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Influence of polymerization method on the thermoelectric properties of multi-walled carbon nanotubes/polypyrrole composites.
- Source :
-
Synthetic Metals . Jan2016, Vol. 211, p58-65. 8p. - Publication Year :
- 2016
-
Abstract
- Multi-walled carbon nanotubes (MWCNTs)/polypyrrole (PPy) thermoelectric composites with MWCNT content ranging from 0 to 68 wt% have been prepared by in-situ polymerization or interfacial polymerization method. Both methods have enhanced the thermoelectric properties of PPy significantly. TEM observation shows that the in-situ polymerized composite consists of MWCNTs/PPy core/shell structures, while the interfacial polymerized composite is inhomogeneous: only a small amount of MWCNTs being coated with PPy and most of the MWCNTs aggregated into bundles and clusters. Due to the uniform dispersion of MWCNTs in the PPy matrix and therefore the stronger π–π interactions between MWCNTs and PPy, the in-situ polymerized composite shows higher electrical conductivity than the interfacial polymerized composite. Both of the composites have similar Seebeck coefficients. The power factor of an in-situ polymerized composite with 68 wt% MWCNTs reaches 2.20 μW/mK 2 , which is 26.5 times greater than that of pure PPy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03796779
- Volume :
- 211
- Database :
- Academic Search Index
- Journal :
- Synthetic Metals
- Publication Type :
- Academic Journal
- Accession number :
- 111825778
- Full Text :
- https://doi.org/10.1016/j.synthmet.2015.11.013