Absorption by water vapour in the 1 to <f>2 μm</f> region

The near-IR (in the range 5000–<f>10 000 cm−1</f>, 1–<f>2 μm</f>) bands of water vapour have been measured in absorption in the laboratory at sub-Doppler spectral resolution (up to <f>0.0054 cm−1</f> after numerical apodisation) by Fourier transform spectroscopy. Measurements have been made at <f>296 K</f> on pure water vapour (at pressures between 2 and <f>20 hPa</f>) and mixtures of water and air (at total pressures of 100 and <f>1000 hPa</f>), at optical path lengths in the range 0.26–<f>9.75 m</f>. Measured absorption intensities have been compared with values calculated using the HITRAN 2000 molecular database. These comparisons indicate that the intensities of the <f>2ν(1.4 μm)</f> and <f>2ν+δ(1.14 μm)</f> bands are underestimated in HITRAN 2000 by approximately 15% and 20%, respectively, for pure water vapour measurements, and 12% for both bands in the case of water–air mixtures. The <f>ν+δ (1.86 μm)</f> band is in good agreement (0.4% for pure water vapour and less than 6% for mixtures with air) with HITRAN 2000. For typical atmospheric conditions, these absorption bands are sufficiently strong that radiation is fully absorbed at wavelengths in the region of the band centres. Hence the extra absorption that has been identified has only a modest impact (<f>0.16 W m−2</f> or about 0.2%) on the global-mean clear-sky absorption of solar radiation. The impact in the upper troposphere is several times larger. [Copyright &y& Elsevier]