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DPP containing D–π–A organic dyes toward highly efficient dye-sensitized solar cells.
- Source :
-
Dyes & Pigments . Feb2016, Vol. 125, p27-35. 9p. - Publication Year :
- 2016
-
Abstract
- Two diketopyrrolopyrrole (DPP) containing D–π–A organic dyes, named as TEDBn and TEDTh were prepared. Their optical, electrochemical and photophysical properties were investigated and their application in dye-sensitized solar cells (DSCs) was demonstrated. The broaden absorption and low-energy λ max of DPP containing dyes were contributed from DPP bridge and EDOT π-conjugated moiety. Compared to TEDTh, TEDBn has smaller absorption coefficient and higher optical bandgap. Nevertheless the power conversion efficiency (PCE) of TEDBn based DSC is 7.2% which is larger than that of TEDTh based DSC and 90% of N719 based cell. The higher PCE of TEDBn based device originates from both higher open-circuit voltage (V OC ) and short-circuit current (J SC ). Femtosecond time-resolved photoluminescence data show that the electron injection at TEDBn/TiO 2 is more efficient than that at TEDTh/TiO 2 interface, resulting in higher J SC (and IPCE) of TEDBn based DSC. Density function theory (DFT) calculations revealed that TEDBn is a linear structure which leads to higher dye loading on TiO 2 than TEDTh which featured a bend conformation, better TiO 2 surface coverage, resulting in larger V OC . Therefore, the overall efficiency of the cell sensitized by TEDBn is better than that the devices based on TEDTh. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 01437208
- Volume :
- 125
- Database :
- Academic Search Index
- Journal :
- Dyes & Pigments
- Publication Type :
- Academic Journal
- Accession number :
- 111487208
- Full Text :
- https://doi.org/10.1016/j.dyepig.2015.09.033