78.552(7)°, for I and II, respectively, Z = 2, sp. gr. P $$\overline 1$$. The pyran ring in both the compounds deviates significantly from planarity and adopts boat conformation. The crystal structure is stabilized by N-H···O and N-H···N hydrogen bonds. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10637745
- Volume :
- 60
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Crystallography Reports
- Publication Type :
- Academic Journal
- Accession number :
- 111160210
- Full Text :
- https://doi.org/10.1134/S1063774515070251