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Sequential oxidation/thermal induced intramolecular [2+2] cycloaddition of propynol-vinylidenecyclopropanes: access to novel cyclobutene-containing spiro[2.3]hexenes.
- Source :
-
Tetrahedron . Feb2016, Vol. 72 Issue 5, p584-591. 8p. - Publication Year :
- 2016
-
Abstract
- An efficient and highly regioselective synthetic method has been developed for the preparation of novel cyclobutene-containing spiro[2.3]hexenes fused with six or seven-membered carbo- or hetero-cycles in good to excellent yields following a thermal induced intramolecular [2+2] cycloaddition of alkynone-vinylidenecyclopropanes or a sequential oxidation/thermal induced intramolecular [2+2] cycloaddition process of propynol-vinylidenecyclopropanes under metal-free conditions. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404020
- Volume :
- 72
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Tetrahedron
- Publication Type :
- Academic Journal
- Accession number :
- 112176571
- Full Text :
- https://doi.org/10.1016/j.tet.2015.11.064